Cure It Evo Primer - Part C

Product code

[UFI: U500-C029-G003-D9X9]

1.2. Relevant identified uses of the substance or mixture and uses advised against

Relevant identified uses

Primer.

Uses advised against

Do not use for purposes other than those prescribed.

1.3. Details of the supplier of the safety data sheet

1.4. Emergency telephone number

+44 (0)1942 518150 Mon-Friday 8.30am – 4.30pm

2. Hazards identification

2.1 Classification of the substance or mixture

Classification according to Regulation (EC) No 1272/2008 (CLP)

Flam. Liq. 3; H226  Flammable liquid and vapour.
Skin Irrit. 2; H315  Causes skin irritation.
Skin Sens. 1; H317  May cause an allergic skin reaction.
Eye Irrit. 2; H319  Causes serious eye irritation.
Acute Tox. 4; H332  Harmful if inhaled.
Resp. Sens. 1; H334  May cause allergy or asthma symptoms or breathing difficulties if inhaled.
STOT SE 3; H335  May cause respiratory irritation.
Carc. 2; H351  Suspected of causing cancer.
STOT RE 2; H373  May cause damage to organs through prolonged or repeated exposure.
Aquatic Chronic 3; H412  Harmful to aquatic life with long lasting effects.

2.2 Label elements

2.2.1. Labelling according to Regulation (EC) No 1272/2008 [CLP]

Signal word: Danger

H226  Flammable liquid and vapour.
H315  Causes skin irritation.
H317  May cause an allergic skin reaction.
H319  Causes serious eye irritation.
H332  Harmful if inhaled.
H334  May cause allergy or asthma symptoms or breathing difficulties if inhaled.
H335  May cause respiratory irritation.
H351  Suspected of causing cancer.
H373  May cause damage to organs through prolonged or repeated exposure.
H412  Harmful to aquatic life with long lasting effects.
P210  Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P280  Wear protective gloves/protective clothing/eye protection/face protection.
P303 + P361 + P353  IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water [or shower].
P304 + P340  IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P305 + P351 + P338  IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P308 + P313  IF exposed or concerned: Get medical advice/attention.

2.2.2. Contains:

xylene
reaction mass of 4,4'-methylenediphenyl diisocyanate and o-(p-isocyanatobenzyl)phenyl isocyanate
diphenylmethane diisocyanate, isomers and homologues
4,4'-methylenediphenyl diisocyanate, oligomers

2.2.3. Special provisions

MDI notice
Persons already sensitised to diisocyanates may develop allergic reactions when using this product. Persons suffering from asthma, eczema or skin problems should avoid contact, including dermal contact, with this product. This product should not be used under conditions of poor ventilation unless a protective mask with an appropriate gas filter (i.e. type A1 according to standard EN 14387) is used.

EUH204: Contains isocyanates. May produce an allergic reaction.
Information according to Commission Regulation (EC) No. 2020/1449, which must appear on the label of a product containing diisocyanates in a concentration ≥ 0.1%
As from 24 August 2023 adequate training is required before industrial or professional use.

2.3. Other hazards

The substances in the mixture are not classified as persistent, bioaccumulative and toxic (PBT) or very persistent and very bioaccumulative (vPvB).

Following inhalation

Remove patient to fresh air - move out of dangerous area. Keep at rest in a position comfortable for breathing. When breathing is difficult, properly trained personnel may assist affected person by administering oxygen. If symptoms develop and persist, seek medical attention. Show to physician Safety data sheet and label.

Following skin contact

Wash thoroughly using copious warm water and soap or cleaning agent based on polyethylene and rinse thoroughly. Wash contaminated clothes and shoes before reuse. If irritation persists, seek medical attention. Show this safety data sheet to a doctor.

Following eye contact

Rinse immediately with plenty of water. Remove any contact lenses and open eyelids wide apart. Continue to rinse for at least 10 minutes. If irritation does not stop, seek professional medical treatment! Show the physician the safety data sheet or label.

Following ingestion

Rinse mouth thoroughly with water. Remove any dentures. Give a few small glasses of water or milk to drink. Stop if the affected person feels sick as vomiting may be dangerous. Do not induce vomiting unless under the direction of medical personnel. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Never give anything by mouth to an unconscious person. Move affected person to fresh air and keep warm and at rest in a position comfortable for breathing. In case of doubt or if feeling unwell seek medical help. Show the physician the safety data sheet or label.

4.2. Most important symptoms and effects, both acute and delayed

Inhalation

Harmful.
Can cause irritation of respiratory system.
May cause allergy or asthma symptoms or breathing difficulties if inhaled

Skin contact

Itching, redness, pain.
May cause sensitisation by skin contact (symptoms: itching, redness, rashes).

