SAFETY DATA SHEET according to Regulation 1907/2006
Product name:

SALOX®

Creation date: 2.3.2009 · Revision: 6.1.2016 · Version: 2.0

1. Identification of the substance/mixture and of the company/undertaking


chemius.net/ce634

1.1. Product identifier

Product name

SALOX®

Synonyms

Calcined Alumina, Kalzinierte Tonerde, Calcinata allumina, Kalcinirana glinica: 100 (GKM), LS15 (GKT-LS), LS15SG (GKT-LS-SG), S15 (GKT), S15SG (GKT-SG), M-1 (GKE), M-1FG (GKE-MF), M-S1 (GKE-V), M-S1FG (GKE-V-MF; ALO-G4-4G), M-MS1FG, MS 100, MS15 (GKT-MS), S100 (GKM), VLS15 (GKT-VLS), VLS15SG (GKT-VLS-SG)

Name

aluminium oxide (CAS: 1344-28-1, EC: 215-691-6)

REACH Registration number

01-2119529248-35-0068

1.2. Relevant identified uses of the substance or mixture and uses advised against

Relevant identified uses

Raw material in the refractories, ceramics, glass and chemical industries, abrasives, polishing aids; use as an additive, filler, pigment

Uses advised against

No information.

1.3. Details of the supplier of the safety data sheet

Manufacturer

SILKEM, d. o. o.
Address: Tovarniška cesta 10, 2325 Kidričevo, Slovenia
Tel.: +386 2 7991 200
Fax: +386 2 7991 230
e-mail: info@silkem.si

1.4. Emergency telephone number

Emergency

112

Supplier

+386 2 7991 214 (7h - 15h)

2. Hazards identification

2.1 Classification of the substance or mixture

Classification according to Regulation (EC) No 1272/2008 (CLP)

According to the regulation, the chemical is not classified as hazardous.

2.2 Label elements

2.2.1. Labelling according to Regulation (EC) No 1272/2008 [CLP]

P261  Avoid breathing dust/fume/gas/mist/vapours/spray.
P280  Wear protective gloves/protective clothing/eye protection/face protection.
P304 + P340  IF INHALED: Remove person to fresh air and keep comfortable for breathing.

2.2.2. Contains:

-

2.2.3. Special provisions

The product is not classified as dangerous according to regulations.

2.3. Other hazards

No information.

3. Composition/information on ingredients

3.1. Substances

Name CAS
EC
Index
% Classification according to Regulation (EC)
No 1272/2008 (CLP)
Classification according to directive 67/548/EEC or 99/45/EC REACH Registration No.
aluminium oxide 1344-28-1
215-691-6
-
99.3-99.7 not classified not classified 01-2119529248-35-0068

3.2. Mixtures

For substances see 3.1.

4. First aid measures

4.1. Description of first aid measures

General notes

Never give anything by mouth to an unconscious person. Place patient in recovery position and ensure airway patency.

Following inhalation

Remove patient to fresh air - move out of dangerous area. If symptoms develop and persist, seek medical attention.

Following skin contact

Take off all contaminated clothing. If symptoms develop and persist, seek medical attention. Areas of the body that have come into contact with the product must be rinsed with water.

Following eye contact

Immediately flush eyes with running water, keeping eyelids appart. If irritation persists, seek professional medical attention.

Following ingestion

Do not induce vomiting! Rinse mouth thoroughly with water. In case of doubt or if feeling unwell seek medical help. Show the physician the Safety Data Sheet or label.

4.2. Most important symptoms and effects, both acute and delayed

Inhalation

Breathing dust can irritate the respiratory tract.

Skin contact

No irritant effects.

Eye contact

Dust may irritate the eyes.

Ingestion

No data.

4.3. Indication of any immediate medical attention and special treatment needed

-

5. Firefighting measures

5.1. Extinguishing media

Suitable extinguishing media

Carbon dioxide. Dry chemical powder. Water spray. Alcohol resistant foam.

Unsuitable extinguishing media

Full water jet.

