SAFETY DATA SHEET according to Regulation 1907/2006 amended by 2020/878/EU
Product name:
Roofcell Basecoat
Creation date: 13.4.2021 |
Roofcell Basecoat
UFI: 7A00-C0F3-3003-Q03E
Resin for roofing. Contact the manufacturer for any other applications.
No information.
ManufacturerG&B Northwest Ltd | SupplierG&B Northwest Ltd |
+44 (0)1942 518150 Mon-Friday 8.30 am – 4.30 pm
Flam. Liq. 3; H226 Flammable liquid and vapour.
Skin Irrit. 2; H315 Causes skin irritation.
Eye Irrit. 2; H319 Causes serious eye irritation.
STOT SE 3; H335 May cause respiratory irritation.
Repr. 2; H361d Suspected of damaging the unborn child.
STOT RE 1; H372 Causes damage to organs through prolonged or repeated exposure.
Aquatic Chronic 3; H412 Harmful to aquatic life with long lasting effects.
Signal word: Danger
H226 Flammable liquid and vapour.
H315 Causes skin irritation.
H319 Causes serious eye irritation.
H335 May cause respiratory irritation.
H361d Suspected of damaging the unborn child.
H372 Causes damage to organs through prolonged or repeated exposure.
H412 Harmful to aquatic life with long lasting effects.
EUH208 Contains phthalic anhydride. May produce an allergic reaction.
P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P243 Take action to prevent static discharges.
P260 Do not breathe vapours.
P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P302 + P352 IF ON SKIN: Wash with plenty of soap and water.
P304 + P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P403 + P233 Store in a well-ventilated place. Keep container tightly closed.
styrene
Special hazards are not known or expected.
No information.
For mixtures see 3.2.
Name | CAS EC Index |
% | Classification according to Regulation (EC) No 1272/2008 (CLP) |
Specific Conc. Limits | Classification according to directive 67/548/EEC or 99/45/EC | REACH Registration No. |
---|---|---|---|---|---|---|
calcium carbonate | 471-34-1 207-439-9 - |
<50 | not classified | not classified | - | |
styrene | 100-42-5 202-851-5 601-026-00-0 |
<40 | Flam. Liq. 3; H226 Asp. Tox. 1; H304 Skin Irrit. 2; H315 Eye Irrit. 2; H319 Acute Tox. 4; H332 STOT SE 3; H335 Repr. 2; H361d STOT RE 1; H372 Aquatic Chronic 3; H412 |
Xn; R20-48/20-65 Xi; R36/37/38 R10 |
01-2119457861-32 | |
phthalic anhydride | 85-44-9 201-607-5 607-009-00-4 |
<1 | Acute Tox. 4; H302 Skin Irrit. 2; H315 Skin Sens. 1; H317 Eye Dam. 1; H318 Resp. Sens. 1; H334 STOT SE 3; H335 |
Xn; R22-42/43 Xi; R37/38-41 |
01-2119457017-41 | |
Amorphous Silica | 112945-52-5 - - |
<1 | not classified | not classified | - | |
2,2,4,6,6-pentamethylheptane | 13475-82-6 236-757-0 - |
ca. 0,3 | Flam. Liq. 3; H226 Asp. Tox. 1; H304 Aquatic Chronic 1; H410 EUH066 |
Xn; R65 R10 |
01-2119490725-29 | |
naphtha (petroleum), hydrodesulphurized heavy [P] | 64742-82-1 265-185-4 649-330-00-2 |
ca. 0,1 | Flam. Liq. 3; H226 Asp. Tox. 1; H304 STOT SE 3; H336 Aquatic Chronic 2; H411 |
Xn; R65 N; R51/53 R10-66 |
01-2119490979-12 |
P | The classification as a carcinogen or mutagen need not apply if it can be shown that the substance contains less than 0,1 % w/w benzene (Einecs No 200-753-7). When the substance is not classified as a carcinogen at least the precautionary statements (P102-)P260- P262-P301 + P310-P331 shall apply. This note applies only to certain complex oil-derived substances in Part 3. |
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Do not breathe dust/fume/gas/mist/vapors/spray. Never give anything by mouth to an unconscious person. Place patient in recovery position and ensure airway patency. When in doubt or if feeling unwell seek medical assistance. Show the safety data sheet and label to the physician.
No action shall be taken involving any personal risk or without suitable training. When it is suspected, that there may still be harmful vapours/fumes present in the air, respiratory protection (mask; self contained breathing apparatus) must be used. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Use personal protective equipment. See section 8 for more information.
Remove patient to fresh air - move out of dangerous area. Keep at rest in a position comfortable for breathing. If breathing is irregular or respiratory arrest occurs provide artificial respiration. Seek medical help immediately.
Take off all contaminated clothing. Wash affected skin areas thoroughly with plenty of water and soap. If symptoms develop and persist, seek medical attention.
Immediately flush eyes with running water, keeping eyelids apart. If irritation persists, seek professional medical attention.
Do not induce vomiting! Rinse mouth thoroughly with water. Never give anything by mouth to an unconscious person. Consult a physician. Show the physician the safety data sheet or label.
Can cause irritation of respiratory system.
Coughing, sneezing, nasal discharge, labored breathing.