Eye contact

Causes severe eye irritation.
Redness, tearing, pain.

Ingestion

May cause nausea/vomiting and diarrhea.
May cause abdominal discomfort.

4.3. Indication of any immediate medical attention and special treatment needed

Treat symptomatically.

Unsuitable extinguishing media

Full water jet.

5.2. Special hazards arising from the substance or mixture

Hazardous combustion products

In case of a fire toxic gases can be generated; do not inhale gases/smoke. In the event of fire the following can be generated: carbon monoxide (CO), carbon dioxide (CO₂).
Nitrogen oxides (NO_X). Hydrocarbons. Possible bursting of container due to pressure rise.

5.3. Advice for firefighters

Protective actions

No action shall be taken involving any personal risk or without suitable training. In case of fire evacuate the area. In case of fire or heating do not breathe fumes/vapours. Keep upwind to avoid inhalation of firefighting gases, vapours, fumes and smoke. Cool containers at risk with water spray. If possible remove containers from endangered area. Use water to cool exposed surfaces and to protect the firefighters. Prolonged heating can cause an explosion. Reaction between water and hot isocyanate may be vigorous.

Special protective equipment for firefighters

Firefighters should wear appropriate protective clothing for firefighters (including helmets, protective boots and gloves) (EN 469) and self-contained breathing apparatus (SCBA) with a full face-piece (EN 137).

Additional information

Contaminated firefighting water must be disposed of in accordance with the regulations; do not allow to reach the sewage system.

Ensure adequate ventilation. Keep away from sources of ignition and/or heat; No smoking! No action shall be taken involving any personal risk or without suitable training. Prevent access to unprotected personnel. Evacuate the danger zone. Do not breathe vapour or mist. Avoid contact with skin, eyes and clothing. Do not touch or walk through spilled material. In case of insufficient ventilation, wear suitable respiratory protection equipment.

6.1.2. For emergency responders

During intervention, use personal protective equipment (Section 8).

6.2. Environmental precautions

Do not allow product to reach water/drains/sewage systems or permeable soil. If accidental large entry into water or ground occurs, inform responsible authorities.

6.3. Methods and material for containment and cleaning up

6.3.1. For containment

Stem the spill if this does not pose risks.

6.3.2. For cleaning up

Ventilate the premises. Approach the spill from upwind. For small spillages absorb the spillage with an inert, dry material and place it in a suitable waste disposal container. Large spill: Evacuate exposed perosennel from the danger area. Wash spillages into an effluent treatment plant or proceed as follows: Absorb product (with inert material), collect it in special container and dispose it to a licensed hazardous-waste disposal contractor. Fill into marked and tightly sealed containers. Clean contaminated objects and areas thoroughly observing environmental regulations. Contaminated absorbent material may pose the same hazard as the spilt product. Wash thoroughly after dealing with a spillage. Dispose of waste to licensed waste disposal site in accordance with the requirements of the local Waste Disposal Authority.

6.3.3. Other information

See Section 11 for additional information on health hazards. See Section 12: ECOLOGICAL INFORMATION.

6.4. Reference to other sections

See also Sections 8 and 13.

Use general or local exhaust ventilation to prevent inhaling vapours and aerosols. Avoid formation of aerosols.

Do not discharge into drains, surface water and soil. After use immediately close container tightly.

7.1.2. Advice on general occupational hygiene

Do not eat, drink or smoke while working. Do not breathe vapours/mist. Use good personal hygiene practices – wash hands at breaks and when done working with material. Avoid contact with skin, eyes and clothes. Remove contaminated clothes and wash them before reuse. Wear suitable protective equipment; see Section 8. Avoid exposure - obtain special instructions before using. Do not handle broken packages without protective equipment. Read and understand all safety instructions before use. At the end of working time, take a shower and change clothes.

7.2. Conditions for safe storage, including any incompatibilities

7.2.1. Technical measures and storage conditions

Protect from open fire, heat and direct sunlight. Keep away from food, drink and animal feeding stuffs. Keep away from sources of ignition - no smoking. Keep in a cool, dry and well ventilated place. Store in accordance with local regulations. To prevent damage of packaging. Bund storage facilities to prevent soil and water pollution in the event of spillage. The storage area floor should be leak-tight, jointless and not absorbent.

7.2.2. Packaging materials

Store only in original container.

7.2.3. Requirements for storage rooms and vessels

Close opened containers after use. Put the containers upright to prevent from leaking. Do not store in unlabelled containers.

7.2.4. Storage class

-

7.2.5. Further information on storage conditions

-

7.3. Specific end use(s)

See identified uses in Section 1.2.