5.2. Special hazards arising from the substance or mixture

Hazardous combustion products

-

5.3. Advice for firefighters

Protective actions

-

Special protective equipment for fire-fighters

Fire-fighters should wear appropriate protective clothing for fire-fighters (including helmets, protective boots and gloves) (EN 469) and self-contained breathing apparatus (SCBA) with a full face-piece (EN 137) .

6. ACCIDENTAL RELEASE MEASURES

6.1. Personal precautions, protective equipment and emergency procedures

6.1.1. For non-emergency personnel

Protective equipment

Use personal protective equipment (Section 8).

Emergency procedures

Ensure adequate ventilation.

6.1.2. For emergency responders

-

6.2. Environmental precautions

If accidental entry into water or ground occurs, inform responsible authorities.

6.3. Methods and material for containment and cleaning up

6.3.1. For containment

-

6.3.2. For cleaning up

Collect in a suitable container and dispose of according to regulations.

6.3.3. Other information

-

6.4. Reference to other sections

See also sections 8 and 13.

7. Handling and storage

7.1. Precautions for safe handling

7.1.1. Protective measures

Measures to prevent fire

Ensure adequate ventilation.

Measures to prevent aerosol and dust generation

Prevent dusting.

Measures to protect the environment

-

7.1.2. Advice on general occupational hygiene

Use good personal hygiene practices-wash hands at breaks and when done working with material. Do not eat, drink or smoke while working. Do not breathe dust.

7.2. Conditions for safe storage, including any incompatibilities

7.2.1. Technical measures and storage conditions

Keep in cool and well ventilated area. Keep away from food, drink and animal feedingstuffs.

7.2.2. Packaging materials

-

7.2.3. Requirements for storage rooms and vessels

-

7.2.4. Storage class

-

7.2.5. Further information on storage conditions

-

7.3. Specific end use(s)

Recommendations

-

Industrial sector specific solutions

-

8. Exposure controls/personal protection

8.1. Control parameters

8.1.1. Occupational Exposure limit values

Name (CAS) Limit values Short-term exposure limit Remarks Biological Tolerance Values
ml/m3
(ppm)
mg/m3
ml/m3
(ppm)
mg/m3
Aluminium oxides inhalable dust (1344-28-1) - 10 - -
Aluminium oxides respirable dust (1344-28-1) - 4 - -

Exposure limit values (IUCLID)

Name value interval x time Type
aluminium oxide (1344-28-1) 2 mg/m3 10 mg/m3 (6 x 8h) MAK (DE)
aluminium oxide (1344-28-1) 5 mg/m3 10 mg/m3 (6 x 8h) MAC (NL)
Source: IUCLID (For information only)

8.1.2. Information on monitoring procedures

BS EN 14042:2003 Title Identifier: Workplace atmospheres. Guide for the application and use of procedures for the assessment of exposure to chemical and biological agents.

8.1.3. DNEL/DMEL values

No information.

8.1.4. PNEC values

No information.

8.2. Exposure controls

8.2.1. Appropriate engineering control

Substance/mixture related measures to prevent exposure during identified uses

Use good personal hygiene practices-wash hands at breaks and when done working with material.

Technical measures to prevent exposure

Provide good ventilation and local exhaust in areas with increased concentration.

8.2.2. Personal protective equipment

Eye and face protection

Safety glasses with side protection (EN 166).

Hand protection

Protective gloves (EN 374).

Skin protection

Cotton protective clothing (EN ISO 13688) and shoes that cover the entire foot (EN ISO 20345).

Respiratory protection

-

Thermal hazards

-

8.2.3. Environmental exposure controls

-

9. PHYSICAL AND CHEMICAL PROPERTIES

9.1. Information on basic physical and chemical properties

- Physical state: solid
- Colour: white
- Odour: No odour

Important health, safety and environmental information

- pH No information.
- Melting point/Freezing point > 2000 °C
- Initial boiling point/boiling range > 2980 °C
- Flash point No information.
- Evaporation rate No information.
- Flammability (solid, gas) Not flammable.
- Explosion limits (vol%) No information.
- Vapour pressure No information.
- Vapour density No information.
- Density Relative density:
800 – 1100
- Solubility Water:
Insoluble
- Partition coefficient No information.
- Auto-ignition temperature No information.
- Decomposition temperature No information.
- Viscosity No information.
- Explosive properties No information.
- Oxidising properties No information.

