SAFETY DATA SHEET according to Regulation 1907/2006
Product name:

PREMIX B3

Creation date: 18.6.2008 · Revision: 7.1.2016 · Version: 2.0

1. Identification of the substance/mixture and of the company/undertaking


chemius.net/SN2b5

1.1. Product identifier

Product name

PREMIX B3

1.2. Relevant identified uses of the substance or mixture and uses advised against

Use

The mixture of raw materials for the production of detergents

Uses advised against

not known.

1.3. Details of the supplier of the safety data sheet

Manufacturer

SILKEM, d. o. o.
Address: Tovarniška cesta 10, 2325 Kidričevo, Slovenia
Tel.: +386 2 7991 200
Fax: +386 2 7991 230
e-mail: info@silkem.si

1.4. Emergency telephone number

Emergency

112

Supplier

+386 2 7991 208 (7h - 15h)

2. Hazards identification

2.1 Classification of the substance or mixture

Classification according to Reg. 1272/2008

Skin Irrit. 2; H315  Causes skin irritation.
Eye Dam. 1; H318  Causes serious eye damage.

2.2 Label elements

2.2.1. Labelling according to Regulation (EC) No 1272/2008 [CLP]

Signal word: Danger

H315  Causes skin irritation.
H318  Causes serious eye damage.
P264  Wash hands, face and exposed skin thoroughly after handling.
P280  Wear protective gloves/protective clothing/eye protection/face protection.
P305 + P351 + P338  IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P362 + P364  Take off contaminated clothing and wash it before reuse.

2.2.2. Contains:

Dodecylbenzenesulfonic acid, sodium salt (CAS: 68411-30-3, EC: 285-600-2)
Sodium silicate (CAS: 1344-09-8, EC: 215-687-4)

2.2.3. Special provisions

Irritates eyes and skin.

2.3. Other hazards

The substances in the mixture does not meet the PBT / vPvB criteria according to REACH, Annex XIII

3. Composition/information on ingredients

3.1. Substances

For mixtures see 3.2.

3.2. Mixtures

Chemical name CAS
EC
Index
% Classification according to Regulation (EC) No 1272/2008 [CLP] Classification according to directive 67/548/EEC or 99/45/EC REACH reg. number
Zeolite 1318-02-1
215-283-8
-
69-75 not classified not classified 01-2119429034-49-0017
Sodium sulphate 7757-82-6
231-820-9
-
10-12 not classified not classified -
Dodecylbenzenesulfonic acid, sodium salt 68411-30-3
285-600-2
-
7.5-8.5 Acute Tox. 4; H302
Skin Irrit. 2; H315
Eye Dam. 1; H318
Xn; R22
Xi; R38-41
-
Sodium silicate 1344-09-8
215-687-4
-
4.5-5.5 Skin Irrit. 2; H315
Eye Irrit. 2; H319
STOT SE 3; H335
Xi; R36/37/38 01-2119448725-31-0029
Fatty acids, C16-18, sodium salts 68424-38-4
270-299-2
-
2.9-3.1 not classified not classified -

4. First aid measures

4.1. Description of first aid measures

General measures

Never give anything by mouth to an unconscious person. Place patient stably in side position for transportation.

Inhalation

Remove patient to fresh air-move out of dangerous area. If symptoms persist seek medical attention.

Skin contact

Take off all contaminated clothing. Wash thoroughly with plenty of water and soap! If feeling unwell seek medical help.

Eye contact

Immediately flush eyes with running water, keeping eyelids open. If irritation persist, seek professional medical attention.

Ingestion

Do not induce vomiting. Rinse mouth with water. Consult a physician. Show the physician the Safety Data Sheet or label.

4.2. Most important symptoms and effects, both acute and delayed

Inhalation

Can cause irritation of respiratory system.

Skin contact

Itching, redness, pain.

Eye contact

Contact with eyes can cause irritation (redness, tearing, pain).

Ingestion

Irritates mucous membranes in the mouth, throat, esophagus and in gastrointestinal area.
May cause nausea/vomiting and diarrhea.