-

8.1.2. Information on monitoring procedures

BS EN 14042:2003 Title Identifier: Workplace atmospheres. Guide for the application and use of procedures for the assessment of exposure to chemical and biological agents. BS EN 482:2021 Workplace exposure. Procedures for the determination of the concentration of chemical agents. Basic performance requirements.

8.1.3. DNEL/DMEL values

8.1.4. PNEC values

8.2. Exposure controls

8.2.1. Appropriate engineering control

Do not breathe vapours/aerosols. Use good personal hygiene practices – wash hands at breaks and when done working with material. Handle in accordance with good industrial hygiene and safety practice. Do not eat, drink or smoke while working. Avoid contact with skin, eyes and clothes.

Remove all contaminated clothes immediately and wash them before reuse. Keep eyewash bottles or personal eyewash units and emergency showers available. Contaminated work clothing should not be allowed out of the workplace. Clean equipment and the work area every day. Warn cleaning personnel of any hazardous properties of the product.

Provide good ventilation and local exhaust in areas with increased concentration. Keep away from food, drink and animal feeding stuffs.

8.2.2. Personal protective equipment

Tight fitting protective goggles (EN 166). If an inhalation hazard also exists, a full-face respirator may be required instead.

If a risk assessment indicates it is necessary, protection gloves should be worn. Protective gloves (EN iSO 374). When prolonged or frequently repeated contact may occur, a glove with a protection class of 5 or higher (breakthrough time greater than 240 minutes according to EN374) is recommended. When only brief contact is expected, a glove with a protection class of 3 or higher (breakthrough time greater than 60 minutes according to EN374) is recommended. Check during use that gloves are retaining their protective properties and change them as soon as any deterioration is detected. Frequent changes of gloves are recommended.

Appropriate footwear and additional protective clothing complying with an approved standardshould be worn if a risk assessment indicates skin contamination is possible. At high risk of skin exposure chemical suits (EN ISO 6530:2005) and boots may be required (EN ISO 20345:2012).

Not needed under normal use and adequate ventilation. If limit values are exceeded use standardized respirators. Use a respirator with an approved filter if a risk assessment indicates this is necessary. Check that mask fits tightly and change filter regularly. Wear suitable protective breathing mask (EN 136) with filter A2-P2 (EN 14387). At elevated concentrations of vapours/aerosols in the air wear a mask (EN 140) with filter A2-P2 (EN 14387).

-

8.2.3. Environmental exposure controls

Implement measures to protect the environment. Avoid release to the environment. The emissions generated by manufacturing processes, including those generated by ventilation equipment, should be checked to ensure compliance with environmental standards.

Keep container tightly sealed when not in use.

Do not allow product to reach drains, sewage systems or ground water.

10.2. Chemical stability

Product is stable under normal conditions of use, recommended handling and storage conditions.

10.3. Possibility of hazardous reactions

There are no known hazardous reactions.

10.4. Conditions to avoid

No special precautions required. Consider the directions for use and storage.

10.5. Incompatible materials

Not known.

10.6. Hazardous decomposition products

Under normal use conditions no hazardous decomposition products are expected. In case of fire/explosion vapours/gases that pose a health hazard are released.

Summary of evaluation of the CMR properties

Suspected of causing cancer.

11.2. Information on other hazards

11.2.1. Endocrine disrupting properties

No information.

11.2.2. Other information

No information.

12.1.2. Chronic (long-term) toxicity

No information.

12.2. Persistence and degradability

12.2.1. Abiotic degradation, physical- and photo-chemical elimination

No information.

12.2.2. Biodegradation

No information.

Additional information

No data on biodegradability.

12.3. Bioaccumulative potential

12.3.1. Partition coefficient

No information.

12.3.2. Bioconcentration factor (BCF)

No information.

Additional information

No data available for mixture.

12.4. Mobility in soil

12.4.1. Known or predicted distribution to environmental compartments

No information.

12.4.2. Surface tension

No information.

12.4.3. Adsorption/Desorption

No information.

Additional information

No data available for mixture.

12.5. Results of PBT and vPvB assessment

Does not contain component(s) that meet(s) the criteria of PBT and/or vPvB as listed in Annex XIII of Regulation (EC) No 1907/2006.

12.6. Endocrine disrupting properties

No information.

12.7. Additional information

Harmful to aquatic life with long lasting effects.
Do not allow to reach ground water, water courses or sewage system.

Uncleaned containers are classified as hazardous waste - they should be handled in the same manner as the contents. Deliver completely emptied containers to approved waste disposal authorities. Uncleaned containers should not be perforated, cut or welded. Empty containers represent a fire hazard as they may contain flammable product residues and vapour. Dispose of in accordance with applicable waste disposal regulation.