May cause allergic respiratory reaction.
Long-term inhalation may cause severe damage to the health.
Irritating to the skin.
Itching, redness, pain.
May cause sensitisation by skin contact (symptoms: itching, redness, rashes).
Causes severe eye irritation.
Redness, tearing, pain.
May cause abdominal discomfort.
May cause nausea/vomiting and diarrhea.
Irritates mucous membranes in the mouth, throat, esophagus and in gastrointestinal area.
Treat symptomatically.
Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.
Alcohol-resistant foam.
Fire extinguishing powder.
Carbon dioxide (CO2).
Full water jet. Do not use water jet as an extinguisher, as this will spread the fire.
In case of a fire toxic gases can be generated; do not inhale gases/smoke. Vapours and air can form explosive mixtures. The vapor/gas is heavier than air and will spread along the ground. In the event of fire the following can be generated: carbon monoxide (CO), carbon dioxide (CO2).
Prolonged heating can cause an explosion. Vapours can form explosive mixtures with air. In case of fire or heating do not breathe fumes/vapours. Cool containers at risk with water spray. If possible remove containers from endangered area. No action shall be taken involving any personal risk or without suitable training.
Firefighters should wear appropriate protective clothing for firefighters (including helmets, protective boots and gloves) (EN 469) and self-contained breathing apparatus (SCBA) with a full face-piece (EN 137).
Contaminated firefighting water and fire residues must be disposed of in accordance with the local regulations.
Use personal protective equipment (Section 8).
Ensure adequate ventilation. Keep away from sources of ignition and/or heat; No smoking! Take precautionary measures against static discharges. Prevent access to unprotected personnel. No action shall be taken involving any personal risk or without suitable training. Evacuate the danger zone. Do not breathe vapour or mist. Avoid contact with skin, eyes and clothing.
During intervention, use personal protective equipment (Section 8).
Do not allow product to reach water/drains/sewage systems or permeable soil. If accidental large entry into water or ground occurs, inform responsible authorities.
Stem the spill if this does not pose risks.
Absorb product (with inert material), collect it in special container and dispose it to a licensed hazardous-waste disposal contractor. Clean contaminated area with plenty of water. Use spark-proof tools. Ventilate the premises. Use only explosion-proof instruments and equipment. Prevent release into the sewer, water, basements or confined areas.
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See also Sections 8 and 13.
Ensure adequate ventilation. Take precautionary measures against static discharges. Keep away from sources of ignition - no smoking. Use spark-proof tools. Ensure proper grounding of the equipment. Vapours are heavier than air and spread along the floor. They form explosive mixtures with air. In order to avoid the risk of fires and explosions, never use compressed air when handling. Empty containers may contain flammable product residues. Do not weld, solder, drill, cut.
Use general or local exhaust ventilation to prevent inhaling vapours and aerosols.
Do not discharge into drains, surface water and soil. After use immediately close container tightly.
Do not eat, drink or smoke while working. Do not breathe vapours/mist. Use good personal hygiene practices – wash hands at breaks and when done working with material. Avoid contact with skin, eyes and clothes. Remove contaminated clothes and wash them before reuse. Wear suitable protective equipment; see Section 8. In case of insufficient ventilation, wear suitable respiratory protection equipment.
Store in accordance with local regulations. Protect from open fire, heat and direct sunlight. Keep away from food, drink and animal feeding stuffs. Keep away from sources of ignition - no smoking. Keep in a cool, dry and well ventilated place. Store below 30°C. Keep away from strong oxidising agents. Keep away from peroxides. Keep away from reducing agents.
Store only in original container. Metallic GRP containers.
Close opened containers after use. Put the containers upright to prevent from leaking. Do not store in unlabelled containers.
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See identified uses in Section 1.2.
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Name (CAS) | Limit values | Short-term exposure limit | Remarks | Biological Tolerance Values | ||
---|---|---|---|---|---|---|
ml/m3 (ppm) |
mg/m3 |
ml/m3 (ppm) |
mg/m3 |
|||
Phthalic anhydride (85-44-9) | 4 | 12 | Sen | |||
Styrene (100-42-5) | 100 | 430 | 250 | 1080 | ||
styrene (100-42-5) | 50 | 215 | 100 | 425 | India; source: Ministry of Labour and Employment, Permissible Levels of Certain Chemical substances in work environment |
BS EN 14042:2003 Title Identifier: Workplace atmospheres. Guide for the application and use of procedures for the assessment of exposure to chemical and biological agents. BS EN 482:2021 Workplace exposure. Procedures for the determination of the concentration of chemical agents. Basic performance requirements.