4.3. Indication of any immediate medical attention and special treatment needed

-

5. Firefighting measures

5.1. Extinguishing media

Suitable extinguishing media

Carbon dioxide. Dry chemical powder. Water spray. Alcohol resistant foam.

Unsuitable extinguishing media

Full water jet.

5.2. Special hazards arising from the substance or mixture

Hazardous combustion products

-

5.3. Advice for firefighters

Protective actions

In case of fire do not breathe fumes/gases.

Special protective equipment for fire-fighters

Fire-fighters should wear appropriate protective clothing for fire-fighters (including helmets, protective boots and gloves) (EN 469) and self-contained breathing apparatus (SCBA) with a full face-piece (EN 137) .

6. ACCIDENTAL RELEASE MEASURES

6.1. Personal precautions, protective equipment and emergency procedures

6.1.1. For non-emergency personnel

Protective equipment

Use personal protective equipment (Section 8). Avoid contact with the eyes and skin.

Emergency procedures

Ensure adequate ventilation.

6.1.2. For emergency responders

-

6.2. Environmental precautions

If accidental entry into water or ground occurs, inform responsible authorities.

6.3. Methods and material for containment and cleaning up

6.3.1. For containment

-

6.3.2. For cleaning up

Collect in a suitable container and dispose according to regulations.

6.3.3. Other information

-

6.4. Reference to other sections

See also sections 8 and 13.

7. Handling and storage

7.1. Precautions for safe handling

7.1.1. Protective measures

Measures to prevent fire

Ensure adequate ventilation.

Measures to prevent aerosol and dust generation

Prevent dusting.

Measures to protect the environment

-

7.1.2. Advice on general occupational hygiene

Use good personal hygiene practices-wash hands at breaks and when done working with material. Do not eat, drink or smoke while working. Avoid contact with skin and eyes. Do not breathe dust.

7.2. Conditions for safe storage, including any incompatibilities

7.2.1. Technical measures and storage conditions

Keep in cool and well ventilated area. Keep away from food, drink and animal feedingstuffs.

7.2.2. Packaging materials

-

7.2.3. Requirements for storage rooms and vessels

-

7.2.4. Storage class

-

7.2.5. Further information on storage conditions

-

7.3. Specific end use(s)

Recommendations

-

Industrial sector specific solutions

-

8. Exposure controls/personal protection

8.1. Control parameters

8.1.1. Occupational Exposure limit values

Chemical name (CAS) Limit values Short-term exposure limit Remarks Biological Tolerance Values
ml/m3
(ppm)
mg/m3
ml/m3
(ppm)
mg/m3
Sodium silicate (1344-09-8) 10 UK, DE, IUCLID

Exposure limit values (IUCLID)

Chemical name value interval x time Type
Zeolite (1318-02-1) 0,15 mg/m3 18 mg/m3 (1 x 8h) MAK (DE)
Sodium silicate (1344-09-8) 10 mg/m3 10 mg/m3 (6 x 8h) OES (UK)
Dodecylbenzenesulfonic acid, sodium salt (68411-30-3) 1000 ppm 700 ml/m3 (4 x 30min) MAK (DE)
Fatty acids, C16-18, sodium salts (68424-38-4) 6 mg/m3 340 mg/m3 (8 x 5min) MAK (DE)
Sodium sulphate (7757-82-6) 6 mg/m3 2 mg/m3 (4 x 10min) MAK (DE)
Source: IUCLID (For information only)

8.1.2. Information on monitoring procedures

BS EN 14042:2003 Title Identifier: Workplace atmospheres. Guide for the application and use of procedures for the assessment of exposure to chemical and biological agents.

