SAFETY DATA SHEET according to Regulation 1907/2006
Creation date: 2.3.2009
Calcined Alumina, Kalzinierte Tonerde, Calcinata allumina, Kalcinirana glinica: 100 (GKM), LS15 (GKT-LS), LS15SG (GKT-LS-SG), S15 (GKT), S15SG (GKT-SG), M-1 (GKE), M-1FG (GKE-MF), M-S1 (GKE-V), M-S1FG (GKE-V-MF; ALO-G4-4G), M-MS1FG, MS 100, MS15 (GKT-MS), S100 (GKM), VLS15 (GKT-VLS), VLS15SG (GKT-VLS-SG)
aluminium oxide (CAS: 1344-28-1, EC: 215-691-6)
Raw material in the refractories, ceramics, glass and chemical industries, abrasives, polishing aids; use as an additive, filler, pigment
SILKEM, d. o. o.
+386 2 7991 214 (7h - 15h)
According to the regulation, the chemical is not classified as hazardous.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P304 + P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
The product is not classified as dangerous according to regulations.
|%||Classification according to Regulation (EC)
No 1272/2008 (CLP)
|Classification according to directive 67/548/EEC or 99/45/EC||REACH Registration No.|
|99.3-99.7||not classified||not classified||01-2119529248-35-0068|
For substances see 3.1.
Never give anything by mouth to an unconscious person. Place patient in recovery position and ensure airway patency.
Remove patient to fresh air - move out of dangerous area. If symptoms develop and persist, seek medical attention.
Take off all contaminated clothing. If symptoms develop and persist, seek medical attention. Areas of the body that have come into contact with the product must be rinsed with water.
Immediately flush eyes with running water, keeping eyelids appart. If irritation persists, seek professional medical attention.
Do not induce vomiting! Rinse mouth thoroughly with water. In case of doubt or if feeling unwell seek medical help. Show the physician the Safety Data Sheet or label.
Breathing dust can irritate the respiratory tract.
No irritant effects.
Dust may irritate the eyes.
Carbon dioxide. Dry chemical powder. Water spray. Alcohol resistant foam.
Full water jet.
Fire-fighters should wear appropriate protective clothing for fire-fighters (including helmets, protective boots and gloves) (EN 469) and self-contained breathing apparatus (SCBA) with a full face-piece (EN 137) .
Use personal protective equipment (Section 8).
Ensure adequate ventilation.
If accidental entry into water or ground occurs, inform responsible authorities.
Collect in a suitable container and dispose of according to regulations.
See also sections 8 and 13.
Ensure adequate ventilation.
Use good personal hygiene practices-wash hands at breaks and when done working with material. Do not eat, drink or smoke while working. Do not breathe dust.
Keep in cool and well ventilated area. Keep away from food, drink and animal feedingstuffs.
|Name (CAS)||Limit values||Short-term exposure limit||Remarks||Biological Tolerance Values|
|Aluminium oxides inhalable dust (1344-28-1)||-||10||-||-|
|Aluminium oxides respirable dust (1344-28-1)||-||4||-||-|
|Name||value||interval x time||Type|
|aluminium oxide (1344-28-1)||2||mg/m3||10||mg/m3 (6 x 8h)||MAK (DE)|
|aluminium oxide (1344-28-1)||5||mg/m3||10||mg/m3 (6 x 8h)||MAC (NL)|
|Source: IUCLID (For information only)|
BS EN 14042:2003 Title Identifier: Workplace atmospheres. Guide for the application and use of procedures for the assessment of exposure to chemical and biological agents.
Use good personal hygiene practices-wash hands at breaks and when done working with material.
Provide good ventilation and local exhaust in areas with increased concentration.
Safety glasses with side protection (EN 166).
Protective gloves (EN 374).
Cotton protective clothing (EN ISO 13688) and shoes that cover the entire foot (EN ISO 20345).
|-||Melting point/Freezing point||> 2000 °C|
|-||Initial boiling point/boiling range||> 2980 °C|
|-||Flash point||No information.|
|-||Evaporation rate||No information.|
|-||Flammability (solid, gas)||Not flammable.|
|-||Explosion limits (vol%)||No information.|
|-||Vapour pressure||No information.|
|-||Vapour density||No information.|
800 – 1100
|-||Partition coefficient||No information.|
|-||Auto-ignition temperature||No information.|
|-||Decomposition temperature||No information.|
|-||Explosive properties||No information.|
|-||Oxidising properties||No information.|
Product is stable under normal conditions according of handling and storage.
No special precautions required. Consider the directions for use and storage.