13.1.2. Waste treatment-relevant information

-

13.1.3. Sewage disposal-relevant information

-

13.1.4. Other disposal recommendations

-

15.1.1. Information according 2004/42/EC about limitation of emissions of volatile organic compounds (VOC-guideline)

Not applicable.

15.2. Chemical Safety Assessment

A Chemical Safety Assessment has not been carried out.

Abbreviations and acronyms

ATE - Acute Toxicity Estimate
ADR - Agreement concerning the International Carriage of Dangerous Goods by Road
ADN - European Agreement concerning the International Carriage of Dangerous Goods by Inland Waterways
CEN - European Committee for Standardisation
C&L - Classification and Labelling
CLP - Classification Labelling Packaging Regulation; Regulation (EC) No 1272/2008
CAS# - Chemical Abstracts Service number
CMR - Carcinogen, Mutagen, or Reproductive Toxicant
CSA - Chemical Safety Assessment
CSR - Chemical Safety Report
DMEL - Derived Minimal Effect Level
DNEL - Derived No Effect Level
DPD - Dangerous Preparations Directive 1999/45/EC
DSD - Dangerous Substances Directive 67/548/EEC
DU - Downstream User
EC - European Community
ECHA - European Chemicals Agency
EC-Number - EINECS and ELINCS Number (see also EINECS and ELINCS)
EEA - European Economic Area (EU + Iceland, Liechtenstein and Norway)
EEC - European Economic Community
EINECS - European Inventory of Existing Commercial Substances
ELINCS - European List of notified Chemical Substances
EN - European Standard
EQS - Environmental Quality Standard
EU - European Union
Euphrac - European Phrase Catalogue
EWC - European Waste Catalogue (replaced by LoW – see below)
GES - Generic Exposure Scenario
GHS - Globally Harmonized System
IATA - International Air Transport Association
ICAO-TI - Technical Instructions for the Safe Transport of Dangerous Goods by Air
IMDG - International Maritime Dangerous Goods
IMSBC - International Maritime Solid Bulk Cargoes
IT - Information Technology
IUCLID - International Uniform Chemical Information Database
IUPAC - International Union for Pure Applied Chemistry
JRC - Joint Research Centre
Kow - octanol-water partition coefficient
LC₅₀ - Lethal Concentration to 50 % of a test population
LD₅₀ - Lethal Dose to 50% of a test population (Median Lethal Dose)
LE - Legal Entity
LoW - List of Wastes (see http://ec.europa.eu/environment/waste/framework/list.htm)
LR - Lead Registrant
M/I - Manufacturer / Importer
MS - Member States
MSDS - Material Safety Data Sheet
OC - Operational Conditions
OECD - Organization for Economic Co-operation and Development
OEL - Occupational Exposure Limit
OJ - Official Journal
OR - Only Representative
OSHA - European Agency for Safety and Health at work
PBT - Persistent, Bioaccumulative and Toxic substance
PEC - Predicted Effect Concentration
PNEC(s) - Predicted No Effect Concentration(s)
PPE - Personal Protection Equipment
(Q)SAR - Qualitative Structure Activity Relationship
REACH - Registration, Evaluation, Authorisation and Restriction of Chemicals Regulation (EC) No 1907/2006
RID - Regulations concerning the International Carriage of Dangerous Goods by Rail
RIP - REACH Implementation Project
RMM - Risk Management Measure
SCBA - Self-Contained Breathing Apparatus
SDS - Safety data sheet
SIEF - Substance Information Exchange Forum
SME - Small and Medium sized Enterprises
STOT - Specific Target Organ Toxicity
(STOT) RE - Repeated Exposure
(STOT) SE - Single Exposure
SVHC - Substances of Very High Concern
UN - United Nations
vPvB - Very Persistent and Very Bioaccumulative

Key literature references and sources for data

-

List of relevant H phrases

H226  Flammable liquid and vapour.
H304  May be fatal if swallowed and enters airways.
H312  Harmful in contact with skin.
H315  Causes skin irritation.
H317  May cause an allergic skin reaction.
H319  Causes serious eye irritation.
H332  Harmful if inhaled.
H334  May cause allergy or asthma symptoms or breathing difficulties if inhaled.
H335  May cause respiratory irritation.
H351  Suspected of causing cancer .
H373  May cause damage to organs through prolonged or repeated exposure .
H412  Harmful to aquatic life with long lasting effects.

Further information

Medical supervision of all employees who come in contact with respiratory sensitisers is recommended. Personell with a history of asthma-type conditions, bronchitis or skin sensitisation conditions should not work with MDI based products. The OELs listed do not apply to previously sensitised individuals. Sensitised individuals should be removed from any further exposure.