8.1.3. DNEL values

For components

Chemical name Type exp. route exp. frequency value Remark
Sodium sulphate (7757-82-6) Worker inhalation long term (systemic effects) 20 mg/m³
Sodium sulphate (7757-82-6) Worker inhalation long term (local effects) 20 mg/m³
Sodium sulphate (7757-82-6) Consumer inhalation long term (systemic effects) 12 mg/m³
Sodium sulphate (7757-82-6) Consumer inhalation long term (local effects) 12 mg/m³
Dodecylbenzenesulfonic acid, sodium salt (68411-30-3) Worker dermal long term (systemic effects) 170 mg/kg
Dodecylbenzenesulfonic acid, sodium salt (68411-30-3) Worker inhalation long term (systemic effects) 12 mg/m³
Dodecylbenzenesulfonic acid, sodium salt (68411-30-3) Consumer oral long term (systemic effects) 0,85 mg/kg
Dodecylbenzenesulfonic acid, sodium salt (68411-30-3) Consumer dermal long term (systemic effects) 85 mg/kg
Dodecylbenzenesulfonic acid, sodium salt (68411-30-3) Consumer inhalation long term (systemic effects) 3 mg/m³
Dodecylbenzenesulfonic acid, sodium salt (68411-30-3) Worker inhalation long term (local effects) 12 mg/m³
Dodecylbenzenesulfonic acid, sodium salt (68411-30-3) Consumer inhalation long term (local effects) 3 mg/m³
Sodium silicate (1344-09-8) Worker dermal long term (systemic effects) 1,59 mg/kg bw/day
Sodium silicate (1344-09-8) Worker inhalation long term (systemic effects) 5,61 mg/m³
Sodium silicate (1344-09-8) Consumer dermal long term (systemic effects) 0,8 mg/kg bw/day
Sodium silicate (1344-09-8) Consumer inhalation long term (systemic effects) 1,38 mg/m³
Sodium silicate (1344-09-8) Consumer oral long term (systemic effects) 0,8 mg/kg bw/day

8.1.4. PNEC values

For components

Chemical name exp. route value Remark
Sodium sulphate (7757-82-6) fresh water 11,09 mg/L
Sodium sulphate (7757-82-6) marine water 1,109 mg/L
Sodium sulphate (7757-82-6) water treatment plant 800 mg/L
Sodium sulphate (7757-82-6) fresh water sediment 40,2 mg/kg
Sodium sulphate (7757-82-6) marine water sediment 4,02 mg/kg
Sodium sulphate (7757-82-6) soil 1,54 mg/kg
Sodium sulphate (7757-82-6) water, intermittent release 17,66 mg/L
Dodecylbenzenesulfonic acid, sodium salt (68411-30-3) fresh water 0,268 mg/L
Dodecylbenzenesulfonic acid, sodium salt (68411-30-3) marine water 0,0268 mg/L
Dodecylbenzenesulfonic acid, sodium salt (68411-30-3) soil 35 mg/kg
Dodecylbenzenesulfonic acid, sodium salt (68411-30-3) fresh water sediment 8,1 mg/kg
Dodecylbenzenesulfonic acid, sodium salt (68411-30-3) marine water sediment 8,1 mg/kg
Dodecylbenzenesulfonic acid, sodium salt (68411-30-3) water treatment plant 2,43 mg/L
Dodecylbenzenesulfonic acid, sodium salt (68411-30-3) water, intermittent release 0,00167 mg/L
Sodium silicate (1344-09-8) fresh water 7,5 mg/L
Sodium silicate (1344-09-8) marine water 1 mg/L
Sodium silicate (1344-09-8) water, intermittent release 7,5 mg/L
Sodium silicate (1344-09-8) fresh water sediment 7,5 mg/kg
Sodium silicate (1344-09-8) water treatment plant 348 mg/L
Sodium silicate (1344-09-8) food chain 348 mg/kg oral

8.2. Exposure controls

8.2.1. Appropriate engineering control

Substance/mixture related measures to prevent exposure during identified uses

Use good personal hygiene practices-wash hands at breaks and when done working with material.

Technical measures to prevent exposure

Provide good ventilation and local exhaust in the area with increased concentration.

8.2.2. Personal protective equipment

Eye and face protection

Tight fitting protective goggles (EN 166).

Hand protection

Protective gloves (EN 374).

