SAFETY DATA SHEET according to Regulation 1907/2006
Creation date: 5.5.2017
Zeolite (CAS: 1318-02-1, EC: 215-283-8)
SILKEM, d. o. o.
+386 2 7991 208 (7h - 15h)
According to the regulation, the product is not classified as hazardous.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P304 + P341 IF INHALED: If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing.
Special hazards are not known or expected.
|%||Classification according to Regulation (EC)
No 1272/2008 (CLP)
|Specific Conc. Limits||Classification according to directive 67/548/EEC or 99/45/EC||REACH Registration No.|
|>99||not classified||not classified||01-2119429034-49-0017|
For substances see 3.1.
When in doubt or if feeling unwell seek medical assistance.
Remove patient to fresh air - move out of dangerous area. Ventilate the premises. Inhale fresh air. If symptoms develop and persist, seek medical attention.
Product is not irritating to the skin. Areas of the body that have come into contact with the product must be rinsed immediately with plenty of running water.
If substance has got into eyes, immediately wash out with plenty of water. If irritation persists, seek professional medical attention.
In case of doubt or if feeling unwell seek medical help.
Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Carbon dioxide. Dry chemical powder. Water spray. Alcohol resistant foam.
Full water jet.
In case of fire or heating do not breathe fumes/vapours.
In case of fire: Wear suitable respiratory equipment - self-contained breathing apparatus and full protective equipment.
Contaminated firefighting water must be disposed of in accordance with the regulations; do not allow to reach the sewage system.
Use personal protective equipment (Section 8). Thoroughly clean hands after use or contact.
Wear appropriate personal protective equipment!
Not necessary. If accidental large entry into water or ground occurs, inform responsible authorities.
Pick up mechanically and remove it in accordance with regulation.
See also Sections 8 and 13.
Take precautionary measures against static discharges.
Prevent dusting. Ensure good ventilation and extraction.
Avoid release to the environment.
Avoid contact with skin and eyes. Use personal protective equipment. Do not eat or drink while working.
Keep in well closed containers. Keep in a dry place. Keep container in a well ventilated place. Keep away from food, drink and animal feeding stuffs. This product is hygroscopic.
|Name (CAS)||Limit values||Short-term exposure limit||Remarks||Biological Tolerance Values|
|Zeolite (1318-02-1)||10||WEL long-term, inhalable|
|Zeolite (1318-02-1)||4||WEL long-term, respirable|
BS EN 14042:2003 Workplace atmospheres. Guide for the application and use of procedures for the assessment of exposure to chemical and biological agents. BS EN 482:2012+A1:2015 Workplace exposure. General requirements for the performance of procedures for the measurement of chemical agents. BS EN 689:2018 Workplace exposure. Measurement of exposure by inhalation to chemical agents. Strategy for testing compliance with occupational exposure limit values.
|Name||Type||Exposure route||Exposure frequency||Value||Remark|
|Zeolite (1318-02-1)||Worker||inhalation||long term ()||3 mg/m³|
|Zeolite (1318-02-1)||Worker||dermal||long term ()||2,5 mg/kg bw/day|
|Zeolite (1318-02-1)||fresh water||3,2 mg/L|
|Zeolite (1318-02-1)||marine water||0,32 mg/L|
|Zeolite (1318-02-1)||soil||600 mg/kg dw|
Use good personal hygiene practices – wash hands at breaks and when done working with material. Handle in accordance with good industrial hygiene and safety practice.
Keep eyewash bottles or personal eyewash units available.
Provide good ventilation and local exhaust in areas with increased concentration.
Safety glasses with side protection (EN 166).
Protective gloves (EN 374).
Cotton protective clothing and shoes that cover the entire foot (EN ISO 20345).
Not needed under normal use and adequate ventilation. In case of insufficient ventilation wear mask with filter P2.
|-||pH||11 – 12|
|-||Melting point/freezing point||No information.|
|-||Initial boiling point/boiling range||No information.|
|-||Flash point||No information.|
|-||Evaporation rate||No information.|
|-||Flammability (solid, gas)||No information.|
|-||Explosion limits (vol%)||No information.|
|-||Vapour pressure||No information.|
|-||Vapour density||No information.|
< 0,5 g/cm3
|-||Partition coefficient||No information.|
|-||Auto-ignition temperature||No information.|
|-||Decomposition temperature||No information.|
|-||Explosive properties||No information.|
|-||Oxidising properties||No information.|
Stable under normal conditions.
Product is stable under normal conditions.
The product is stable under recommended storage and handling conditions.
No special precautions required. Consider the directions for use and storage. Protect from moisture and water - keep in dry place.
