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SAFETY DATA SHEET according to Regulation 1907/2006 amended by 2020/878/EU
Product name:
Cure It Acetone
Creation date: 16.7.2019 |
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Cure It Acetone
acetone (CAS: 67-64-1, EC: 200-662-2, Index: 606-001-00-8)
01-2119471330-49
UFI: GM00-E0GJ-800K-1KHP
Solvent.
Do not use for purposes other than those prescribed.
SupplierG&B Northwest Ltd |
+44 (0) 3301 222666 Mon-Friday 8.30am – 4.30pm
Flam. Liq. 2; H225 Highly flammable liquid and vapour.
Eye Irrit. 2; H319 Causes serious eye irritation.
STOT SE 3; H336 May cause drowsiness or dizziness.
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Signal word: Danger
H225 Highly flammable liquid and vapour.
H319 Causes serious eye irritation.
H336 May cause drowsiness or dizziness.
EUH066 Repeated exposure may cause skin dryness or cracking.
P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P233 Keep container tightly closed.
P235 Keep cool.
P240 Ground and bond container and receiving equipment.
P241 Use explosion-proof electrical/ventilating/lighting equipment.
P242 Use non-sparking tools.
P243 Take action to prevent static discharges.
P261 Avoid breathing mist/vapours/spray.
P264 Wash hands, forearms and exposed areas thoroughly after handling.
P271 Use only outdoors or in a well-ventilated area.
P280 Wear protective gloves/protective clothing/eye protection.
P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water [or shower].
P304 + P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312 Call a POISON CENTER/doctor if you feel unwell.
P337 + P313 If eye irritation persists: Get medical advice/attention.
P370 + P378 In case of fire: Use appropriate media to extinguish.
P403 + P233 Store in a well-ventilated place. Keep container tightly closed.
P405 Store locked up.
P501 Dispose of contents/container in accordance with national regulation.
acetone
Special hazards are not known or expected.
In case of insufficient ventilation and/or through use, explosive/highly flammable mixtures may develop.
The components in this formulation do not meet the criteria for classification as PBT.
| Name | CAS EC Index |
% | Classification according to Regulation (EC) No 1272/2008 (CLP) |
Specific Conc. Limits | Classification according to directive 67/548/EEC or 99/45/EC | REACH Registration No. |
|---|---|---|---|---|---|---|
| acetone | 67-64-1 200-662-2 606-001-00-8 |
≤ 100 | Flam. Liq. 2; H225 Eye Irrit. 2; H319 STOT SE 3; H336 EUH066 |
F; R11 Xi; R36 R66-67 |
01-2119471330-49 |
For substances see 3.1.
Never give anything by mouth to an unconscious person. Place patient in recovery position and ensure airway patency. When in doubt or if feeling unwell seek medical assistance. Show the safety data sheet and label to the physician.
Remove patient to fresh air - move out of dangerous area. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. Obtain professional medical help!
Take off all contaminated clothing. Wash affected skin areas thoroughly with plenty of water and soap. If symptoms develop and persist, seek medical attention.
Immediately flush eyes with running water, keeping eyelids apart. If irritation persists, seek professional medical attention.
Do not induce vomiting! If vomiting occurs, the patient should hold the head lower than the hips, because it reduces the possibility of aspiration. Rinse mouth and drink plenty of water (only if the person is conscious). Immediately consult a doctor. Show the physician the safety data sheet or label.
Vapours may cause drowsiness and dizziness.
Excessive exposure to spray mist, fog, or vapours may cause respiratory irritation.
Coughing, sneezing, nasal discharge, labored breathing.
Repeated exposure may cause dry skin or cracked skin.
Contact with skin may cause irritation (redness, itching).
Redness, tearing, pain.
May cause abdominal discomfort.
May cause nausea/vomiting and diarrhea.
Irritates mucous membranes in the mouth, throat, esophagus and in gastrointestinal area.
Have eye wash facilities in place close to the operators’ work area to provide immediate first aid prior to medical attention. Severe cases of eye contact and ingestion should receive medical attention immediately.
Carbon dioxide. Dry chemical powder. Water spray. Alcohol resistant foam. Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.
Full water jet.