Skin protection

Cotton protective clothing (EN ISO 13688) and shoes that cover the entire foot (EN ISO 20345).

Respiratory protection

In case of insufficient ventilation wear suitable respiratory protection. Mask with dust filter (P2) or FFP2(EN 149).

Thermal hazards

-

8.2.3. Environmental exposure controls

-

9. PHYSICAL AND CHEMICAL PROPERTIES

9.1. Information on basic physical and chemical properties

- Physical state: solid
- Colour: white
- Odour: None

Important health, safety and environmental information

- pH 10,5 – 11, conc. 1 %
- Melting point/Freezing point No information
- Initial boiling point/boiling range No information
- Flashpoint No information
- Evaporation rate No information
- Ignition temperature No information
- Explosion limits (vol%) No information
- Vapour pressure No information
- Vapour density No information
- Density Bulk density:
350 – 450 kg/m3
- Solubility Water:
Soluble
- Partition coefficient No information
- Auto-ignition temperature No information
- Decomposition temperature No information
- Viscosity No information
- Explosive properties Product is not explosive.
- Oxidising properties No information

9.2. Other information

- Remarks:

10. STABILITY AND REACTIVITY

10.1. Reactivity

-

10.2. Chemical stability

Product is stable under normal conditions according to handling and storage.

10.3. Possibility of hazardous reactions

-

10.4. Conditions to avoid

No special precautions required. Consider the directions for use and storage.

10.5. Incompatible materials

No specific incompatible substances.

10.6. Hazardous decomposition products

Under normal use conditions no hazardous decomposition products expected. In case of fire/explosion vapours dangerous for health are spread.

11. Toxicological information

11.1. Information on toxicological effects

11.1.1. Acute toxicity

For components
Chemical name exp. route Type species Time value Method Remark
Sodium sulphate (7757-82-6) oral LD50 rat 2001 mg/kg OECD 401
Sodium sulphate (7757-82-6) inhalation LC50 rat 4 h 5,01 mg/l OECD 436
Sodium sulphate (7757-82-6) oral ATE 2001 mg/kg bw
Sodium sulphate (7757-82-6) inhalation ATE 4 h 5,01 mg/l
Dodecylbenzenesulfonic acid, sodium salt (68411-30-3) oral LD50 rat 1260 mg/kg
Sodium silicate (1344-09-8) oral LD50 rat > 2000 mg/kg
(1318-02-1)* oral LD50 dog 1000 – 31600 mg/kg
(1318-02-1)* oral LD50 rat 5000 – 31600 mg/kg
(1344-09-8)* oral LD50 mouse 770 – 39800 mg/kg
(1344-09-8)* oral LD50 rat 1153 – 39800 mg/kg
(68411-30-3)* oral LD50 rat 650 – 820 mg/kg
(68411-30-3)* oral LD50 rat 1207 – 1767 mg/kg
(68424-38-4)* oral LD50 rat 2000 – 15000 mg/kg
(68424-38-4)* oral LD50 rat 5000 – 15000 mg/kg
(7757-82-6)* oral LD50 mouse 193 – 1500 mg/kg
(7757-82-6)* oral LD50 mouse 5989 – 1500 mg/kg
(68424-38-4)* dermal LD50 rabbit 2 – 1200 mg/kg
(68424-38-4)* dermal LD50 rabbit 2000 – 1200 mg/kg
(1318-02-1)* dermal LD50 rabbit 2000 – 2000 mg/kg
(1318-02-1)* inhalation LC50 rat 1 h 2 – 18 mg/l
(1318-02-1)* inhalation LC50 rat 1 h 2 – 18 mg/l
(68424-38-4)* inhalation LC50 rat 4 h 5 – 300000 mg/l
(1344-09-8)* inhalation LC50 rat 1 h 18 – 18 mg/l
* Source: IUCLID (For information only)

11.1.2. Skin corrosion/irritation, serious eye damage/irritation

For components
Chemical name exp. route species Time result Method Remark
Dodecylbenzenesulfonic acid, sodium salt (68411-30-3) dermal rabbit Irritating to the skin. OECD 404
Dodecylbenzenesulfonic acid, sodium salt (68411-30-3) eyes rabbit Danger of serious eye injury. OECD 405
Sodium silicate (1344-09-8) dermal Contact with skin causes irritation.
Sodium silicate (1344-09-8) eyes Severely irritating; causes tearing
Sodium silicate (1344-09-8) inhalation Causes respiratory tract irritation.

