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SAFETY DATA SHEET according to Regulation 1907/2006 amended by 2020/878/EU
Product name: ASORBIO® ZAG-MFI
Creation date: 1.2.2017 ·
Revision: 4.5.2020 ·
Version: 2.1
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1. Identification of the substance/mixture and of the company/undertaking
chemius.net/KlX2d
1.1. Product identifier
Product name
ASORBIO® ZAG-MFI
Name
Zeolite, silica rich, crystalline, synthetic, non-fibrous (CAS: 1318-02-1, EC: 930-985-0)
REACH Registration number
01-2119455853-31
1.2. Relevant identified uses of the substance or mixture and uses advised against
Relevant identified uses
Industrial use.
Uses advised against
not known.
1.3. Details of the supplier of the safety data sheet
Supplier
SILKEM, d. o. o.
Address: Tovarniška cesta 10, 2325 Kidričevo, Slovenia
Phone: +386 2 7991 200
Fax: +386 2 7991 230
E-mail: info@silkem.si
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SILKEM, d.o.o.
Tovarniška cesta 10
2325 Kidričevo
Slovenia
1.4. Emergency telephone number
112
+386 2 7991 208 (7h - 15h)
2. Hazards identification
2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No 1272/2008 (CLP)
According to the regulation, the product is not classified as hazardous.
2.2 Label elements
2.2.1. Labelling according to Regulation (EC) No 1272/2008 [CLP]
Pictograms not applicable according to Regulation 1272/2008.
2.2.3. Special provisions
Special hazards are not known or expected.
2.3. Other hazards
The substances in the mixture are not classified as persistent, bioaccumulative and toxic (PBT) or very persistent and very bioaccumulative (vPvB).
3. Composition/information on ingredients
Product description
EINECS: 215-283-8 and CAS: 1318-02-1 are merely used for information as related numbers and as a pre-registration identifier.
EINECS numbers mentionned here have been designated by ECHA after registration.
3.1. Substances
| Name |
CAS
EC
Index |
% |
Classification according to Regulation (EC)
No 1272/2008 (CLP) |
Specific Conc. Limits |
Classification according to directive 67/548/EEC or 99/45/EC |
REACH Registration No. |
| Zeolite, silica rich, crystalline, synthetic, non-fibrous |
1318-02-1
930-985-0
- |
77-83 |
not classified |
|
not classified |
01-2119455853-31 |
3.2. Mixtures
For substances see 3.1.
4. First aid measures
4.1. Description of first aid measures
General notes
When in doubt or if feeling unwell seek medical assistance.
Following inhalation
Remove patient to fresh air - move out of dangerous area. Ventilate the premises. Inhale fresh air. If symptoms develop and persist, seek medical attention.
Following skin contact
Product is not irritating to the skin. Areas of the body that have come into contact with the product must be rinsed with water.
Following eye contact
If substance has got into eyes, immediately wash out with plenty of water. If irritation persists, seek professional medical attention.
Following ingestion
In case of doubt or if feeling unwell seek medical help.
4.2. Most important symptoms and effects, both acute and delayed
Inhalation
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4.3. Indication of any immediate medical attention and special treatment needed
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5. Firefighting measures
5.1. Extinguishing media
Suitable extinguishing media
Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Carbon dioxide. Dry chemical powder. Water spray. Alcohol resistant foam.
Unsuitable extinguishing media
Full water jet.
5.2. Special hazards arising from the substance or mixture
Hazardous combustion products
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5.3. Advice for firefighters
Protective actions
In case of fire or heating do not breathe fumes/vapours.
Special protective equipment for firefighters
In case of fire: Wear suitable respiratory equipment - self-contained breathing apparatus and full protective equipment.
Additional information
Contaminated firefighting water must be disposed of in accordance with the regulations; do not allow to reach the sewage system.
6. ACCIDENTAL RELEASE MEASURES
6.1. Personal precautions, protective equipment and emergency procedures
6.1.1. For non-emergency personnel
Protective equipment
Use personal protective equipment (Section 8). Thoroughly clean hands after use or contact.
Emergency procedures
Avoid dust generation.
6.1.2. For emergency responders
Wear appropriate personal protective equipment!
6.2. Environmental precautions
If accidental large entry into water or ground occurs, inform responsible authorities.
6.3. Methods and material for containment and cleaning up
6.3.1. For containment
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6.3.2. For cleaning up
Pick up mechanically and remove it in accordance with regulation.
6.3.3. Other information
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6.4. Reference to other sections
See also Sections 8 and 13.
7. Handling and storage
7.1. Precautions for safe handling
7.1.1. Protective measures
Measures to prevent fire
Take precautionary measures against static discharges.
Measures to prevent aerosol and dust generation
Prevent dusting. Ensure good ventilation and extraction.
Measures to protect the environment
Avoid release to the environment.
7.1.2. Advice on general occupational hygiene
Avoid contact with skin and eyes. Use personal protective equipment. Do not eat or drink while working.
7.2. Conditions for safe storage, including any incompatibilities
7.2.1. Technical measures and storage conditions
Keep in well closed containers. Keep in a dry place. Keep container in a well ventilated place. Keep away from food, drink and animal feeding stuffs. This product is hygroscopic.