Name | Type | Exposure route | Exposure frequency | Value | Remark |
---|---|---|---|---|---|
styrene (100-42-5) | Worker | inhalation | long term (systemic effects) | 85 mg/m3 | |
styrene (100-42-5) | Worker | inhalation | short term (systemic effects) | 289 mg/m3 | |
styrene (100-42-5) | Worker | inhalation | short term (local effects) | 306 mg/m3 | |
styrene (100-42-5) | Worker | dermal | long term (systemic effects) | 406 mg/kg bw/day | |
styrene (100-42-5) | Consumer | inhalation | long term (systemic effects) | 10,2 mg/m3 | |
styrene (100-42-5) | Consumer | inhalation | short term (systemic effects) | 174,25 mg/m3 | |
styrene (100-42-5) | Consumer | inhalation | short term (local effects) | 182,75 mg/m3 | |
styrene (100-42-5) | Consumer | dermal | long term (systemic effects) | 343 mg/kg bw/day | |
styrene (100-42-5) | Consumer | oral | long term (systemic effects) | 2,1 mg/kg bw/day |
Name | Exposure route | Value | Remark |
---|---|---|---|
styrene (100-42-5) | fresh water | 0,028 mg/L | |
styrene (100-42-5) | marine water | 0,0028 mg/L | |
styrene (100-42-5) | water treatment plant | 5 mg/L | microorganisms |
styrene (100-42-5) | fresh water sediment | 0,614 mg/kg | dry weight |
styrene (100-42-5) | marine water sediment | 0,0614 mg/kg | dry weight |
styrene (100-42-5) | soil | 0,2 mg/kg | dry weight |
styrene (100-42-5) | water, intermittent release | 0,04 mg/L | fresh water |
Do not breathe vapours/aerosols. Use good personal hygiene practices – wash hands at breaks and when done working with material. Handle in accordance with good industrial hygiene and safety practice. Do not eat, drink or smoke while working. Avoid contact with skin, eyes and clothes. When working in confined spaces (tanks, containers, etc.), ensure that there is a supply of air suitable for breathing and wear the recommended equipment.
Remove all contaminated clothes immediately and wash them before reuse.
Provide good ventilation and local exhaust in areas with increased concentration. Keep away from food, drink and animal feeding stuffs. The use of adequate technical equipment must always take priority over personal protective equipment.
Safety glasses with side protection (EN 166). Do not use contact lenses.
Protective gloves (EN 374). The penetration time is determined by the protective glove manufacturer and must be observed. Observe the manufacturer's instructions regarding the use, storage, maintenance and replacement of gloves. In case of damage or at the first signs of wear and tear, change the gloves immediately. The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. Gloves should be removed and replaced immediately if there is any indication of degradation or chemical breakthrough.
Material | Thickness | Penetration Time | Remark |
---|---|---|---|
Neoprene | EN 374 | ||
Nitrile | EN 374 | ||
Viton (fluorinated rubber) | EN 374 | ||
PVA | EN 374 |
Clothing for protection against chemical risks, with antistatic and fireproof properties. Protective antistatic clothing EN 1149 (1:2006, 2:1998 and 3:2004, 5:2008), protective antistatic shoes (EN 20345:2012).
In case of insufficient ventilation wear suitable respiratory protection. In case of insufficient ventilation wear mask with filter A (EN 14387). 'High/elevated concentrations' means that the occupational exposure limit values have been exceeded. In case of dust formation wear appropriate protective mask - mask with particle filter. Protective masks (EN 136) or half masks (EN 140) with filter AP2 (EN 14387).
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Do not allow product to reach drains, sewage systems or ground water.
- | Physical state: | liquid |
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- | Colour: | beige |
- | Odour: | styren like |
- | pH | No information. |
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- | Melting point/freezing point | No information. |
- | Initial boiling point/boiling range | No information. |
- | Flash point | 31 °C |
- | Evaporation rate | No information. |
- | Flammability (solid, gas) | No information. |
- | Explosion limits (vol%) | 0,9 – 6,1 vol % 1,1 – 6,8 vol % |
- | Vapour pressure | 6 hPa at 20 °C |
- | Vapour density | No information. |
- | Density | Density: 1,1 – 1,4 g/cm3 at 20 °C |
- | Solubility | Water: Insoluble Organic solvent: Soluble |
- | Partition coefficient | No information. |
- | Auto-ignition temperature | 490 °C |
- | Decomposition temperature | No information. |
- | Viscosity | Dynamic: 400 – 700 cP at 22 °C |
- | Explosive properties | No information. |
- | Oxidising properties | No information. |
- | Particle characteristics | No information. |
- | Remarks: | Flammability Limits in Air: Upper 6.1 – 6.8%; Lower 0.9 – 1.1%. Soluble in most organic solvents. |
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Temperature above flashpoint: higher fire/explosion hazard.
Product is stable under normal conditions of use, recommended handling and storage conditions.
Vapours and air can form flammable or explosive mixtures. The risk of polymerization.
Protect from heat, direct sunlight, open fire, sparks. Avoid light. Take precautionary measures against static discharges.
Strong oxidising agents.
Peroxide. Reducing agents.
Under normal use conditions no hazardous decomposition products are expected. In case of fire/explosion vapours/gases that pose a health hazard are released. Carbon dioxide; Carbon monoxide.