11.1.3. Respiratory or skin sensitisation

For components
Chemical name exp. route species Time result Method Remark
Dodecylbenzenesulfonic acid, sodium salt (68411-30-3) - Guinea pig Non sensitizing. OECD 406
Sodium silicate (1344-09-8) dermal mouse Non sensitizing. OECD 429

11.1.4. Carcinogenicity, Mutagenicity, Reproductive toxicity

Carcinogenicity

- For components
Chemical name exp. route Type species Time value result Method Remark
Dodecylbenzenesulfonic acid, sodium salt (68411-30-3) Not carcinogenic.
Sodium silicate (1344-09-8) Not carcinogenic.
(Germ cell) mutagenicity

- For components
Chemical name Type species Time result Method Remark
Dodecylbenzenesulfonic acid, sodium salt (68411-30-3) in-vitro Mutagenicity Non-mutagenic
Dodecylbenzenesulfonic acid, sodium salt (68411-30-3) in-vivo Mutagenicity Non-mutagenic
Sodium silicate (1344-09-8) Not mutagenic.
Reproductive toxicity

- For components
Chemical name Reproductive toxicity type Type species Time value result Method Remark
Dodecylbenzenesulfonic acid, sodium salt (68411-30-3) Reproductive toxicity NOAEL (P) rat 2 years 350 mg/kg bw/day oral
Dodecylbenzenesulfonic acid, sodium salt (68411-30-3) Reproductive toxicity NOAEL (F1/F2) rat 2 years 350 mg/kg bw/day oral
Dodecylbenzenesulfonic acid, sodium salt (68411-30-3) Not toxic for reproduction.
Dodecylbenzenesulfonic acid, sodium salt (68411-30-3) Teratogenicity NOAEL rat 20 days 300 mg/kg bw/day oral
Dodecylbenzenesulfonic acid, sodium salt (68411-30-3) Teratogenicity NOAEL rat (female) 20 days 300 mg/kg bw/day oral
Dodecylbenzenesulfonic acid, sodium salt (68411-30-3) Teratogenicity NOAEL mouse 20 days 300 mg/kg bw/day oral
Dodecylbenzenesulfonic acid, sodium salt (68411-30-3) Teratogenicity NOAEL mouse 20 days 2 mg/kg bw/day oral
Dodecylbenzenesulfonic acid, sodium salt (68411-30-3) - not teratogenic
Sodium silicate (1344-09-8) Not toxic for reproduction.
Summary of evaluation of the CMR properties

No information

11.1.5. STOT - single and repeated exposure

For components
Chemical name exp. route Type species Time organ value result Method Exposure Remark
Dodecylbenzenesulfonic acid, sodium salt (68411-30-3) - - Not reported to have any specific target organ general toxicity repeat exposure effects. Repeated exposure
Dodecylbenzenesulfonic acid, sodium salt (68411-30-3) - - Not reported to have any specific target organ general toxicity single exposure effects. Single exposure
Dodecylbenzenesulfonic acid, sodium salt (68411-30-3) oral NOAEL rat 28 days blood, liver, heart, thymus 125 mg/kg bw/day increase in body weight, diarrhea Repeated exposure literature
Dodecylbenzenesulfonic acid, sodium salt (68411-30-3) oral LOAEL rat 28 days blood, liver, heart, thymus 250 mg/kg bw/day increase in body weight, diarrhea Repeated exposure literature
Dodecylbenzenesulfonic acid, sodium salt (68411-30-3) - NOAEL rat 6 months Blood, Kidney 40 mg/kg bw/day increase in body weight, diarrhea Repeated exposure literature
Dodecylbenzenesulfonic acid, sodium salt (68411-30-3) - LOAEL rat 6 months Blood, Kidney 115 mg/kg bw/day increase in body weight, diarrhea Repeated exposure literature
Dodecylbenzenesulfonic acid, sodium salt (68411-30-3) Oral (drinking water) NOAEL rat 9 months blood 85 mg/kg bw/day weight gain Repeated exposure literature
Dodecylbenzenesulfonic acid, sodium salt (68411-30-3) Oral (drinking water) LOAEL rat 9 months blood 145 mg/kg bw/day weight gain Repeated exposure literature
Sodium silicate (1344-09-8) oral - May cause nausea/vomiting and diarrhea Single exposure