Highly flammable liquid and vapour. May form flammable/explosive vapour-air mixture. In case of a fire toxic gases can be generated; do not inhale gases/smoke.
In case of fire or heating do not breathe fumes/vapours. Cool containers at risk with water spray. If possible remove containers from endangered area. No action shall be taken involving any personal risk or without suitable training. In case of fire evacuate the area. Prolonged heating can cause an explosion. Fight fire from a reasonable distance.
Firefighters should wear appropriate protective clothing for firefighters (including helmets, protective boots and gloves) (EN 469) and self-contained breathing apparatus (SCBA) with a full face-piece (EN 137).
Contaminated firefighting water and fire residues must be disposed of in accordance with the local regulations.
Use personal protective equipment (Section 8).
Ensure adequate ventilation. Keep away from sources of ignition and/or heat; No smoking! Take precautionary measures against static discharges. Prevent accumulation of vapours - vapours and air can form explosive mixtures. Vapours can accumulate in low-lying areas. Evacuate the danger zone. Evacuate personnel. No action shall be taken involving any personal risk or without suitable training. Prevent access to unprotected personnel. Do not breathe vapour or mist. Avoid contact with skin, eyes and clothing. In the event of fire and/or explosion do not breathe fumes.
During intervention, use personal protective equipment (Section 8).
Do not allow product to reach water/drains/sewage systems or permeable soil. If accidental large entry into water or ground occurs, inform responsible authorities.
Stem the spill if this does not pose risks.
Prevent release into the sewer, water, basements or confined areas. Absorb product (with inert material), collect it in special container and dispose it to a licensed hazardous-waste disposal contractor. Make sure the leakage site is well aired. Use spark-proof tools. Dispose in accordance with applicable regulations (see Section 13).
See Section 7: safe handling. See Section 11 for additional information on health hazards. See Section 12: ECOLOGICAL INFORMATION.
See also Sections 8 and 13.
Ensure adequate ventilation. Take precautionary measures against static discharges. Ensure proper grounding of the equipment. Keep away from sources of ignition - no smoking. Use spark-proof tools. Vapours are heavier than air and spread along the floor. They form explosive mixtures with air. In order to avoid the risk of fires and explosions, never use compressed air when handling. Empty containers may contain flammable or explosive vapours.
Use general or local exhaust ventilation to prevent inhaling vapours and aerosols.
Do not discharge into drains, surface water and soil. After use immediately close container tightly.
Use good personal hygiene practices – wash hands at breaks and when done working with material. Do not eat, drink or smoke while working. Do not breathe vapours/mist. Avoid contact with skin, eyes and clothes. Remove contaminated clothes and wash them before reuse. Wear suitable protective equipment; see Section 8. In case of insufficient ventilation, wear suitable respiratory protection equipment. Avoid exposure - obtain special instructions before using. Refer to instructions on label and regulations for safety and health at work. Regular cleaning of equipment, work area and clothing is recommended.
Store in accordance with local regulations. Keep in a cool, dry and well ventilated place. Keep away from heat and sources of ignition. Keep away from food, drink and animal feeding stuffs. Keep away from incompatible products (see section 10).
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Close opened containers after use. Put the containers upright to prevent from leaking. Do not store in unlabelled containers. The empty containers contain the residues of the preparation and therefore can also pose a risk.
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See identified uses in Section 1.2.
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| Name (CAS) | Limit values | Short-term exposure limit | Remarks | Biological Tolerance Values | ||
|---|---|---|---|---|---|---|
| ml/m3 (ppm) |
mg/m3 |
ml/m3 (ppm) |
mg/m3 |
|||
| Acetone (67-64-1) | 500 | 1210 | 1500 | 3620 | ||
| acetone (67-64-1) | 750 | 1780 | 1000 | 2375 | India; source: Ministry of Labour and Employment, Permissible Levels of Certain Chemical substances in work environment | |
BS EN 14042:2003 Title Identifier: Workplace atmospheres. Guide for the application and use of procedures for the assessment of exposure to chemical and biological agents. BS EN 482:2021 Workplace exposure. Procedures for the determination of the concentration of chemical agents. Basic performance requirements.