Name | Exposure route | Type | Species | Time | Value | Method | Remark |
---|---|---|---|---|---|---|---|
styrene (100-42-5) | oral | LD50 | rat | 5000 mg/kg | |||
styrene (100-42-5) | dermal | LD50 | rat | 24 h | > 2000 mg/kg bw | OECD 402 | |
styrene (100-42-5) | inhalation | LC50 | rat | 4 h | 11,8 mg/l | ||
phthalic anhydride (85-44-9) | oral | LD50 | rat | 1530 mg/kg bw | |||
phthalic anhydride (85-44-9) | dermal | LD50 | rabbit | > 3160 mg/kg bw | |||
phthalic anhydride (85-44-9) | inhalation | LC50 | rat | 4 h | > 2,14 mg/l | ||
Amorphous Silica (112945-52-5) | dermal | LD50 | rabbit | > 5000 mg/kg | |||
Amorphous Silica (112945-52-5) | inhalation | LC50 | rat | 4 h | > 0,14 mg/l | OECD 403 | |
2,2,4,6,6-pentamethylheptane (13475-82-6) | oral | LD50 | rat | > 5000 mg/kg bw | OECD 401 | ||
2,2,4,6,6-pentamethylheptane (13475-82-6) | dermal | LD50 | rabbit | ≥ 3160 mg/kg bw | |||
2,2,4,6,6-pentamethylheptane (13475-82-6) | inhalation | LC50 | rat | 4 h | > 4,95 mg/l | Equivalent to OECD 403 | |
Additional information: The product is not classified for acute toxicity. |
Name | Species | Time | Result | Method | Remark |
---|---|---|---|---|---|
styrene (100-42-5) | rabbit | Irritating. | |||
phthalic anhydride (85-44-9) | rabbit | Irritating. | OECD 404 | ||
Amorphous Silica (112945-52-5) | rabbit | Non-irritant. | OECD 404 | ||
2,2,4,6,6-pentamethylheptane (13475-82-6) | rabbit | Non-irritant. | Equivalent to OECD 404 | ||
Additional information: Causes skin irritation. |
Name | Species | Time | Result | Method | Remark |
---|---|---|---|---|---|
styrene (100-42-5) | rabbit | Irritating. | |||
phthalic anhydride (85-44-9) | rabbit | Irritating to eyes. | Draize test | ||
Amorphous Silica (112945-52-5) | rabbit | No irritant effect. | OECD 405 | ||
2,2,4,6,6-pentamethylheptane (13475-82-6) | rabbit | No irritant effect. | OECD 405 | ||
Additional information: Causes serious eye damage. |
Name | Exposure route | Species | Time | Result | Method | Remark |
---|---|---|---|---|---|---|
styrene (100-42-5) | - | Non sensitising. | ||||
phthalic anhydride (85-44-9) | dermal | guinea pig | Sensitizing. | OECD 406 | ||
phthalic anhydride (85-44-9) | inhalation | guinea pig | Sensitizing. | |||
Amorphous Silica (112945-52-5) | dermal | Non sensitising. | ||||
Amorphous Silica (112945-52-5) | inhalation | Non sensitising. | ||||
2,2,4,6,6-pentamethylheptane (13475-82-6) | dermal | guinea pig | Negative. | OECD 406 | ||
Additional information: The product is not classified as sensitising. |
Name | Type | Species | Time | Result | Method | Remark |
---|---|---|---|---|---|---|
styrene (100-42-5) | in-vitro mutagenicity | Bacteria | Ambiguous. | OECD 471 | S.typhimurium G46,TA1530, TA1535, TA100, TA98, TA1538, TA1537 | |
styrene (100-42-5) | in-vitro mutagenicity | Cell: Mammalian-Animal | Equivocal | OECD 476 | Hamster | |
styrene (100-42-5) | in-vitro mutagenicity | Positive. | OECD 473, 479 | Chromosome aberration assay | ||
styrene (100-42-5) | in-vivo mutagenicity | mouse | Negative. | OECD 474, 486 | ||
phthalic anhydride (85-44-9) | in-vitro mutagenicity | S.typhimurium TA 1535, TA 1537, TA 98, TA 100 and TA102; Escherichia coli WP2 uvrA | Negative. | OECD 471 | ||
phthalic anhydride (85-44-9) | in-vitro mutagenicity | Cell: Mammalian-Animal | Negative. | OECD 476 | Hamster | |
phthalic anhydride (85-44-9) | in-vitro mutagenicity | hamster | Equivocal | OECD 473 | Chromosome aberration assay | |
Amorphous Silica (112945-52-5) | in-vitro mutagenicity | Negative. | OECD 471 (Bacterial Reverse Mutation Test) | Ames test | ||
Amorphous Silica (112945-52-5) | in-vitro mutagenicity | Cell: Mammalian-Animal | Negative. | OECD 476 | ||
Amorphous Silica (112945-52-5) | in-vitro mutagenicity | Negative. | OECD 473 | Chromosome aberration assay | ||
Amorphous Silica (112945-52-5) | in-vivo mutagenicity | rat | Negative. | |||
2,2,4,6,6-pentamethylheptane (13475-82-6) | in-vitro mutagenicity | S. typhimurium, other: S. typhimurium TA1535, TA1537, TA98, TA100 and TA1538 | Negative. | Equivalent to OECD 471 | ||
