SAFETY DATA SHEET according to Regulation 1907/2006
Product name:

ZP-4A

Creation date: 27.3.2008 · Revision: 14.6.2016 · Version: 2

1. Identification of the substance/mixture and of the company/undertaking


chemius.net/JF569

1.1. Product identifier

Product name

ZP-4A

Synonyms

Zeolit / Zeolite / Zeolith: ZP-4A, ZP-4A-TSR, ZP-4A-MS, ZP-4AM (EC-No. 930-915-9)

Chemical name

Zeolite (CAS: 1318-02-1, EC: 215-283-8)

REACH Registration number

01-2119429034-49-0017

1.2. Relevant identified uses of the substance or mixture and uses advised against

Use

Industrial use

Uses advised against

No information

1.3. Details of the supplier of the safety data sheet

Manufacturer

SILKEM d.o.o
Tovarniška cesta 10, 2325 Kidričevo, Slovenia
Tel: +386 2 7991 200
Fax: +386 2 7991 230
e-mail: info@silkem.si

Supplier

SILKEM, d. o. o.
Address: Tovarniška cesta 10, 2325 Kidričevo, Slovenia
Tel.: +386 2 7991 200
Fax: +386 2 7991 230
e-mail: info@silkem.si

1.4. Emergency telephone number

Emergency

112

Supplier

+386 2 7991 208 (7h - 15h)

2. Hazards identification

2.1 Classification of the substance or mixture

Classification according to Reg. 1272/2008

According to the regulation, the chemical is not classified as hazardous.

2.2 Label elements

2.2.1. Labelling according to Regulation (EC) No 1272/2008 [CLP]

Pictograms not applicable according to Regulation 1272/2008.

2.2.2. Contains:

-

2.2.3. Special provisions

Special hazards are not known or expected.

2.3. Other hazards

No information

3. Composition/information on ingredients

3.1. Substances

Chemical name CAS
EC
Index
% Classification according to Regulation (EC) No 1272/2008 [CLP] Classification according to directive 67/548/EEC or 99/45/EC REACH reg. number
Zeolite 1318-02-1
215-283-8
-
>99 not classified not classified 01-2119429034-49-0017

3.2. Mixtures

For substances see 3.1.

4. First aid measures

4.1. Description of first aid measures

General measures

When in doubt or if symptoms do not disappear seek medical help.

Inhalation

Remove patient to fresh air-move out of dangerous area. Ventilate the premises. Inhale fresh air. If symptoms persist seek medical attention.

Skin contact

Product is not irritating to the skin. Areas of the body that have come into contact with the product must be rinsed with water.

Eye contact

If substance has got into eyes, immediately wash out with plenty of water. If irritation persist, seek professional medical attention.

Ingestion

In case of doubt or if feeling unwell seek medical help.

4.2. Most important symptoms and effects, both acute and delayed

Inhalation

-

Skin contact

-

Eye contact

-

Ingestion

-

4.3. Indication of any immediate medical attention and special treatment needed

-

5. Firefighting measures

5.1. Extinguishing media

Suitable extinguishing media

Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Carbon dioxide. Dry chemical powder. Water spray. Alcohol resistant foam.

Unsuitable extinguishing media

Full water jet.

5.2. Special hazards arising from the substance or mixture

Hazardous combustion products

-

5.3. Advice for firefighters

Protective actions

In case of fire or heating do not breathe fumes/vapours.

Special protective equipment for fire-fighters

In case of fire: Wear suitable respiratory equipment - self-contained breathing apparatus and full protective equipment.

Additional information

Contaminated firefighting water must be disposed of in accordance with the regulations; do not allow to reach the sewage system.

6. ACCIDENTAL RELEASE MEASURES

6.1. Personal precautions, protective equipment and emergency procedures

6.1.1. For non-emergency personnel

Protective equipment

Use personal protective equipment (Section 8). Thoroughly clean hands after use or contact.

Emergency procedures

-

6.1.2. For emergency responders

Wear appropriate personal protective equipment!

6.2. Environmental precautions

Not necessary. If accidental entry into water or ground occurs, inform responsible authorities.

6.3. Methods and material for containment and cleaning up

6.3.1. For containment

-

6.3.2. For cleaning up

Pick up mechanically and remove it in accordance with regulation.

6.3.3. Other information

-

6.4. Reference to other sections

See also sections 8 and 13.