9.2. Other information

- Remarks:

10. STABILITY AND REACTIVITY

10.1. Reactivity

-

10.2. Chemical stability

Product is stable under normal conditions according of handling and storage.

10.3. Possibility of hazardous reactions

-

10.4. Conditions to avoid

No special precautions required. Consider the directions for use and storage.

10.5. Incompatible materials

-

10.6. Hazardous decomposition products

Under normal use conditions no hazardous decomposition products are expected.

11. Toxicological information

11.1. Information on toxicological effects

11.1.1. Acute toxicity

For components
Name Exposure route Type Species Time Value Method Remark
aluminium oxide (1344-28-1) oral LD50 rat > 5000 mg/kg
aluminium oxide (1344-28-1) inhalation LC50 rat > 2,3 mg/l
(1344-28-1)* oral LD50 rat 5000 – 10500 mg/kg
(1344-28-1)* inhalation LC50 rat 1 h 18 – 18 mg/l
* Source: IUCLID (For information only)

11.1.2. Skin corrosion/irritation, serious eye damage/irritation

No information.

11.1.3. Respiratory or skin sensitisation

No information.

11.1.4. Carcinogenicity, Mutagenicity, Reproductive toxicity

Carcinogenicity

No information.

(Germ cell) mutagenicity

No information.

Reproductive toxicity

No information.

Summary of evaluation of the CMR properties

No information.

11.1.5. STOT - single and repeated exposure

No information.

11.1.6. Aspiration hazard

No information.

12. Ecological information

12.1. Toxicity

12.1.1. Acute (short-term) toxicity

Acute toxicity of ingredients (IUCLID)

CAS Species
Fish Daphnia Algae
1344-28-1 LC50/96h: 3185 - 478 mg/l * EC50/48h: 632 - 18000 mg/l * LC50/72h: 10000 - 320 mg/l *
 Source: IUCLID (For information only)

12.1.2. Chronic (long-term) toxicity

No information.

12.2. Persistence and degradability

12.2.1. Abiotic degradation, physical- and photo-chemical elimination

No information.

12.2.2. Biodegradation

No information.

12.3. Bioaccumulative potential

12.3.1. Partition coefficient

No information.

12.3.2. Bioconcentration factor (BCF)

No information.

12.4. Mobility in soil

12.4.1. Known or predicted distribution to environmental compartments

No information.

12.4.2. Surface tension

No information.

12.4.3. Adsorption/Desorption

No information.

12.5. Results of PBT and vPvB assessment

No evaluation.

12.6. Other adverse effects

No information.

13. Disposal considerations

13.1. Waste treatment methods

13.1.1. Product / Packaging disposal

Waste chemical

Disposal must be made according to official regulations: deliver it to authorized collector/remover/transformer of hazardous waste.

Packaging

Deliver completely emptied containers to approved waste disposal authorities.

13.1.2. Waste treatment-relevant information

-

13.1.3. Sewage disposal-relevant information

-

13.1.4. Other disposal recommendations

-

14. Transport information

14.1. UN number

not applicable

14.2. UN proper shipping name

ADR, RID, IMDG, ADN, IATA: Not dangerous according to transport regulations.

14.3. Transport hazard class(es)

not applicable

14.4. Packing group

not applicable

14.5. Environmental hazards

NO

14.6. Special precautions for user

not applicable

14.7. Transport in bulk according to Annex II of Marpol and the IBC Code

not applicable

15. Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture

- Regulation (EC) No 1907/2006 concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH)(including last amendment Commission Regulation (EU) 2015/830)

- Regulation (EC) No 1272/2008 on classification, labelling and packaging of substances and mixtures

15.1.1. Information according 2004/42/EC about limitation of emissions of volatile organic compounds (VOC-guideline)

not applicable

15.2. Chemical Safety Assessment

No Chemical Safety Assessment has been carried out for this substance/mixture by the supplier.

