SAFETY DATA SHEET according to Regulation 1907/2006
Creation date: 17.6.2010
Zeolite compound / Zeolith Compound ZC9
The mixture of raw materials for the production of detergents
SILKEM, d. o. o.
+386 2 7991 214 (7h - 15h)
According to the regulation, the product is not classified as hazardous.
Pictograms not applicable according to Regulation 1272/2008.
Irritates eyes and skin.
The substances in the mixture are not classified as persistent, bioaccumulative and toxic (PBT) or very persistent and very bioaccumulative (vPvB).
For mixtures see 3.2.
|%||Classification according to Regulation (EC)
No 1272/2008 (CLP)
|Specific Conc. Limits||Classification according to directive 67/548/EEC or 99/45/EC||REACH Registration No.|
|86-92||not classified||not classified||01-2119429034-49-0017|
|2-propenoic acid, polymer with 2,5-furandione, sodium salt (acrylic acid/maleic acid - copolymer, sodium salt)||52255-49-9
|9,0-9,6||not classified||not classified||-|
|(1-hydroxyethylidene)bisphosphonic acid, sodium salt||29329-71-3
|0,6-0,8||Met. Corr. 1; H290
Acute Tox. 4; H302
In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). Never give anything by mouth to an unconscious person. Place patient in recovery position and ensure airway patency.
Remove patient to fresh air - move out of dangerous area. Ventilate the premises. Inhale fresh air. Seek medical help immediately.
Areas of the body that have come into contact with the product must be rinsed immediately with plenty of running water. If irritation of skin persists seek medical attention.
Immediately flush eyes with plenty of water while keeping eyelids apart (at least 15 minutes). Consult a physician immediately!
In case of doubt or if feeling unwell seek medical help.
Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Use the usual extinguishing measures (carbon dioxide (CO2), dry chemical, foam; water spray)
Full water jet.
In case of fire or heating do not breathe fumes/vapours.
Use personal protective equipment (Section 8). Wear safety gloves and glasses. Thoroughly clean hands after use or contact.
High risk of slipping due to leakage/spillage of product.
Use appropriate containment to dispose waste (according to current regulation-section 13.) If accidental large entry into water or ground occurs, inform responsible authorities.
Pick up mechanically and remove it in accordance with regulation.
See also Sections 8 and 13.
Avoid contact with skin and eyes. Use personal protective equipment. Do not eat or drink while working.
Keep in well closed containers. Keep in a dry place. Keep container in a well ventilated place.
BS EN 14042:2003 Workplace atmospheres. Guide for the application and use of procedures for the assessment of exposure to chemical and biological agents. BS EN 482:2012+A1:2015 Workplace exposure. General requirements for the performance of procedures for the measurement of chemical agents. BS EN 689:2018 Workplace exposure. Measurement of exposure by inhalation to chemical agents. Strategy for testing compliance with occupational exposure limit values.
|Name||Type||Exposure route||Exposure frequency||Value||Remark|
|(1-hydroxyethylidene)bisphosphonic acid, sodium salt (29329-71-3)||Consumer||oral||short term (systemic effects)||6,5 mg/kg bw|
|(1-hydroxyethylidene)bisphosphonic acid, sodium salt (29329-71-3)||Consumer||oral||long term (systemic effects)||6,5 mg/kg bw/day|
|(1-hydroxyethylidene)bisphosphonic acid, sodium salt (29329-71-3)||fresh water||0,134 mg/L|
|(1-hydroxyethylidene)bisphosphonic acid, sodium salt (29329-71-3)||marine water||0,014 mg/L|
|(1-hydroxyethylidene)bisphosphonic acid, sodium salt (29329-71-3)||soil||41 mg/kg|
|(1-hydroxyethylidene)bisphosphonic acid, sodium salt (29329-71-3)||water treatment plant||20 mg/L|
|(1-hydroxyethylidene)bisphosphonic acid, sodium salt (29329-71-3)||marine water sediment||5,9 mg/kg||dry weight|
|(1-hydroxyethylidene)bisphosphonic acid, sodium salt (29329-71-3)||fresh water sediment||59 mg/kg||dry weight|
Avoid contact with eyes and skin.