| Name | Type | Exposure route | Exposure frequency | Value | Remark |
|---|---|---|---|---|---|
| acetone (67-64-1) | Worker | inhalation | long term (systemic effects) | 1210 mg/m3 | |
| acetone (67-64-1) | Worker | inhalation | short term (local effects) | 2420 mg/m3 | |
| acetone (67-64-1) | Worker | dermal | long term (systemic effects) | 186 mg/kg bw/day | |
| acetone (67-64-1) | Consumer | inhalation | long term (systemic effects) | 200 mg/m3 | |
| acetone (67-64-1) | Consumer | dermal | long term (systemic effects) | 62 mg/kg bw/day | |
| acetone (67-64-1) | Consumer | oral | long term (systemic effects) | 62 mg/kg bw/day |
| Name | Exposure route | Value | Remark |
|---|---|---|---|
| acetone (67-64-1) | fresh water | 10,6 mg/L | |
| acetone (67-64-1) | marine water | 1,06 mg/L | |
| acetone (67-64-1) | water treatment plant | 100 mg/L | |
| acetone (67-64-1) | fresh water sediment | 30,4 mg/kg | dry weight |
| acetone (67-64-1) | marine water sediment | 3,04 mg/kg | dry weight |
| acetone (67-64-1) | soil | 33,3 mg/kg | dry weight |
Handle in accordance with good industrial hygiene and safety practice. Use good personal hygiene practices – wash hands at breaks and when done working with material. Do not breathe vapours/aerosols. Do not eat, drink or smoke while working. Avoid contact with skin, eyes and clothes. Appropriate technical measures to reduce exposure of workers must be chosen depending on the specific use of the product and the resulting risk of exposure at the workplace.
Remove all contaminated clothes immediately and wash them before reuse. Keep eyewash bottles or personal eyewash units available at the workplace.
Provide good ventilation and local exhaust in areas with increased concentration. Keep away from food, drink and animal feeding stuffs.
Wear tight fitting protective goggles and/or face protection (EN 166:2001).
Protective gloves (EN 374). The penetration time is determined by the protective glove manufacturer and must be observed. Observe the manufacturer's instructions regarding the use, storage, maintenance and replacement of gloves. In case of damage or at the first signs of wear and tear, change the gloves immediately. The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. Wash hands after every use.
| Material | Thickness | Penetration Time | Remark |
|---|---|---|---|
| Butyl rubber | 0,3 mm | ≥ 8 h |
Protective antistatic clothing EN 1149 (1:2006, 2:1998 and 3:2004, 5:2008), protective antistatic shoes (EN 20345:2012). Immediately wash contaminated clothing before reuse.
In case of insufficient ventilation wear suitable respiratory protection. Protective masks (EN 136) or half masks (EN 140) with filter A (EN 14387). Wear suitable protective breathing mask (EN 136) with filter A2-P2 (EN 14387).
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Do not allow product to reach drains, sewage systems or ground water.
| - | Physical state: | liquid |
|---|---|---|
| - | Colour: | colourless |
| - | Odour: | pungent Odour threshold: 13 ppm |
| - | pH | No information. |
|---|---|---|
| - | Melting point/freezing point | No information. |
| - | Initial boiling point/boiling range | No information. |
| - | Flash point | -16,99 °C (closed cup) |
| - | Evaporation rate | No information. |
| - | Flammability (solid, gas) | No information. |
| - | Explosion limits (vol%) | 2 – 13 vol % |
| - | Vapour pressure | 433,3 hPa at 39,5 °C 245,3 hPa at 20 °C |
| - | Vapour density | No information. |
| - | Density | Density: 0,791 g/cm3 at 25 °C |
| - | Solubility | Water: miscible |
| - | Partition coefficient | Log Pow: -0,24 |
| - | Auto-ignition temperature | 465 °C |
| - | Decomposition temperature | No information. |
| - | Viscosity | No information. |
| - | Explosive properties | No information. |
| - | Oxidising properties | No information. |
| - | Particle characteristics | No information. |
| - | Remarks: | Surface tension: 23.2 mN/m at 20.0°C. |
|---|
No data available.