11.1.6. Aspiration hazard

No information

12. Ecological information

12.1. Toxicity

12.1.1. Acute (short-term) toxicity

For components
Substance (CAS Nr.) Type Value Exposure time Species Organism Method Remark
Sodium sulphate (7757-82-6) LC50 7960 mg/L 96 h fish Pimephales promelas
EC50 1766 mg/L 48 h crustacea Daphnia magna
EC50 1900 mg/L 72 h algae Nitzschia linearis
Dodecylbenzenesulfonic acid, sodium salt (68411-30-3) LC50 1,67 mg/L 96 h fish Lepomis macrochirus
EC50 2,9 mg/L 48 h crustacea Daphnia magna
EC50 29 mg/L 96 h algae Selenastrum capricornutum
Sodium silicate (1344-09-8) LC50 3158 – 478 mg/L 96 h fish
LC50 301 – 478 mg/L 96 h fish
EC50 216 – 18000 mg/L 96 h algae
Acute toxicity of ingredients (IUCLID)

CAS Species
Fish Daphnia Algae
68411-30-3 LC50/96h: 0 - 1 mg/l *
LC50/96h: 0 - 7 mg/l *
EC50/48h: 0 - 100 mg/l *
EC50/48h: 1 - 9 mg/l *
LC50/14days: 1 - 125 mg/l *
LC50/28days: 1 - 125 mg/l *
68424-38-4 LC50/96h: 46 - 118 mg/l *
LC50/96h: 54 - 118 mg/l *
EC50/24h: 40 - 6 mg/l *
EC50/72h: 86 - 6 mg/l *
LC50/72h: 10 - 50 mg/l *
LC50/96h: 120 - 50 mg/l *
7757-82-6 LC50/96h: 120 - 5350000 mg/l *
LC50/96h: 120 - 14500 mg/l *
EC50/48h: 4 - 120 micrograms/l *
EC50/24h: 4 - 120 micrograms/l *
LC50/5days: 64 - 16 micrograms/l *
LC50/20days: 64 - 16 mg/l *
1344-09-8 LC50/96h: 301 - 478 mg/l *
LC50/96h: 3185 - 478 mg/l *
EC50/96h: 160 - 18000 mg/l *
EC50/96h: 216 - 18000 mg/l *
LC50/72h: 10000 - 320 mg/l *
LC50/20days: 64 - 16 mg/l *
1318-02-1 LC50/28days: 1800 - 3200 mg/l *
LC50/96h: 1800 - 3200 mg/l *
EC50/48h: 0 - 50000 mg/l *
EC50/24h: 0 - 50000 mg/l *
LC50/4days: 18 - 320 mg/l *
LC50/96h: 65 - 75 mg/l *
 Source: IUCLID (For information only)

12.1.2. Chronic (long-term) toxicity

For components
Substance (CAS Nr.) Type Value Exposure time Species Organism Method Remark
Sodium sulphate (7757-82-6) NOEC 8000 mg/l crustacea
Dodecylbenzenesulfonic acid, sodium salt (68411-30-3) NOEC 0,1 – 1 mg/l 28 days fish Lepomis macrochirus Growth rate, literature value