Remove all contaminated clothes immediately and wash them before reuse. Keep eyewash bottles or personal eyewash units available.
Safety glasses with side protection (EN 166). Eye wash bottle with clean water.
Protective gloves (EN 374).
Cotton protective clothing and shoes that cover the entire foot (EN ISO 20345). Avoid contact with skin. Shower.
Wear suitable protective breathing mask (EN 136) with filter A2-P2 (EN 14387).
|-||pH||10 – 11|
|-||Melting point/freezing point||No information.|
|-||Initial boiling point/boiling range||No information.|
|-||Flash point||No information.|
|-||Evaporation rate||No information.|
|-||Flammability (solid, gas)||No information.|
|-||Explosion limits (vol%)||No information.|
|-||Vapour pressure||No information.|
|-||Vapour density||No information.|
520 – 620 kg/m3
|-||Partition coefficient||No information.|
|-||Auto-ignition temperature||No information.|
|-||Decomposition temperature||No information.|
|-||Explosive properties||No information.|
|-||Oxidising properties||No information.|
Product is stable under normal conditions.
Follow directions for use and storage. Protect from moisture and water - keep in dry place.
Under normal use conditions no hazardous decomposition products are expected.
|Zeolite (1318-02-1)||oral||LD50||Dog||1000 – 31600 mg/kg|
|Zeolite (1318-02-1)||oral||LD50||rat||5000 – 31600 mg/kg|
|(1-hydroxyethylidene)bisphosphonic acid, sodium salt (29329-71-3)||oral||LD50||rat||940 mg/kg bw||OECD 401|
|(1-hydroxyethylidene)bisphosphonic acid, sodium salt (29329-71-3)||oral||ATE||940 mg/kg bw|
|(1-hydroxyethylidene)bisphosphonic acid, sodium salt (29329-71-3)||Non-irritant.|
|(1-hydroxyethylidene)bisphosphonic acid, sodium salt (29329-71-3)||Irritating.|
|(1-hydroxyethylidene)bisphosphonic acid, sodium salt (29329-71-3)||dermal||Non sensitising.|
|Substance (CAS Nr.)||Type||Value||Exposure time||Species||Organism||Method||Remark|
|(1-hydroxyethylidene)bisphosphonic acid, sodium salt (29329-71-3)||LC50||195 mg/L||fish||Oncorhynchus mykiss||OECD 203|
|LC50||> 250 mg/L||Aquatic organisms||Photobacterium phosphoreum||DIN 38412/part 8|
|EC50||527 mg/L||crustacea||Daphnia magna||OECD 202|
|Substance (CAS Nr.)||Type||Value||Exposure time||Species||Organism||Method||Remark|
|(1-hydroxyethylidene)bisphosphonic acid, sodium salt (29329-71-3)||NOEC||200 mg/l|
|NOEC||6,75 mg/l||crustaceans||Daphnia magna||EPA 66013-75-009|
|Substance (CAS Nr.)||Type||Rate||Time||Evaluation||Method||Remark|
|(1-hydroxyethylidene)bisphosphonic acid, sodium salt (29329-71-3)||aerobic||1,6 %||not readily biodegradable|
|Substance (CAS Nr.)||Media||Value||Temperature||pH||Concentration||Method|
|(1-hydroxyethylidene)bisphosphonic acid, sodium salt (29329-71-3)||Log Pow||-3,5|
|Substance (CAS Nr.)||Type||Criterion||Value||Evaluation||Method||Remark|
|(1-hydroxyethylidene)bisphosphonic acid, sodium salt (29329-71-3)||Soil||log KOC||16610|
Avoid release to the environment.
Substance: (1-hydroxyethylidene)bisphosphonic acid, sodium salt
No bioaccumulation expected.
This substance is not PBT-/vPvB..
Disposal must be made according to official regulations: deliver it to authorised collector/remover/transformer of hazardous waste.