Product is stable under normal conditions of use, recommended handling and storage conditions.
No data available.
Protect from heat, direct sunlight, open fire, sparks. Take precautionary measures against static discharges. Avoid contact with incompatible materials.
Reducing agents. Bases.
Oxidants.
Acetone reacts violently with phosphorous oxychloride.
Under normal use conditions no hazardous decomposition products are expected. In case of fire/explosion vapours/gases that pose a health hazard are released.
| Name | Exposure route | Type | Species | Time | Value | Method | Remark |
|---|---|---|---|---|---|---|---|
| acetone (67-64-1) | oral | LD50 | rat | 5800 mg/kg | Behavioural: Altered sleep time, tremor, headache. Ingestion may cause gastrointestinal irritation, nausea, vomiting and diarrhoea. | ||
| acetone (67-64-1) | inhalation | LD50 | rat | 8 h | 50100 mg/m3 | Drowsiness, Dizziness, Unconciousness | |
| acetone (67-64-1) | dermal | LD50 | guinea pig | 7426 mg/kg | |||
| Additional information: The product is not classified for acute toxicity. | |||||||
| Name | Species | Time | Result | Method | Remark |
|---|---|---|---|---|---|
| acetone (67-64-1) | rabbit | 24 h | Mild irritating. | ||
| Additional information: The product is not classified as irritating to the skin. | |||||
| Name | Species | Time | Result | Method | Remark |
|---|---|---|---|---|---|
| acetone (67-64-1) | rabbit | 24 h | Irritating. | ||
| Additional information: Causes serious eye irritation. | |||||
| Name | Exposure route | Species | Time | Result | Method | Remark |
|---|---|---|---|---|---|---|
| acetone (67-64-1) | dermal | guinea pig | Non sensitising. | |||
| Additional information: The product is not classified as sensitising. | ||||||
No information.
No information.
No information.
The product is not classified as carcinogenic, mutagenic or toxic for reproduction.
| Name | Exposure route | Type | Species | Time | Organ | Value | Result | Method | Remark |
|---|---|---|---|---|---|---|---|---|---|
| acetone (67-64-1) | - | - | May cause drowsiness or dizziness. | ||||||
| Additional information: May cause drowsiness or dizziness. | |||||||||
| Additional information: Repeated exposure may cause skin dryness or cracking. |
| Additional information: Aspiration hazard: Not classified. |
No information.
No information.
| Substance (CAS Nr.) | Type | Value | Exposure time | Species | Organism | Method | Remark |
|---|---|---|---|---|---|---|---|
| acetone (67-64-1) | LC50 | 5540 mg/L | 96 h | fish | Oncorhynchus mykiss | ||
| LC50 | 8800 mg/L | 48 h | crustacea | Daphnia magna |
No information.
No information.
| Substance (CAS Nr.) | Type | Rate | Time | Evaluation | Method | Remark |
|---|---|---|---|---|---|---|
| acetone (67-64-1) | biodegradability | 91 % | rapidly biodegradable | OECD 301 B |
| Media | Value | Temperature | pH | Concentration | Method |
|---|---|---|---|---|---|
| Log Pow | -0,24 |
| Substance (CAS Nr.) | species | Organism | Value | Duration | Evaluation | Method | Remark |
|---|---|---|---|---|---|---|---|
| acetone (67-64-1) | - | Does not bioaccumulate. |
No information.
No information.
No information.
The substance is not considered persistent, bioaccumulative and toxic (PBT).
No information.
Not classified as hazardous to the aquatic environment.
Do not allow undiluted product or large quantities of it to reach ground water, water bodies or sewage system.
Disposal must be made according to official regulations: deliver it to authorised collector/remover/transformer of hazardous waste. Do not allow product to reach drains/sewage systems. Dispose of in accordance with applicable waste disposal regulation.
Uncleaned containers are classified as hazardous waste - they should be handled in the same manner as the contents. Deliver completely emptied containers to approved waste disposal authorities. Empty containers represent a fire hazard as they may contain flammable product residues and vapour. Uncleaned containers should not be perforated, cut or welded. Dispose of in accordance with applicable waste disposal regulation.
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UN 1090
ACETONE
3
II
NO.