2,2,4,6,6-pentamethylheptane (13475-82-6) | in-vitro mutagenicity | Mammalian cells - hamster | Negative. | Equivalent to OECD 476 | ||
2,2,4,6,6-pentamethylheptane (13475-82-6) | in-vitro mutagenicity | Negative. | Equivalent to OECD 473 | Chromosome aberration assay | ||
2,2,4,6,6-pentamethylheptane (13475-82-6) | in-vivo mutagenicity | mouse | Negative. | Equivalent to OECD 474 |
Name | Exposure route | Type | Species | Time | Value | Result | Method | Remark |
---|---|---|---|---|---|---|---|---|
styrene (100-42-5) | inhalation | NOAEC | rat | ≥ 4,34 mg/m3 air | negative | OECD 453 | ||
styrene (100-42-5) | inhalation (vapours) | LOAEC | mouse (male/female) | 0,09 – 0,18 mg/l | Positive | OECD 453 | ||
styrene (100-42-5) | oral | NOAEL | rat | ≥ 2000 mg/kg bw/day | positive | |||
styrene (100-42-5) | oral | LOAEL | mouse | 150 mg/kg bw/day | Positive | |||
phthalic anhydride (85-44-9) | oral | NOAEL | rat | 105 weeks | 1000 mg/kg bw/day | negative | ||
phthalic anhydride (85-44-9) | oral | NOAEL | mouse (male) | 72 weeks | 3570 mg/kg bw/day | negative | ||
phthalic anhydride (85-44-9) | oral | NOAEL | mouse (female) | 72 weeks | 1785 mg/kg bw/day | negative | ||
Amorphous Silica (112945-52-5) | oral | NOAEL | rat | 1800 – 3200 mg/kg bw/day | negative | OECD 453 |
Name | Reproductive toxicity type | Type | Species | Time | Value | Result | Method | Remark |
---|---|---|---|---|---|---|---|---|
styrene (100-42-5) | Effects on fertility | NOAEL/LOAEL | rat | 60 days | 100 – 200 mg/kg bw/day | Positive. | Inhalation | |
styrene (100-42-5) | Effects on fertility | NOAEL/LOAEL | rat | 60 days | 200 – 400 mg/kg bw/day | Positive. | OECD 422 | oral |
styrene (100-42-5) | Reproductive toxicity | LOAEC (P, F1) | rat | 2,13 mg/L | Negative. | two-generation study; OECD 416 | Inhalation | |
styrene (100-42-5) | Reproductive toxicity | NOAEC (P, F1) | rat | 0,64 mg/L | Negative. | two-generation study; OECD 416 | Inhalation | |
styrene (100-42-5) | Reproductive toxicity | NOAEC (F2) | rat | 0,21 mg/L | Negative. | two-generation study; OECD 416 | Inhalation | |
styrene (100-42-5) | Reproductive toxicity | LOAEC (F2) | rat | 70 days | 0,64 mg/L | Negative. | two-generation study; OECD 416 | Inhalation |
styrene (100-42-5) | Maternal toxicity + developmental toxicity | NOAEC/LOAEC | rat | 50 days | 1,08 – 2,15 mg/L | Positive. | Inhalation | |
styrene (100-42-5) | Maternal toxicity | LOAEC | rat | 1,28 mg/L | Positive. | OECD 414 | 6-15 days; inhalation | |
styrene (100-42-5) | Developmental toxicity | NOAEC | rat | ≥ 2,56 mg/L | Negative. | OECD 414 | 6-15 days; inhalation | |
styrene (100-42-5) | Maternal toxicity + developmental toxicity | NOAEC | rabbit | 2,56 mg/L | Negative. | OECD | 6-18 days; inhalation | |
phthalic anhydride (85-44-9) | Reproductive toxicity | NOAEL | mouse (male) | 72 weeks | 3570 mg/kg bw/day | Negative. | oral | |
phthalic anhydride (85-44-9) | Reproductive toxicity | NOAEL | mouse (female) | 72 weeks | 1785 mg/kg bw/day | Negative. | oral | |
phthalic anhydride (85-44-9) | Reproductive toxicity | NOAEL | rat (female) | 105 weeks | 1000 mg/kg bw/day | Negative. | oral | |
phthalic anhydride (85-44-9) | Maternal toxicity | NOAEL | rat | 1000 mg/kg bw/day | Positive. | oral | ||
phthalic anhydride (85-44-9) | Teratogenicity | NOAEL | rat | 1700 mg/kg bw/day | Positive. | oral | ||
Amorphous Silica (112945-52-5) | Reproductive toxicity | NOAEL | rat | 497 mg/kg bw/day | Negative. | OECD 415 | oral | |
Amorphous Silica (112945-52-5) | Teratogenicity | NOAEL | rat | 1350 mg/kg bw/day | Negative. | OECD 414 | oral | |
Amorphous Silica (112945-52-5) | Maternal toxicity | NOAEL | rat | 1350 mg/kg bw/day | Negative. | OECD 414 | oral | |
2,2,4,6,6-pentamethylheptane (13475-82-6) | oral | NOAEL | rat | ≥ 1000 mg/kg bw/day | Negative. | Equivalent to OECD 422 | P/F1 | |
2,2,4,6,6-pentamethylheptane (13475-82-6) | Developmental toxicity | NOAEL | rat (female) | 15 days | ≥ 5220 mg/m³ | Negative. | Equivalent to OECD 414 |
Suspected of damaging the unborn child.