Deliver completely emptied containers to approved waste disposal authorities.
ADR, RID, IMDG, ADN, IATA: Not dangerous according to transport regulations.
- Regulation (EC) No 1907/2006 concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH)(including last amendment Commission Regulation (EU) 2015/830)
- Regulation (EC) No 1272/2008 on classification, labelling and packaging of substances and mixtures
Water hazard class: 2, annex 4.
No Chemical Safety Assessment has been carried out for this substance/mixture by the supplier.
ATE - Acute Toxicity Estimate
ADR - European Agreement concerning the International Carriage of Dangerous Goods by Road
ADN - European Agreement concerning the International Carriage of Dangerous Goods by Inland Waterways
CEN - European Committee for Standardisation
C&L - Classification and Labelling
CLP - Classification Labelling Packaging Regulation; Regulation (EC) No 1272/2008
CAS# - Chemical Abstracts Service number
CMR - Carcinogen, Mutagen, or Reproductive Toxicant
CSA - Chemical Safety Assessment
CSR - Chemical Safety Report
DMEL - Derived Minimal Effect Level
DNEL - Derived No Effect Level
DPD - Dangerous Preparations Directive 1999/45/EC
DSD - Dangerous Substances Directive 67/548/EEC
DU - Downstream User
EC - European Community
ECHA - European Chemicals Agency
EC-Number - EINECS and ELINCS Number (see also EINECS and ELINCS)
EEA - European Economic Area (EU + Iceland, Liechtenstein and Norway)
EEC - European Economic Community
EINECS - European Inventory of Existing Commercial Substances
ELINCS - European List of notified Chemical Substances
EN - European Standard
EQS - Environmental Quality Standard
EU - European Union
Euphrac - European Phrase Catalogue
EWC - European Waste Catalogue (replaced by LoW – see below)
GES - Generic Exposure Scenario
GHS - Globally Harmonized System
IATA - International Air Transport Association
ICAO-TI - Technical Instructions for the Safe Transport of Dangerous Goods by Air
IMDG - International Maritime Dangerous Goods
IMSBC - International Maritime Solid Bulk Cargoes
IT - Information Technology
IUCLID - International Uniform Chemical Information Database
IUPAC - International Union for Pure Applied Chemistry
JRC - Joint Research Centre
Kow - octanol-water partition coefficient
LC50 - Lethal Concentration to 50 % of a test population
LD50 - Lethal Dose to 50% of a test population (Median Lethal Dose)
LE - Legal Entity
LoW - List of Wastes (see http://ec.europa.eu/environment/waste/framework/list.htm)
LR - Lead Registrant
M/I - Manufacturer / Importer
MS - Member States
MSDS - Material Safety Data Sheet
OC - Operational Conditions
OECD - Organization for Economic Co-operation and Development
OEL - Occupational Exposure Limit
OJ - Official Journal
OR - Only Representative
OSHA - European Agency for Safety and Health at work
PBT - Persistent, Bioaccumulative and Toxic substance
PEC - Predicted Effect Concentration
PNEC(s) - Predicted No Effect Concentration(s)
PPE - Personal Protection Equipment
(Q)SAR - Qualitative Structure Activity Relationship
REACH - Registration, Evaluation, Authorisation and Restriction of Chemicals Regulation (EC) No 1907/2006
RID - Regulations concerning the International Carriage of Dangerous Goods by Rail
RIP - REACH Implementation Project
RMM - Risk Management Measure
SCBA - Self-Contained Breathing Apparatus
SDS - Safety data sheet
SIEF - Substance Information Exchange Forum
SME - Small and Medium sized Enterprises
STOT - Specific Target Organ Toxicity
(STOT) RE - Repeated Exposure
(STOT) SE - Single Exposure
SVHC - Substances of Very High Concern
UN - United Nations
vPvB - Very Persistent and Very Bioaccumulative
ZC9, Silkem, d. o. o., Version 1.0
H290 May be corrosive to metals.
H302 Harmful if swallowed.