Under normal use conditions no hazardous decomposition products are expected.
|aluminium oxide (1344-28-1)||oral||LD50||rat||> 5000 mg/kg|
|aluminium oxide (1344-28-1)||inhalation||LC50||rat||> 2,3 mg/l|
|(1344-28-1)*||oral||LD50||rat||5000 – 10500 mg/kg|
|(1344-28-1)*||inhalation||LC50||rat||1 h||18 – 18 mg/l|
|* Source: IUCLID (For information only)|
|1344-28-1||LC50/96h: 3185 - 478 mg/l *||EC50/48h: 632 - 18000 mg/l *||LC50/72h: 10000 - 320 mg/l *|
|Source: IUCLID (For information only)|
Disposal must be made according to official regulations: deliver it to authorized collector/remover/transformer of hazardous waste.
Deliver completely emptied containers to approved waste disposal authorities.
ADR, RID, IMDG, ADN, IATA: Not dangerous according to transport regulations.
- Regulation (EC) No 1907/2006 concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH)(including last amendment Commission Regulation (EU) 2015/830)
- Regulation (EC) No 1272/2008 on classification, labelling and packaging of substances and mixtures
No Chemical Safety Assessment has been carried out for this substance/mixture by the supplier.
New product name.
ATE - Acute Toxicity Estimate
ADR - European Agreement concerning the International Carriage of Dangerous Goods by Road
ADN - European Agreement concerning the International Carriage of Dangerous Goods by Inland Waterways
CEN - European Committee for Standardisation
C&L - Classification and Labelling
CLP - Classification Labelling Packaging Regulation; Regulation (EC) No 1272/2008
CAS# - Chemical Abstracts Service number
CMR - Carcinogen, Mutagen, or Reproductive Toxicant
CSA - Chemical Safety Assessment
CSR - Chemical Safety Report
DMEL - Derived Minimal Effect Level
DNEL - Derived No Effect Level
DPD - Dangerous Preparations Directive 1999/45/EC
DSD - Dangerous Substances Directive 67/548/EEC
DU - Downstream User
EC - European Community
ECHA - European Chemicals Agency
EC-Number - EINECS and ELINCS Number (see also EINECS and ELINCS)
EEA - European Economic Area (EU + Iceland, Liechtenstein and Norway)
EEC - European Economic Community
EINECS - European Inventory of Existing Commercial Substances
ELINCS - European List of notified Chemical Substances
EN - European Standard
EQS - Environmental Quality Standard
EU - European Union
Euphrac - European Phrase Catalogue
EWC - European Waste Catalogue (replaced by LoW – see below)
GES - Generic Exposure Scenario
GHS - Globally Harmonized System
IATA - International Air Transport Association
ICAO-TI - Technical Instructions for the Safe Transport of Dangerous Goods by Air
IMDG - International Maritime Dangerous Goods
IMSBC - International Maritime Solid Bulk Cargoes
IT - Information Technology
IUCLID - International Uniform Chemical Information Database
IUPAC - International Union for Pure Applied Chemistry
JRC - Joint Research Centre
Kow - octanol-water partition coefficient
LC50 - Lethal Concentration to 50 % of a test population
LD50 - Lethal Dose to 50% of a test population (Median Lethal Dose)
LE - Legal Entity
LoW - List of Wastes (see http://ec.europa.eu/environment/waste/framework/list.htm)
LR - Lead Registrant
M/I - Manufacturer / Importer
MS - Member States
MSDS - Material Safety Data Sheet
OC - Operational Conditions
OECD - Organization for Economic Co-operation and Development
OEL - Occupational Exposure Limit
OJ - Official Journal
OR - Only Representative
OSHA - European Agency for Safety and Health at work
PBT - Persistent, Bioaccumulative and Toxic substance
PEC - Predicted Effect Concentration
PNEC(s) - Predicted No Effect Concentration(s)
PPE - Personal Protection Equipment
(Q)SAR - Qualitative Structure Activity Relationship
REACH - Registration, Evaluation, Authorisation and Restriction of Chemicals Regulation (EC) No 1907/2006
RID - Regulations concerning the International Carriage of Dangerous Goods by Rail
RIP - REACH Implementation Project
RMM - Risk Management Measure
SCBA - Self-Contained Breathing Apparatus
SDS - Safety data sheet
SIEF - Substance Information Exchange Forum
SME - Small and Medium sized Enterprises
STOT - Specific Target Organ Toxicity
(STOT) RE - Repeated Exposure
(STOT) SE - Single Exposure
SVHC - Substances of Very High Concern
UN - United Nations
vPvB - Very Persistent and Very Bioaccumulative
Safety Data Sheet of GK, Version 1.0