7. Handling and storage

7.1. Precautions for safe handling

7.1.1. Protective measures

Measures to prevent fire

Take precautionary measures against static discharges.

Measures to prevent aerosol and dust generation

Prevent dusting. Ensure good ventilation and extraction.

Measures to protect the environment

Avoid release to the environment.

7.1.2. Advice on general occupational hygiene

Avoid contact with skin and eyes. Use personal protective equipment. Do not eat or drink while working.

7.2. Conditions for safe storage, including any incompatibilities

7.2.1. Technical measures and storage conditions

Keep in well closed containers. Keep in a dry place. Keep container in a well ventilated place. Keep away from food, drink and animal feedingstuffs. This product is hygroscopic.

7.2.2. Packaging materials

-

7.2.3. Requirements for storage rooms and vessels

-

7.2.4. Storage class

-

7.2.5. Further information on storage conditions

-

7.3. Specific end use(s)

Recommendations

-

Industrial sector specific solutions

-

8. Exposure controls/personal protection

8.1. Control parameters

8.1.1. Occupational Exposure limit values

No information

Exposure limit values (IUCLID)

Chemical name value interval x time Type
Zeolite (1318-02-1) 0,15 mg/m3 18 mg/m3 (1 x 8h) MAK (DE)
Zeolite (1318-02-1) 3 mg/m3 18 mg/m3 (1 x 8h) TLV (US)
Source: IUCLID (For information only)

8.1.2. Information on monitoring procedures

BS EN 14042:2003 Title Identifier: Workplace atmospheres. Guide for the application and use of procedures for the assessment of exposure to chemical and biological agents.

8.1.3. DNEL values

No information

8.1.4. PNEC values

No information

8.2. Exposure controls

8.2.1. Appropriate engineering control

Substance/mixture related measures to prevent exposure during identified uses

Use good personal hygiene practices-wash hands at breaks and when done working with material. Handle in accordance with good industrial hygiene and safety practice.

Organisational measures to prevent exposure

Keep eyewash bottles or personal eyewash units available.

Technical measures to prevent exposure

Provide good ventilation and local exhaust in the area with increased concentration.

8.2.2. Personal protective equipment

Eye and face protection

Safety glasses with side protection (EN 166).

Hand protection

Protective gloves (EN 374).

Skin protection

Cotton protective clothing (EN ISO 13688) and shoes that cover the entire foot (EN ISO 20345).

Respiratory protection

Not needed under normal use and adequate ventilation. Mask with dust filter (P2) or FFP2(EN 149).

Thermal hazards

-

8.2.3. Environmental exposure controls

-

9. PHYSICAL AND CHEMICAL PROPERTIES

9.1. Information on basic physical and chemical properties

- Physical state: solid
- Colour: white
- Odour: odourless

Important health, safety and environmental information

- pH 11 – 12
- Melting point/Freezing point No information
- Initial boiling point/boiling range No information
- Flashpoint No information
- Evaporation rate No information
- Ignition temperature No information
- Explosion limits (vol%) No information
- Vapour pressure No information
- Vapour density No information
- Density Density:
> 2 g/cm3
- Solubility Water:
insoluble
- Partition coefficient No information
- Auto-ignition temperature No information
- Decomposition temperature No information
- Viscosity No information
- Explosive properties No information
- Oxidising properties No information

9.2. Other information

- Remarks:

10. STABILITY AND REACTIVITY

10.1. Reactivity

Stable under normal conditions.

10.2. Chemical stability

Product is stable under normal conditions.

10.3. Possibility of hazardous reactions

The product is stable under recommended storage and handling conditions.

10.4. Conditions to avoid

No special precautions required. Consider the directions for use and storage. Protect from moisture and water - keep in dry place.

10.5. Incompatible materials

Not known.

10.6. Hazardous decomposition products

Under normal use conditions no hazardous decomposition products expected.