16. Other information

Indication of changes

New product name.

Abbreviations and acronyms

ATE - Acute Toxicity Estimate
ADR - European Agreement concerning the International Carriage of Dangerous Goods by Road
ADN - European Agreement concerning the International Carriage of Dangerous Goods by Inland Waterways
CEN - European Committee for Standardisation
C&L - Classification and Labelling
CLP - Classification Labelling Packaging Regulation; Regulation (EC) No 1272/2008
CAS# - Chemical Abstracts Service number
CMR - Carcinogen, Mutagen, or Reproductive Toxicant
CSA - Chemical Safety Assessment
CSR - Chemical Safety Report
DMEL - Derived Minimal Effect Level
DNEL - Derived No Effect Level
DPD - Dangerous Preparations Directive 1999/45/EC
DSD - Dangerous Substances Directive 67/548/EEC
DU - Downstream User
EC - European Community
ECHA - European Chemicals Agency
EC-Number - EINECS and ELINCS Number (see also EINECS and ELINCS)
EEA - European Economic Area (EU + Iceland, Liechtenstein and Norway)
EEC - European Economic Community
EINECS - European Inventory of Existing Commercial Substances
ELINCS - European List of notified Chemical Substances
EN - European Standard
EQS - Environmental Quality Standard
EU - European Union
Euphrac - European Phrase Catalogue
EWC - European Waste Catalogue (replaced by LoW – see below)
GES - Generic Exposure Scenario
GHS - Globally Harmonized System
IATA - International Air Transport Association
ICAO-TI - Technical Instructions for the Safe Transport of Dangerous Goods by Air
IMDG - International Maritime Dangerous Goods
IMSBC - International Maritime Solid Bulk Cargoes
IT - Information Technology
IUCLID - International Uniform Chemical Information Database
IUPAC - International Union for Pure Applied Chemistry
JRC - Joint Research Centre
Kow - octanol-water partition coefficient
LC50 - Lethal Concentration to 50 % of a test population
LD50 - Lethal Dose to 50% of a test population (Median Lethal Dose)
LE - Legal Entity
LoW - List of Wastes (see http://ec.europa.eu/environment/waste/framework/list.htm)
LR - Lead Registrant
M/I - Manufacturer / Importer
MS - Member States
MSDS - Material Safety Data Sheet
OC - Operational Conditions
OECD - Organization for Economic Co-operation and Development
OEL - Occupational Exposure Limit
OJ - Official Journal
OR - Only Representative
OSHA - European Agency for Safety and Health at work
PBT - Persistent, Bioaccumulative and Toxic substance
PEC - Predicted Effect Concentration
PNEC(s) - Predicted No Effect Concentration(s)
PPE - Personal Protection Equipment
(Q)SAR - Qualitative Structure Activity Relationship
REACH - Registration, Evaluation, Authorisation and Restriction of Chemicals Regulation (EC) No 1907/2006
RID - Regulations concerning the International Carriage of Dangerous Goods by Rail
RIP - REACH Implementation Project
RMM - Risk Management Measure
SCBA - Self-Contained Breathing Apparatus
SDS - Safety data sheet
SIEF - Substance Information Exchange Forum
SME - Small and Medium sized Enterprises
STOT - Specific Target Organ Toxicity
(STOT) RE - Repeated Exposure
(STOT) SE - Single Exposure
SVHC - Substances of Very High Concern
UN - United Nations
vPvB - Very Persistent and Very Bioaccumulative

Key literature references and sources for data

Safety Data Sheet of GK, Version 1.0

List of relevant H phrases

-

The information of this SDS is based on the present state of our knowledge and meets the requirements of EU and national laws. The user’s working conditions however, are beyond our knowledge and control. The product is not to be used for purposes other than those specified under section 1 without a written permission. It remains the responsibility of the user to ensure that the necessary steps are taken to meet the laws and regulations. Handling of the product may only be done by people above 18 years of age, who are satisfactorily informed of how to do the work, the hazardous properties and necessary safety precautions. The information given in this SDS is to describe the product only in terms of health and safety requirements and should not, therefore, be construed as guaranteeing specific properties.