7.2.2. Packaging materials
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7.2.3. Requirements for storage rooms and vessels
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7.2.5. Further information on storage conditions
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7.3. Specific end use(s)
Recommendations
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Industrial sector specific solutions
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8. Exposure controls/personal protection
8.1. Control parameters
8.1.1. Occupational exposure limit values
No information.
8.1.2. Information on monitoring procedures
BS EN 14042:2003 Title Identifier: Workplace atmospheres. Guide for the application and use of procedures for the assessment of exposure to chemical and biological agents. BS EN 482:2021 Workplace exposure. Procedures for the determination of the concentration of chemical agents. Basic performance requirements.
8.1.3. DNEL/DMEL values
No information.
8.1.4. PNEC values
No information.
8.2. Exposure controls
8.2.1. Appropriate engineering control
Substance/mixture related measures to prevent exposure during identified uses
Use good personal hygiene practices – wash hands at breaks and when done working with material. Handle in accordance with good industrial hygiene and safety practice.
Organisational measures to prevent exposure
Keep eyewash bottles or personal eyewash units available.
Technical measures to prevent exposure
Provide good ventilation and local exhaust in areas with increased concentration.
8.2.2. Personal protective equipment
Eye and face protection
Safety glasses with side protection (EN 166).
Hand protection
Protective gloves (EN 374).
Skin protection
Cotton protective clothing and shoes that cover the entire foot (EN ISO 20345:2011).
Respiratory protection
Not needed under normal use and adequate ventilation. Mask with dust filter (P2) or FFP2 (EN 149).
8.2.3. Environmental exposure controls
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9. PHYSICAL AND CHEMICAL PROPERTIES
9.1. Information on basic physical and chemical properties
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Physical state: |
solid; granules |
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Colour: |
white |
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Odour: |
no odour |
Important health, safety and environmental information
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pH |
No information. |
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Melting point/freezing point |
No information. |
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Initial boiling point/boiling range |
No information. |
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Flash point |
No information. |
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Evaporation rate |
No information. |
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Flammability (solid, gas) |
No information. |
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Explosion limits (vol%) |
No information. |
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Vapour pressure |
No information. |
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Vapour density |
No information. |
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Density |
Relative density:
720 – 820 |
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Solubility |
No information. |
| - |
Partition coefficient |
No information. |
| - |
Auto-ignition temperature |
No information. |
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Decomposition temperature |
No information. |
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Viscosity |
No information. |
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Explosive properties |
No information. |
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Oxidising properties |
No information. |
| - |
Particle characteristics |
No information. |
10. STABILITY AND REACTIVITY
10.1. Reactivity
Stable under normal conditions.
10.2. Chemical stability
Product is stable under normal conditions.
10.3. Possibility of hazardous reactions
The product is stable under recommended storage and handling conditions.
10.4. Conditions to avoid
No special precautions required. Consider the directions for use and storage. Protect from moisture and water - keep in dry place.
10.5. Incompatible materials
Not known.
10.6. Hazardous decomposition products
Under normal use conditions no hazardous decomposition products are expected.
11. Toxicological information
11.1. Information on hazard classes as defined in Regulation (EC) No 1272/2008
(a) Acute toxicity
No information.
(b) Skin corrosion/irritation
No information.
(c) Serious eye damage/irritation
No information.
(d) Respiratory or skin sensitisation
No information.
(e) (Germ cell) mutagenicity
No information.
(f) Carcinogenicity
No information.
(g) Reproductive toxicity
No information.
Summary of evaluation of the CMR properties
No information.
(h) STOT-single exposure
No information.
(i) STOT-repeated exposure
No information.
(j) Aspiration hazard
No information.
11.2. Information on other hazards
11.2.1. Endocrine disrupting properties
No information.
11.2.2. Other information
No information.
12. Ecological information
12.1. Toxicity
12.1.1. Acute (short-term) toxicity
No information.
12.1.2. Chronic (long-term) toxicity
No information.
12.2. Persistence and degradability
12.2.1. Abiotic degradation, physical- and photo-chemical elimination
No information.
12.2.2. Biodegradation
No information.
12.3. Bioaccumulative potential
12.3.1. Partition coefficient
No information.
12.3.2. Bioconcentration factor (BCF)
No information.
12.4. Mobility in soil
12.4.1. Known or predicted distribution to environmental compartments
No information.
12.4.2. Surface tension
No information.
12.4.3. Adsorption/Desorption
No information.
12.5. Results of PBT and vPvB assessment
The components in this formulation do not meet the criteria for classification as PBT or vPvB.
12.6. Endocrine disrupting properties
No information.
12.7. Additional information
For product
Avoid release to the environment.
13. Disposal considerations
13.1. Waste treatment methods
13.1.1. Product / Packaging disposal
Waste chemical
Waste should be handled in accordance with local or national regulations
Packaging
Deliver completely emptied containers to approved waste disposal authorities.
13.1.2. Waste treatment-relevant information
Disposal in accordance with the Rules on the management of waste.
