Cure It Evo Primer Part B

Product code

[UFI: 0J10-002W-N001-AAXD]

1.2. Relevant identified uses of the substance or mixture and uses advised against

Relevant identified uses

Hardener for Cure It resin and topcoat.

Uses advised against

Do not use for purposes other than those prescribed.

1.3. Details of the supplier of the safety data sheet

1.4. Emergency telephone number

+44 (0)1942 518150 Mon-Friday 8.30am – 4.30pm

2. Hazards identification

2.1 Classification of the substance or mixture

Classification according to Regulation (EC) No 1272/2008 (CLP)

Org. Perox. D; H242  Heating may cause a fire.
Acute Tox. 4; H302  Harmful if swallowed.
Skin Corr. 1B; H314  Causes severe skin burns and eye damage.

2.2 Label elements

2.2.1. Labelling according to Regulation (EC) No 1272/2008 [CLP]

Signal word: Danger

H242  Heating may cause a fire.
H302  Harmful if swallowed.
H314  Causes severe skin burns and eye damage.
P233  Keep container tightly closed.
P235  Keep cool.
P262  Do not get in eyes, on skin, or on clothing.
P280  Wear protective gloves/protective clothing/eye protection/face protection.
P303 + P361 + P353  IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water [or shower].
P305 + P351 + P338  IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P315  Get immediate medical advice/attention.
P501  Dispose of contents/container in accordance with national regulation.

2.2.2. Contains:

methyl ethyl ketone peroxide

2.2.3. Special provisions

Keep/store away from clothing/strong acids, bases, heavy metals salts and other reducing substances/combustible materials.

2.3. Other hazards

The substances in the mixture does not meet the PBT criteria according to REACH, Annex XIII

Following inhalation

Remove patient to fresh air - move out of dangerous area. In case of unconsciousness bring patient into stable side position and seek medical attention. Seek medical help immediately. If breathing is irregular or respiratory arrest occurs provide artificial respiration. Keep at rest in a position comfortable for breathing.

Following skin contact

Take off all contaminated clothing. Wash affected skin areas thoroughly with plenty of water and soap. If symptoms develop and persist, seek medical attention.

Following eye contact

Immediately flush eyes with running water, keeping eyelids apart. After 5 minutes of rinsing, remove contact lenses, if present, and continue rinsing. Consult a physician immediately!

Following ingestion

Do not induce vomiting! Rinse mouth and drink plenty of water (only if the person is conscious). If vomiting occurs, the patient should hold the head lower than the hips, because it reduces the possibility of aspiration. Immediately consult a doctor. Show the physician the safety data sheet or label.

4.2. Most important symptoms and effects, both acute and delayed

Inhalation

Excessive exposure to spray mist, fog, or vapours may cause respiratory irritation.
Symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, nose and throat pain.

Skin contact

May cause localised redness, swelling, itching, intense pain, blistering, ulceration and tissue destruction.

Eye contact

Redness, pain, burning sensation, tearing, can cause permanent damage to the eyes.
May cause corneal injury.

Ingestion

May cause abdominal discomfort.
May cause nausea/vomiting and diarrhea.
Harmful to health.
If ingested, may cause burns of the mouth and throat, as well as perforation of the esophagus and stomach.

4.3. Indication of any immediate medical attention and special treatment needed

Treat symptomatically. Have eye wash facilities in place close to the operators’ work area to provide immediate first aid prior to medical attention. Severe cases of eye contact and ingestion should receive medical attention immediately.

Unsuitable extinguishing media

Full water jet.

5.2. Special hazards arising from the substance or mixture

Hazardous combustion products

In case of a fire toxic gases can be generated; do not inhale gases/smoke.

5.3. Advice for firefighters

Protective actions

In case of fire or heating do not breathe fumes/vapours. Cool containers at risk with water spray. If possible remove containers from endangered area. No action shall be taken involving any personal risk or without suitable training.

Special protective equipment for firefighters

Firefighters should wear appropriate protective clothing for firefighters (including helmets, protective boots and gloves) (EN 469) and self-contained breathing apparatus (SCBA) with a full face-piece (EN 137).

Additional information

Contaminated firefighting water must be disposed of in accordance with the regulations; do not allow to reach the sewage system.

Ensure adequate ventilation. Keep away from sources of ignition and/or heat; No smoking! Prevent access to unprotected personnel. No action shall be taken involving any personal risk or without suitable training. Evacuate the danger zone. Do not breathe vapour or mist. Avoid contact with skin, eyes and clothing.

6.1.2. For emergency responders

During intervention, use personal protective equipment (Section 8).

6.2. Environmental precautions

Do not allow product to reach water/drains/sewage systems or permeable soil. In case of release into the environment, inform the relevant authorities.

6.3. Methods and material for containment and cleaning up

6.3.1. For containment

Stem the spill if this does not pose risks.