12.2. Persistence and degradability

12.2.1. Abiotic degradation, physical- and photo-chemical elimination

No information

12.2.2. Biodegradation

For components
Substance (CAS Nr.) Organism Rate Time Evaluation Method Remark
Dodecylbenzenesulfonic acid, sodium salt (68411-30-3) aerobic 89 % 29 days 34,3 mg/l
Sodium silicate (1344-09-8) - not readily biodegradable

12.3. Bioaccumulative potential

12.3.1. Partition coefficient

For components
Substance (CAS Nr.) Media value Temperature pH Concentration Method
Sodium sulphate (7757-82-6) Octanol-water (log Pow) -4,38
Dodecylbenzenesulfonic acid, sodium salt (68411-30-3) Log Pow 3,32

12.3.2. Bioconcentration factor (BCF)

For components
Substance (CAS Nr.) species organism value Duration Evaluation Method Remark
Sodium sulphate (7757-82-6) BCF 0,5
Dodecylbenzenesulfonic acid, sodium salt (68411-30-3) BCF 2

12.4. Mobility in soil

12.4.1. Known or predicted distribution to environmental compartments

No information

12.4.2. Surface tension

No information

12.4.3. Adsorption/Desorption

For components
Substance (CAS Nr.) Organism Criterion value Evaluation Method Remark
Dodecylbenzenesulfonic acid, sodium salt (68411-30-3) Soil log KOC 3,32

12.5. Results of PBT and vPvB assessment

The components in this formulation do not meet the criteria for classification as PBT or vPvB.

12.6. Other adverse effects

No information

12.7. Additional information

For components

Substance: Dodecylbenzenesulfonic acid, sodium salt

Low bioaccumulation potential.

Substance: Sodium silicate

Do not allow to reach ground water, water bodies or sewage systems.

13. Disposal considerations

13.1. Waste treatment methods

13.1.1. Product / Packaging disposal

Waste chemical

Disposal must be made according to official regulations: to leave it to authorized collector/remover/transformer of hazardous waste.

Packaging

Completely emptied containers leave to approved waste disposal authorities in charge.

13.1.2. Waste treatment-relevant information

-

13.1.3. Sewage disposal-relevant information

-

13.1.4. Other disposal recommendations

-

14. Transport information

14.1. UN number

not applicable

14.2. UN proper shipping name

ADR, RID, IMDG, ADN, IATA: Not dangerous according to transport regulations.

14.3. Transport hazard class(es)

not applicable

14.4. Packing group

not applicable

14.5. Environmental hazards

NO

14.6. Special precautions for user

not applicable

14.7. Transport in bulk according to Annex II of Marpol and the IBC Code

not applicable

15. Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture

- Regulation (EC) No 1907/2006 concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH)(including last amendment Commission Regulation (EU) 2015/830)

- Regulation (EC) No 1272/2008 on classification, labelling and packaging of substances and mixtures

15.1.1. Information according 2004/42/EC about limitation of emissions of volatile organic compounds (VOC-guideline)

not applicable

15.2. Chemical Safety Assessment

No Chemical Safety Assessment has been carried out for this substance/mixture by the supplier.

16. Other information

Indication of changes

New classification of the mixture according to CLP (EC) No. 1272/2008

Key literature references and sources for data

PREMIX B3, Silkem, d. o. o., Version 1.0

List of relevant H phrases

H302  Harmful if swallowed.
H315  Causes skin irritation.
H318  Causes serious eye damage.
H319  Causes serious eye irritation.
H335  May cause respiratory irritation.

The information of this SDS is based on the present state of our knowledge and meets the requirements of EU and national laws. The user’s working conditions however, are beyond our knowledge and control. The product is not to be used for purposes other than those specified under section 1 without a written permission. It remains the responsibility of the user to ensure that the necessary steps are taken to meet the laws and regulations. Handling of the product may only be done by people above 18 years of age, who are satisfactorily informed of how to do the work, the hazardous properties and necessary safety precautions. The information given in this SDS is to describe the product only in terms of health and safety requirements and should not, therefore, be construed as guaranteeing specific properties.