1 L
(D/E)
-16.99 °C, c.c.
F-E, S-D
Goods may not be carried in bulk in bulk containers, containers or vehicles.
- Regulation (EC) No 1907/2006 concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH)(including last amendment Commission Regulation (EU) 2020/878)
- Regulation (EC) No 1272/2008 on classification, labelling and packaging of substances and mixtures
Not applicable.
A Chemical Safety Assessment has not been carried out.
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ATE - Acute Toxicity Estimate
ADR - Agreement concerning the International Carriage of Dangerous Goods by Road
ADN - European Agreement concerning the International Carriage of Dangerous Goods by Inland Waterways
CEN - European Committee for Standardisation
C&L - Classification and Labelling
CLP - Classification Labelling Packaging Regulation; Regulation (EC) No 1272/2008
CAS# - Chemical Abstracts Service number
CMR - Carcinogen, Mutagen, or Reproductive Toxicant
CSA - Chemical Safety Assessment
CSR - Chemical Safety Report
DMEL - Derived Minimal Effect Level
DNEL - Derived No Effect Level
DPD - Dangerous Preparations Directive 1999/45/EC
DSD - Dangerous Substances Directive 67/548/EEC
DU - Downstream User
EC - European Community
ECHA - European Chemicals Agency
EC-Number - EINECS and ELINCS Number (see also EINECS and ELINCS)
EEA - European Economic Area (EU + Iceland, Liechtenstein and Norway)
EEC - European Economic Community
EINECS - European Inventory of Existing Commercial Substances
ELINCS - European List of notified Chemical Substances
EN - European Standard
EQS - Environmental Quality Standard
EU - European Union
Euphrac - European Phrase Catalogue
EWC - European Waste Catalogue (replaced by LoW – see below)
GES - Generic Exposure Scenario
GHS - Globally Harmonized System
IATA - International Air Transport Association
ICAO-TI - Technical Instructions for the Safe Transport of Dangerous Goods by Air
IMDG - International Maritime Dangerous Goods
IMSBC - International Maritime Solid Bulk Cargoes
IT - Information Technology
IUCLID - International Uniform Chemical Information Database
IUPAC - International Union for Pure Applied Chemistry
JRC - Joint Research Centre
Kow - octanol-water partition coefficient
LC50 - Lethal Concentration to 50 % of a test population
LD50 - Lethal Dose to 50% of a test population (Median Lethal Dose)
LE - Legal Entity
LoW - List of Wastes (see http://ec.europa.eu/environment/waste/framework/list.htm)
LR - Lead Registrant
M/I - Manufacturer / Importer
MS - Member States
MSDS - Material Safety Data Sheet
OC - Operational Conditions
OECD - Organization for Economic Co-operation and Development
OEL - Occupational Exposure Limit
OJ - Official Journal
OR - Only Representative
OSHA - European Agency for Safety and Health at work
PBT - Persistent, Bioaccumulative and Toxic substance
PEC - Predicted Effect Concentration
PNEC(s) - Predicted No Effect Concentration(s)
PPE - Personal Protection Equipment
(Q)SAR - Qualitative Structure Activity Relationship
REACH - Registration, Evaluation, Authorisation and Restriction of Chemicals
Regulation (EC) No 1907/2006
RID - Regulations concerning the International Carriage of Dangerous Goods by Rail
RIP - REACH Implementation Project
RMM - Risk Management Measure
SCBA - Self-Contained Breathing Apparatus
SDS - Safety data sheet
SIEF - Substance Information Exchange Forum
SME - Small and Medium sized Enterprises
STOT - Specific Target Organ Toxicity
(STOT) RE - Repeated Exposure
(STOT) SE - Single Exposure
SVHC - Substances of Very High Concern
UN - United Nations
vPvB - Very Persistent and Very Bioaccumulative
Safety Data Sheet, Cure It Acetone, G& B Northwest Ltd, Revision Date: 6th December 2018, Version: 2.2.
H225 Highly flammable liquid and vapour.
H319 Causes serious eye irritation.
H336 May cause drowsiness or dizziness.
EUH066 Repeated exposure may cause skin dryness or cracking.