6.3.2. For cleaning up

Absorb product (with inert material), collect it in special container and dispose it to a licensed hazardous-waste disposal contractor. Prevent release into the sewer, water, basements or confined areas. Dispose in accordance with applicable regulations (see Section 13).

6.3.3. Other information

See Section 7: safe handling. See Section 11 for additional information on health hazards. Dispose of in accordance with the instructions from Section 13.

6.4. Reference to other sections

See also Sections 8 and 13.

Use general or local exhaust ventilation to prevent inhaling vapours and aerosols.

Do not discharge into drains, surface water and soil. After use immediately close container tightly.

7.1.2. Advice on general occupational hygiene

Do not eat, drink or smoke while working. Do not breathe vapours/mist. Use good personal hygiene practices – wash hands at breaks and when done working with material. Avoid contact with skin, eyes and clothes. Remove contaminated clothes and wash them before reuse. Wear suitable protective equipment; see Section 8.

7.2. Conditions for safe storage, including any incompatibilities

7.2.1. Technical measures and storage conditions

Protect from open fire, heat and direct sunlight. Keep away from food, drink and animal feeding stuffs. Keep in a cool, dry and well ventilated place. Store below 30°C. Keep away from incompatible products (see section 10).

7.2.2. Packaging materials

Store only in original container.

7.2.3. Requirements for storage rooms and vessels

Close opened containers after use. Put the containers upright to prevent from leaking. Do not store in unlabelled containers.

7.2.4. Storage class

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7.2.5. Further information on storage conditions

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7.3. Specific end use(s)

See identified uses in Section 1.2.

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8.1.2. Information on monitoring procedures

BS EN 14042:2003 Title Identifier: Workplace atmospheres. Guide for the application and use of procedures for the assessment of exposure to chemical and biological agents. BS EN 482:2021 Workplace exposure. Procedures for the determination of the concentration of chemical agents. Basic performance requirements.

8.1.3. DNEL/DMEL values

No information.

8.1.4. PNEC values

No information.

8.2. Exposure controls

8.2.1. Appropriate engineering control

Do not breathe vapours/aerosols. Use good personal hygiene practices – wash hands at breaks and when done working with material. Handle in accordance with good industrial hygiene and safety practice. Do not eat, drink or smoke while working. Avoid contact with skin, eyes and clothes.

Remove all contaminated clothes immediately and wash them before reuse. Keep eyewash bottles or personal eyewash units and emergency showers available.

Provide good ventilation and local exhaust in areas with increased concentration. Keep away from food, drink and animal feeding stuffs.

8.2.2. Personal protective equipment

Wear tight fitting protective goggles and/or face protection (EN 166:2001).

Protective gloves (EN 374). The penetration time is determined by the protective glove manufacturer and must be observed. Observe the manufacturer's instructions regarding the use, storage, maintenance and replacement of gloves. In case of damage or at the first signs of wear and tear, change the gloves immediately. The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer.

Cotton protective clothing and shoes that cover the entire foot (EN ISO 20345:2011). At high risk of skin exposure chemical suits (EN ISO 6530:2005) and boots may be required (EN ISO 20345:2012). Immediately wash contaminated clothing before reuse.

Protective masks (EN 136) or half masks (EN 140) with filter A (EN 14387).

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8.2.3. Environmental exposure controls

Do not allow product to reach drains, sewage systems or ground water.

10.2. Chemical stability

In case of contact with incompatible materials, it may also decompose at a lower temperature than SADT.

10.3. Possibility of hazardous reactions

The vapours may also form explosive mixtures with the air.

10.4. Conditions to avoid

Protect from heat, direct sunlight, open fire, sparks.

10.5. Incompatible materials

Accelerators;
Strong acids.
Strong bases. Heavy metals. Heavy metal salts. Reducing agents. Avoid impurities (e.g. rust, dust, ash) risk of decomposition.

10.6. Hazardous decomposition products

Under normal use conditions no hazardous decomposition products are expected. In case of fire/explosion vapours/gases that pose a health hazard are released.

(e) (Germ cell) mutagenicity

No information.

(f) Carcinogenicity

No information.

(g) Reproductive toxicity

No information.

Summary of evaluation of the CMR properties

The product is not classified as carcinogenic, mutagenic or toxic for reproduction.

11.2. Information on other hazards

11.2.1. Endocrine disrupting properties

No information.

11.2.2. Other information

No information.

12.1.2. Chronic (long-term) toxicity

No information.

12.2. Persistence and degradability

12.2.1. Abiotic degradation, physical- and photo-chemical elimination

No information.

12.3. Bioaccumulative potential

12.3.1. Partition coefficient

No information.

12.3.2. Bioconcentration factor (BCF)

No information.