13.1.3. Sewage disposal-relevant information
-
13.1.4. Other disposal recommendations
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14. Transport information
14.1. UN number or ID number
Not applicable.
14.2. UN proper shipping name
ADR, RID, IMDG, ADN, IATA: Not dangerous according to transport regulations.
14.3. Transport hazard class(es)
Not applicable.
14.4. Packing group
Not applicable.
14.5. Environmental hazards
NO.
14.6. Special precautions for user
Not applicable.
14.7. Maritime transport in bulk according to IMO instruments
Not applicable.
15. Regulatory information
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
- Regulation (EC) No 1907/2006 concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH)(including last amendment Commission Regulation (EU) 2020/878)
- Regulation (EC) No 1272/2008 on classification, labelling and packaging of substances and mixtures
15.1.1. Information according 2004/42/EC about limitation of emissions of volatile organic compounds (VOC-guideline)
Not applicable.
15.2. Chemical Safety Assessment
No Chemical Safety Assessment has been carried out for this substance/mixture by the supplier.
Abbreviations and acronyms
ATE - Acute Toxicity Estimate
ADR - Agreement concerning the International Carriage of Dangerous Goods by Road
ADN - European Agreement concerning the International Carriage of Dangerous Goods by Inland Waterways
CEN - European Committee for Standardisation
C&L - Classification and Labelling
CLP - Classification Labelling Packaging Regulation; Regulation (EC) No 1272/2008
CAS# - Chemical Abstracts Service number
CMR - Carcinogen, Mutagen, or Reproductive Toxicant
CSA - Chemical Safety Assessment
CSR - Chemical Safety Report
DMEL - Derived Minimal Effect Level
DNEL - Derived No Effect Level
DPD - Dangerous Preparations Directive 1999/45/EC
DSD - Dangerous Substances Directive 67/548/EEC
DU - Downstream User
EC - European Community
ECHA - European Chemicals Agency
EC-Number - EINECS and ELINCS Number (see also EINECS and ELINCS)
EEA - European Economic Area (EU + Iceland, Liechtenstein and Norway)
EEC - European Economic Community
EINECS - European Inventory of Existing Commercial Substances
ELINCS - European List of notified Chemical Substances
EN - European Standard
EQS - Environmental Quality Standard
EU - European Union
Euphrac - European Phrase Catalogue
EWC - European Waste Catalogue (replaced by LoW – see below)
GES - Generic Exposure Scenario
GHS - Globally Harmonized System
IATA - International Air Transport Association
ICAO-TI - Technical Instructions for the Safe Transport of Dangerous Goods by Air
IMDG - International Maritime Dangerous Goods
IMSBC - International Maritime Solid Bulk Cargoes
IT - Information Technology
IUCLID - International Uniform Chemical Information Database
IUPAC - International Union for Pure Applied Chemistry
JRC - Joint Research Centre
Kow - octanol-water partition coefficient
LC50 - Lethal Concentration to 50 % of a test population
LD50 - Lethal Dose to 50% of a test population (Median Lethal Dose)
LE - Legal Entity
LoW - List of Wastes (see http://ec.europa.eu/environment/waste/framework/list.htm)
LR - Lead Registrant
M/I - Manufacturer / Importer
MS - Member States
MSDS - Material Safety Data Sheet
OC - Operational Conditions
OECD - Organization for Economic Co-operation and Development
OEL - Occupational Exposure Limit
OJ - Official Journal
OR - Only Representative
OSHA - European Agency for Safety and Health at work
PBT - Persistent, Bioaccumulative and Toxic substance
PEC - Predicted Effect Concentration
PNEC(s) - Predicted No Effect Concentration(s)
PPE - Personal Protection Equipment
(Q)SAR - Qualitative Structure Activity Relationship
REACH - Registration, Evaluation, Authorisation and Restriction of Chemicals
Regulation (EC) No 1907/2006
RID - Regulations concerning the International Carriage of Dangerous Goods by Rail
RIP - REACH Implementation Project
RMM - Risk Management Measure
SCBA - Self-Contained Breathing Apparatus
SDS - Safety data sheet
SIEF - Substance Information Exchange Forum
SME - Small and Medium sized Enterprises
STOT - Specific Target Organ Toxicity
(STOT) RE - Repeated Exposure
(STOT) SE - Single Exposure
SVHC - Substances of Very High Concern
UN - United Nations
vPvB - Very Persistent and Very Bioaccumulative
Key literature references and sources for data
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List of relevant H phrases
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The information of this SDS is based on the present state of our knowledge and meets the requirements of EU and national
laws. The user’s working conditions however, are beyond our knowledge and control. The product is not to be used for purposes
other than those specified under Section 1 without a written permission. It remains the responsibility of the user to ensure that
the necessary steps are taken to meet the laws and regulations. Handling of the product may only be done by people above 18
years of age, who are satisfactorily informed of how to do the work, the hazardous properties and necessary safety precautions.
The information given in this SDS is to describe the product only in terms of health and safety requirements and should not,
therefore, be construed as guaranteeing specific properties.