Name | Exposure route | Type | Species | Time | Organ | Value | Result | Method | Remark |
---|---|---|---|---|---|---|---|---|---|
phthalic anhydride (85-44-9) | inhalation | - | May cause respiratory irritation. | ||||||
Additional information: May cause respiratory irritation. |
Name | Exposure route | Type | Species | Time | Organ | Value | Result | Method | Remark |
---|---|---|---|---|---|---|---|---|---|
styrene (100-42-5) | - | - | ear | Causes damage to organs through prolonged or repeated exposure. | |||||
styrene (100-42-5) | inhalation | NOAEC | rat (male) | 28 days | 3,47 mg/L air | ||||
styrene (100-42-5) | inhalation | NOAEC | 28 days | 2,13 mg/L | ototoxicity | ||||
styrene (100-42-5) | inhalation | NOAEC | mouse | 28 days | 0,181 mg/L | OECD 412 | |||
styrene (100-42-5) | inhalation | NOAEC | rat | 28 days | 0,688 mg/L | OECD 412 | |||
styrene (100-42-5) | inhalation | NOAEC | rat | 90 days | nose | 0,85 mg/L | |||
styrene (100-42-5) | inhalation | NOAEC | rat | 90 days | overall | 2,13 mg/L | |||
styrene (100-42-5) | oral | NOAEL | rat | 1000 mg/kg bw/day | |||||
styrene (100-42-5) | oral | LOAEL | rat | 2000 mg/kg bw/day | |||||
styrene (100-42-5) | oral | NOAEL | mouse | 150 mg/kg bw/day | |||||
styrene (100-42-5) | oral | LOAEL | mouse | 300 mg/kg bw/day | |||||
styrene (100-42-5) | inhalation | LOAEC | rat | 0,21 mg/L | OECD 453 | ||||
phthalic anhydride (85-44-9) | oral | NOAEL | rat | 7 weeks | 1250 mg/kg bw/day | ||||
phthalic anhydride (85-44-9) | oral | LOAEL | rat | 7 weeks | 2500 mg/kg bw/day | ||||
phthalic anhydride (85-44-9) | oral | NOAEL | rat | 105 weeks | 500 mg/kg bw/day | ||||
phthalic anhydride (85-44-9) | oral | LOAEL | mouse (male/female) | 72 weeks | 1717 – 2340 mg/kg bw/day | ||||
Amorphous Silica (112945-52-5) | oral | NOAEL | rat | 4000 – 4500 mg/kg/day | OECD 408 | ||||
Amorphous Silica (112945-52-5) | inhalation | NOEC | rat | 1,3 mg/m3 | |||||
Amorphous Silica (112945-52-5) | inhalation | NOEC | rat | 90 days | < 1,3 mg/m3 | OECD 413 | |||
Amorphous Silica (112945-52-5) | dermal | NOAEL | rabbit | ≥ 10000 mg/kg bw/day | |||||
2,2,4,6,6-pentamethylheptane (13475-82-6) | inhalation | NOAEC | mouse | 17 days | ≥ 400 ppm | Equivalent to OECD 412 | |||
2,2,4,6,6-pentamethylheptane (13475-82-6) | oral | NOAEL | rat | 13 weeks | ≥ 1000 mg/kg | Equivalent to OECD 408 | |||
2,2,4,6,6-pentamethylheptane (13475-82-6) | inhalation | NOAEL | rat | 13 weeks | ≥ 1,16 mg/m3 | OECD 413 | |||
2,2,4,6,6-pentamethylheptane (13475-82-6) | inhalation | NOAEC | rat | 105 weeks | ≥ 400 ppm | ||||
2,2,4,6,6-pentamethylheptane (13475-82-6) | inhalation | NOAEC | rat | 105 weeks | 25 ppm | Equivalent to OECD 453 | |||
Additional information: Causes damage to organs through prolonged or repeated exposure. |
Additional information: Due to viscosity, this product does not present an aspiration hazard. Aspiration hazard: Not classified. |
No information.
No information.