12.4. Mobility in soil

12.4.1. Known or predicted distribution to environmental compartments

No information.

12.4.2. Surface tension

No information.

12.4.3. Adsorption/Desorption

No information.

12.5. Results of PBT and vPvB assessment

This mixture contains no substance considered to be persistent, bioaccumulating nor toxic (PBT).

12.6. Endocrine disrupting properties

No information.

12.7. Additional information

Product is not classified as dangerous for environment.
Do not allow undiluted product or large quantities of it to reach ground water, water bodies or sewage system.

Deliver completely emptied containers to approved waste disposal authorities. Uncleaned containers are classified as hazardous waste - they should be handled in the same manner as the contents. Dispose of in accordance with applicable waste disposal regulation.

13.1.2. Waste treatment-relevant information

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13.1.3. Sewage disposal-relevant information

-

13.1.4. Other disposal recommendations

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15.1.1. Information according 2004/42/EC about limitation of emissions of volatile organic compounds (VOC-guideline)

Not applicable.

15.2. Chemical Safety Assessment

A Chemical Safety Assessment has not been carried out.

Abbreviations and acronyms

ATE - Acute Toxicity Estimate
ADR - Agreement concerning the International Carriage of Dangerous Goods by Road
ADN - European Agreement concerning the International Carriage of Dangerous Goods by Inland Waterways
CEN - European Committee for Standardisation
C&L - Classification and Labelling
CLP - Classification Labelling Packaging Regulation; Regulation (EC) No 1272/2008
CAS# - Chemical Abstracts Service number
CMR - Carcinogen, Mutagen, or Reproductive Toxicant
CSA - Chemical Safety Assessment
CSR - Chemical Safety Report
DMEL - Derived Minimal Effect Level
DNEL - Derived No Effect Level
DPD - Dangerous Preparations Directive 1999/45/EC
DSD - Dangerous Substances Directive 67/548/EEC
DU - Downstream User
EC - European Community
ECHA - European Chemicals Agency
EC-Number - EINECS and ELINCS Number (see also EINECS and ELINCS)
EEA - European Economic Area (EU + Iceland, Liechtenstein and Norway)
EEC - European Economic Community
EINECS - European Inventory of Existing Commercial Substances
ELINCS - European List of notified Chemical Substances
EN - European Standard
EQS - Environmental Quality Standard
EU - European Union
Euphrac - European Phrase Catalogue
EWC - European Waste Catalogue (replaced by LoW – see below)
GES - Generic Exposure Scenario
GHS - Globally Harmonized System
IATA - International Air Transport Association
ICAO-TI - Technical Instructions for the Safe Transport of Dangerous Goods by Air
IMDG - International Maritime Dangerous Goods
IMSBC - International Maritime Solid Bulk Cargoes
IT - Information Technology
IUCLID - International Uniform Chemical Information Database
IUPAC - International Union for Pure Applied Chemistry
JRC - Joint Research Centre
Kow - octanol-water partition coefficient
LC₅₀ - Lethal Concentration to 50 % of a test population
LD₅₀ - Lethal Dose to 50% of a test population (Median Lethal Dose)
LE - Legal Entity
LoW - List of Wastes (see http://ec.europa.eu/environment/waste/framework/list.htm)
LR - Lead Registrant
M/I - Manufacturer / Importer
MS - Member States
MSDS - Material Safety Data Sheet
OC - Operational Conditions
OECD - Organization for Economic Co-operation and Development
OEL - Occupational Exposure Limit
OJ - Official Journal
OR - Only Representative
OSHA - European Agency for Safety and Health at work
PBT - Persistent, Bioaccumulative and Toxic substance
PEC - Predicted Effect Concentration
PNEC(s) - Predicted No Effect Concentration(s)
PPE - Personal Protection Equipment
(Q)SAR - Qualitative Structure Activity Relationship
REACH - Registration, Evaluation, Authorisation and Restriction of Chemicals Regulation (EC) No 1907/2006
RID - Regulations concerning the International Carriage of Dangerous Goods by Rail
RIP - REACH Implementation Project
RMM - Risk Management Measure
SCBA - Self-Contained Breathing Apparatus
SDS - Safety data sheet
SIEF - Substance Information Exchange Forum
SME - Small and Medium sized Enterprises
STOT - Specific Target Organ Toxicity
(STOT) RE - Repeated Exposure
(STOT) SE - Single Exposure
SVHC - Substances of Very High Concern
UN - United Nations
vPvB - Very Persistent and Very Bioaccumulative

Key literature references and sources for data

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List of relevant H phrases

H242  Heating may cause a fire.
H271  May cause fire or explosion; strong oxidiser.
H302  Harmful if swallowed.
H314  Causes severe skin burns and eye damage.
H315  Causes skin irritation.
H319  Causes serious eye irritation.
H332  Harmful if inhaled.