Under normal use conditions no hazardous decomposition products are expected.
|For product||inhalation||LC50||rat||4 h||18,3 mg/l||dust/aerosol|
|For product||dermal||LD50||rabbit||2000 mg/kg|
|For product||oral||LD50||rat||10000 mg/kg|
|Zeolite (1318-02-1)||oral||LD50||rat||5000 – 31600 mg/kg|
|Zeolite (1318-02-1)||-||Non sensitising.|
|Name||Reproductive toxicity type||Type||Species||Time||Value||Result||Method||Remark|
|EC50||560 – 1000 mg/L||72 h||algae|
|LC50||1800 – 3200 mg/L||96 h||fish|
|Substance (CAS Nr.)||Type||Value||Exposure time||Species||Organism||Method||Remark|
|Zeolite (1318-02-1)||EC50||> 100 mg/L||48 h||daphnia|
|LC50||> 680 mg/L||96 h||fish|
|EC50||> 300 mg/L||96 h||algae|
|Substance (CAS Nr.)||Environment||Type / Method||Half Time||Evaluation||Method||Remark|
|Zeolite (1318-02-1)||water||hydrolysis||The hydrolysis rate is accelerated at high and low pH and is retarded by high concentrations of hydrolysis products|
|Zeolite (1318-02-1)||water||hydrolysis||The hydrolytic reaction results in the formation of natural aluminosilicates such that natural constituents of soil, sediment and water are formed|
|Substance (CAS Nr.)||species||Organism||Value||Duration||Evaluation||Method||Remark|
|Zeolite (1318-02-1)||-||Does not bioaccumulate.|
|Substance (CAS Nr.)||Type||Criterion||Value||Evaluation||Method||Remark|
|Zeolite (1318-02-1)||Soil||Not amenable to biodegradation. In practice zeolite improve nutrient balance in soil.|
Avoid release to the environment.
Waste should be handled in accordance with local or national regulations.
Deliver completely emptied containers to approved waste disposal authorities.
15 01 02 - plastic packaging
ADR, RID, IMDG, ADN, IATA: Not dangerous according to transport regulations.
- Regulation (EC) No 1907/2006 concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH)(including last amendment Commission Regulation (EU) 2015/830)
- Regulation (EC) No 1272/2008 on classification, labelling and packaging of substances and mixtures
No Chemical Safety Assessment has been carried out for this substance/mixture by the supplier.
ATE - Acute Toxicity Estimate
ADR - European Agreement concerning the International Carriage of Dangerous Goods by Road
ADN - European Agreement concerning the International Carriage of Dangerous Goods by Inland Waterways
CEN - European Committee for Standardisation
C&L - Classification and Labelling
CLP - Classification Labelling Packaging Regulation; Regulation (EC) No 1272/2008
CAS# - Chemical Abstracts Service number
CMR - Carcinogen, Mutagen, or Reproductive Toxicant
CSA - Chemical Safety Assessment
CSR - Chemical Safety Report
DMEL - Derived Minimal Effect Level
DNEL - Derived No Effect Level
DPD - Dangerous Preparations Directive 1999/45/EC
DSD - Dangerous Substances Directive 67/548/EEC
DU - Downstream User
EC - European Community
ECHA - European Chemicals Agency
EC-Number - EINECS and ELINCS Number (see also EINECS and ELINCS)
EEA - European Economic Area (EU + Iceland, Liechtenstein and Norway)
EEC - European Economic Community
EINECS - European Inventory of Existing Commercial Substances
ELINCS - European List of notified Chemical Substances
EN - European Standard
EQS - Environmental Quality Standard
EU - European Union
Euphrac - European Phrase Catalogue
EWC - European Waste Catalogue (replaced by LoW – see below)
GES - Generic Exposure Scenario
GHS - Globally Harmonized System
IATA - International Air Transport Association
ICAO-TI - Technical Instructions for the Safe Transport of Dangerous Goods by Air
IMDG - International Maritime Dangerous Goods
IMSBC - International Maritime Solid Bulk Cargoes
IT - Information Technology
IUCLID - International Uniform Chemical Information Database
IUPAC - International Union for Pure Applied Chemistry
JRC - Joint Research Centre
Kow - octanol-water partition coefficient
LC50 - Lethal Concentration to 50 % of a test population
LD50 - Lethal Dose to 50% of a test population (Median Lethal Dose)
LE - Legal Entity
LoW - List of Wastes (see http://ec.europa.eu/environment/waste/framework/list.htm)
LR - Lead Registrant
M/I - Manufacturer / Importer
MS - Member States
MSDS - Material Safety Data Sheet
OC - Operational Conditions
OECD - Organization for Economic Co-operation and Development
OEL - Occupational Exposure Limit
OJ - Official Journal
OR - Only Representative
OSHA - European Agency for Safety and Health at work
PBT - Persistent, Bioaccumulative and Toxic substance
PEC - Predicted Effect Concentration
PNEC(s) - Predicted No Effect Concentration(s)
PPE - Personal Protection Equipment
(Q)SAR - Qualitative Structure Activity Relationship
REACH - Registration, Evaluation, Authorisation and Restriction of Chemicals Regulation (EC) No 1907/2006
RID - Regulations concerning the International Carriage of Dangerous Goods by Rail
RIP - REACH Implementation Project
RMM - Risk Management Measure
SCBA - Self-Contained Breathing Apparatus
SDS - Safety data sheet
SIEF - Substance Information Exchange Forum
SME - Small and Medium sized Enterprises
STOT - Specific Target Organ Toxicity
(STOT) RE - Repeated Exposure
(STOT) SE - Single Exposure
SVHC - Substances of Very High Concern
UN - United Nations
vPvB - Very Persistent and Very Bioaccumulative