Substance (CAS Nr.) | Type | Value | Exposure time | Species | Organism | Method | Remark |
---|---|---|---|---|---|---|---|
styrene (100-42-5) | LC50 | 4,9 mg/L | 72 h | algae | Pseudokirchneriella subcapitata | EPA OTS 797.1050 | |
EC50 | 4,7 mg/L | 48 h | crustacea | Daphnia magna | OECD 202 | ||
NOEC | 1,9 mg/L | crustacea | Daphnia magna | OECD 202 | |||
LC50 | 4,02 mg/L | 96 h | fish | Pimephales promelas | OECD 203 | ||
- | 500 mg/L | 30 min | bacteria | Activated sludge | OECD 209 | ||
phthalic anhydride (85-44-9) | NOEC | 32 mg/L | 72 h | algae | Pseudokirchneriella subcapitata | OECD 201 | |
LC50 | > 99 mg/L | 96 h | fish | Oryzias latipes | OECD 203 | ||
EC50 | > 1000 mg/L | 3 h | microorganisms | Activated sludge | ISO 8192 | ||
EC50 | 13 mg/L | 16 h | microorganisms | Pseudomonas putida | ISO 10712 | ||
EC50 | 731 mg/L | Plants | Lactuca sativa | ||||
EC50 | 68 mg/L | 72 h | algae | ||||
EC50 | 71 mg/L | 48 h | crustacea | Daphnia magna | OECD 202 | ||
Amorphous Silica (112945-52-5) | EC50 | ≥ 1000 mg/L | 24 h | crustacea | Daphnia magna | OECD 202 | |
LC50 | > 10000 mg/L | 96 h | fish | Brachydanio rerio | OECD 203 | ||
2,2,4,6,6-pentamethylheptane (13475-82-6) | EC50 | > 22,5 mg/L | 72 h | algae | Desmodesmus subspicatus | OECD 201 | |
EC50 | > 1,3 mg/L | 48 h | crustacea | Daphnia magna | ASTM E729-88 | ||
LC50 | > 2,8 mg/L | 96 h | fish | Danio rerio | OECD 203 |
Substance (CAS Nr.) | Type | Value | Exposure time | Species | Organism | Method | Remark |
---|---|---|---|---|---|---|---|
styrene (100-42-5) | NOEC | 1,01 mg/l | 21 days | crustacea | Daphnia magna | ||
LOEC | 2,06 mg/l | 21 days | crustacea | Daphnia magna | |||
EC50 | 1,88 mg/l | 21 days | crustacea | Daphnia magna | OECD 203 | ||
LC50 | 120 mg/kg soil dw | 14 days | earthworms | Eisenia fetida | OECD 207 | ||
LOEC | 65 mg/kg soil dw | earthworms | Eisenia fetida | OECD 207 | burrowing time and mean percent weight change | ||
LOEC | 180 mg/kg soil dw | earthworms | Eisenia fetida | OECD 207 | survival | ||
NOEC | 34 mg/kg soil dw | earthworms | Eisenia fetida | OECD 207 | mean percent weight change | ||
phthalic anhydride (85-44-9) | NOEC | 16 mg/l | 21 days | crustacea | Daphnia magna | OECD 211 | |
EC50 | 42 mg/l | 21 days | crustacea | Daphnia magna | OECD 211 | ||
LC50 | 560 mg/l | 7 days | fish | Danio rerio | OECD 210 | ||
LOEC | 32 mg/l | 60 days | fish | ||||
NOEC | 10 mg/l | 60 days | fish | OECD 210 | |||
2,2,4,6,6-pentamethylheptane (13475-82-6) | NOEC | 0,013 mg/l | 21 days | crustacea | Daphnia magna | OECD 211 | |
NOELR | 0,267 mg/l | 28 days | fish | Oncorhynchus mykiss | QSAR |
No information.
Substance (CAS Nr.) | Type | Rate | Time | Evaluation | Method | Remark |
---|---|---|---|---|---|---|
styrene (100-42-5) | biodegradability | 87 % | 20 days | readily biodegradable | Similar to OECD 301D | |
phthalic anhydride (85-44-9) | biodegradability | 68 % | 10 days | readily biodegradable | OECD 301 D | |
phthalic anhydride (85-44-9) | biodegradability | 74 % | 30 days | readily biodegradable | OECD 301 D | |
2,2,4,6,6-pentamethylheptane (13475-82-6) | biodegradability | 14 | 31 days | Not inherently degradable | EPA OTS 796.3100 |
Substance (CAS Nr.) | Media | Value | Temperature | pH | Concentration | Method |
---|---|---|---|---|---|---|
styrene (100-42-5) | Log Pow | 3 | ||||
phthalic anhydride (85-44-9) | Log Pow | 1,6 |
Substance (CAS Nr.) | species | Organism | Value | Duration | Evaluation | Method | Remark |
---|---|---|---|---|---|---|---|
styrene (100-42-5) | BCF | 74 | Calculated value | ||||
phthalic anhydride (85-44-9) | BCF | 3,16 – 3,4 | Calculated value |
No information.
No information.
Substance (CAS Nr.) | Type | Criterion | Value | Evaluation | Method | Remark |
---|---|---|---|---|---|---|
styrene (100-42-5) | Soil | 352 | Koc | |||
styrene (100-42-5) | Soil | log KOC | 2,55 | |||
phthalic anhydride (85-44-9) | Soil | 31 | Koc |
No evaluation.
No information.
Harmful to aquatic life with long lasting effects.
Do not allow to reach ground water, water courses or sewage system.
Substance: styrene
This substance is not considered to be persistent, bioaccumulative and toxic (PBT). This substance is not considered to be very persistent and very bioaccumulative (vPvB).
Substance: phthalic anhydride
This substance is not considered to be persistent, bioaccumulative and toxic (PBT). This substance is not considered to be very persistent and very bioaccumulative (vPvB).
Substance: Amorphous Silica
This substance is not considered to be persistent, bioaccumulative and toxic (PBT). This substance is not considered to be very persistent and very bioaccumulative (vPvB).
Substance: 2,2,4,6,6-pentamethylheptane
This substance is not considered to be persistent, bioaccumulative and toxic (PBT). This substance is not considered to be very persistent and very bioaccumulative (vPvB).