11. Toxicological information

11.1. Information on toxicological effects

11.1.1. Acute toxicity

For product
exp. route Type species Time value Method Remark
inhalation LC50 rat 4 h 18,3 mg/l dust/aerosol
dermal LD50 rabbit 2000 mg/kg
oral LD50 rat 10000 mg/kg
For components
Chemical name exp. route Type species Time value Method Remark
(1318-02-1)* oral LD50 dog 1000 – 31600 mg/kg
(1318-02-1)* oral LD50 rat 5000 – 31600 mg/kg
(1318-02-1)* dermal LD50 rabbit 2000 – 2000 mg/kg
(1318-02-1)* inhalation LC50 rat 1 h 2 – 18 mg/l
(1318-02-1)* inhalation LC50 rat 1 h 2 – 18 mg/l
* Source: IUCLID (For information only)

11.1.2. Skin corrosion/irritation, serious eye damage/irritation

No information

11.1.3. Respiratory or skin sensitisation

No information

11.1.4. Carcinogenicity, Mutagenicity, Reproductive toxicity

Carcinogenicity

No information

(Germ cell) mutagenicity

No information

Reproductive toxicity

No information

Summary of evaluation of the CMR properties

No information

11.1.5. STOT - single and repeated exposure

No information

11.1.6. Aspiration hazard

No information

12. Ecological information

12.1. Toxicity

12.1.1. Acute (short-term) toxicity

For product
Type Value Exposure time Species Organism Method Remark
EC50 560 – 1000 mg/L 72 h algae
LC50 1800 – 3200 mg/L 96 h fish
Acute toxicity of ingredients (IUCLID)

CAS Species
Fish Daphnia Algae
1318-02-1 LC50/28days: 1800 - 3200 mg/l *
LC50/96h: 1800 - 3200 mg/l *
EC50/48h: 0 - 50000 mg/l *
EC50/24h: 0 - 50000 mg/l *
LC50/4days: 18 - 320 mg/l *
LC50/96h: 65 - 75 mg/l *
 Source: IUCLID (For information only)

12.1.2. Chronic (long-term) toxicity

No information

12.2. Persistence and degradability

12.2.1. Abiotic degradation, physical- and photo-chemical elimination

No information

12.2.2. Biodegradation

No information

12.3. Bioaccumulative potential

12.3.1. Partition coefficient

No information

12.3.2. Bioconcentration factor (BCF)

No information

12.4. Mobility in soil

12.4.1. Known or predicted distribution to environmental compartments

No information

12.4.2. Surface tension

No information

12.4.3. Adsorption/Desorption

No information

12.5. Results of PBT and vPvB assessment

No evaluation.

12.6. Other adverse effects

No information

12.7. Additional information

For product

Avoid release to the environment.

13. Disposal considerations

13.1. Waste treatment methods

13.1.1. Product / Packaging disposal

Waste chemical

Ensure that waste is in compliance with local and national requirements.

Packaging

Completely emptied containers leave to approved waste disposal authorities in charge.

13.1.2. Waste treatment-relevant information

Disposal in accordance with the Rules on the management of waste.

13.1.3. Sewage disposal-relevant information

-

13.1.4. Other disposal recommendations

-

14. Transport information

14.1. UN number

not applicable

14.2. UN proper shipping name

ADR, RID, IMDG, ADN, IATA: Not dangerous according to transport regulations.

14.3. Transport hazard class(es)

not applicable

14.4. Packing group

not applicable

14.5. Environmental hazards

NO

14.6. Special precautions for user

not applicable

14.7. Transport in bulk according to Annex II of Marpol and the IBC Code

not applicable

15. Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture

- Regulation (EC) No 1907/2006 concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH)(including last amendment Commission Regulation (EU) 2015/830)

- Regulation (EC) No 1272/2008 on classification, labelling and packaging of substances and mixtures

15.1.1. Information according 2004/42/EC about limitation of emissions of volatile organic compounds (VOC-guideline)

not applicable

15.2. Chemical Safety Assessment

No Chemical Safety Assessment has been carried out for this substance/mixture by the supplier.

16. Other information

Indication of changes

-

Key literature references and sources for data

MSDS, Silkem d.o.o.,ZEOLIT ZP - 4A, 5.1.2000, version 1

List of relevant H phrases

-

The information of this SDS is based on the present state of our knowledge and meets the requirements of EU and national laws. The user’s working conditions however, are beyond our knowledge and control. The product is not to be used for purposes other than those specified under section 1 without a written permission. It remains the responsibility of the user to ensure that the necessary steps are taken to meet the laws and regulations. Handling of the product may only be done by people above 18 years of age, who are satisfactorily informed of how to do the work, the hazardous properties and necessary safety precautions. The information given in this SDS is to describe the product only in terms of health and safety requirements and should not, therefore, be construed as guaranteeing specific properties.