Dispose of in accordance with applicable waste disposal regulation. Disposal must be made according to official regulations: deliver it to authorised collector/remover/transformer of hazardous waste. Do not allow product to reach drains/sewage systems.
Dispose of in accordance with applicable waste disposal regulation. Uncleaned containers are classified as hazardous waste - they should be handled in the same manner as the contents. Deliver completely emptied containers to approved waste disposal authorities. Uncleaned containers should not be perforated, cut or welded. Empty containers represent a fire hazard as they may contain flammable product residues and vapour.
-
-
-
UN 1866
RESIN SOLUTION
3
III
NO.
5 L
(D/E)
31 °C, c.c.
F-E, S-E
Goods may not be carried in bulk in bulk containers, containers or vehicles.
- Regulation (EC) No 1907/2006 concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH)(including last amendment Commission Regulation (EU) 2020/878)
- Regulation (EC) No 1272/2008 on classification, labelling and packaging of substances and mixtures
Not applicable.
Seveso P5c: FLAMMABLE LIQUIDS.
No Chemical Safety Assessment has been carried out for this substance/mixture by the supplier.
-
ATE - Acute Toxicity Estimate
ADR - Agreement concerning the International Carriage of Dangerous Goods by Road
ADN - European Agreement concerning the International Carriage of Dangerous Goods by Inland Waterways
CEN - European Committee for Standardisation
C&L - Classification and Labelling
CLP - Classification Labelling Packaging Regulation; Regulation (EC) No 1272/2008
CAS# - Chemical Abstracts Service number
CMR - Carcinogen, Mutagen, or Reproductive Toxicant
CSA - Chemical Safety Assessment
CSR - Chemical Safety Report
DMEL - Derived Minimal Effect Level
DNEL - Derived No Effect Level
DPD - Dangerous Preparations Directive 1999/45/EC
DSD - Dangerous Substances Directive 67/548/EEC
DU - Downstream User
EC - European Community
ECHA - European Chemicals Agency
EC-Number - EINECS and ELINCS Number (see also EINECS and ELINCS)
EEA - European Economic Area (EU + Iceland, Liechtenstein and Norway)
EEC - European Economic Community
EINECS - European Inventory of Existing Commercial Substances
ELINCS - European List of notified Chemical Substances
EN - European Standard
EQS - Environmental Quality Standard
EU - European Union
Euphrac - European Phrase Catalogue
EWC - European Waste Catalogue (replaced by LoW – see below)
GES - Generic Exposure Scenario
GHS - Globally Harmonized System
IATA - International Air Transport Association
ICAO-TI - Technical Instructions for the Safe Transport of Dangerous Goods by Air
IMDG - International Maritime Dangerous Goods
IMSBC - International Maritime Solid Bulk Cargoes
IT - Information Technology
IUCLID - International Uniform Chemical Information Database
IUPAC - International Union for Pure Applied Chemistry
JRC - Joint Research Centre
Kow - octanol-water partition coefficient
LC50 - Lethal Concentration to 50 % of a test population
LD50 - Lethal Dose to 50% of a test population (Median Lethal Dose)
LE - Legal Entity
LoW - List of Wastes (see http://ec.europa.eu/environment/waste/framework/list.htm)
LR - Lead Registrant
M/I - Manufacturer / Importer
MS - Member States
MSDS - Material Safety Data Sheet
OC - Operational Conditions
OECD - Organization for Economic Co-operation and Development
OEL - Occupational Exposure Limit
OJ - Official Journal
OR - Only Representative
OSHA - European Agency for Safety and Health at work
PBT - Persistent, Bioaccumulative and Toxic substance
PEC - Predicted Effect Concentration
PNEC(s) - Predicted No Effect Concentration(s)
PPE - Personal Protection Equipment
(Q)SAR - Qualitative Structure Activity Relationship
REACH - Registration, Evaluation, Authorisation and Restriction of Chemicals
Regulation (EC) No 1907/2006
RID - Regulations concerning the International Carriage of Dangerous Goods by Rail
RIP - REACH Implementation Project
RMM - Risk Management Measure
SCBA - Self-Contained Breathing Apparatus
SDS - Safety data sheet
SIEF - Substance Information Exchange Forum
SME - Small and Medium sized Enterprises
STOT - Specific Target Organ Toxicity
(STOT) RE - Repeated Exposure
(STOT) SE - Single Exposure
SVHC - Substances of Very High Concern
UN - United Nations
vPvB - Very Persistent and Very Bioaccumulative
Safety data sheet Roofcell Basecoat, G&B (North West) Ltd., date 16.03.2021, version 1.
H226 Flammable liquid and vapour.
H302 Harmful if swallowed.
H304 May be fatal if swallowed and enters airways.
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H318 Causes serious eye damage.
H319 Causes serious eye irritation.
H332 Harmful if inhaled.
H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled.
H335 May cause respiratory irritation.
H336 May cause drowsiness or dizziness.
H361d Suspected of damaging the unborn child.
H372 Causes damage to organs through prolonged or repeated exposure .
H410 Very toxic to aquatic life with long lasting effects.
H411 Toxic to aquatic life with long lasting effects.
H412 Harmful to aquatic life with long lasting effects.
EUH066 Repeated exposure may cause skin dryness or cracking.