SAFETY DATA SHEET according to Regulation 1907/2006
Product name:

smartMELAMINE

Creation date: 29.7.2016 · Revision: 12.6.2017 · Version: 2.1

1. Identification of the substance/mixture and of the company/undertaking


chemius.net/dHlc6

1.1. Product identifier

Product name

smartMELAMINE

1.2. Relevant identified uses of the substance or mixture and uses advised against

Relevant identified uses

Industrial use

Uses advised against

There are no uses advised against.

1.3. Details of the supplier of the safety data sheet

Supplier

smartMELAMINE d.o.o.
Address: Tomšičeva 9, SI-133 Kočevje, Slovenia
Tel.: +49 3672 379 130
Fax: +49 3672 379 379
e-mail: info@smartMELAMINE.com

1.4. Emergency telephone number

Emergency

112

Supplier

+386 1 8959 360

2. Hazards identification

2.1 Classification of the substance or mixture

Classification according to Regulation (EC) No 1272/2008 (CLP)

According to the regulation, the chemical is not classified as hazardous.

2.2 Label elements

2.2.1. Labelling according to Regulation (EC) No 1272/2008 [CLP]

Pictograms not applicable according to Regulation 1272/2008.

2.2.2. Contains:

-

2.2.3. Special provisions

Persons with a history of skin sensitisation problems or asthma, allergies or chronic or recurrent respiratory disease should not be employed in any process in which this product is used.

2.3. Other hazards

No information.

3. Composition/information on ingredients

Product description

Polymer based on melamine resin.

3.1. Substances

For mixtures see 3.2.

3.2. Mixtures

Name CAS
EC
Index
% Classification according to Regulation (EC)
No 1272/2008 (CLP)
Classification according to directive 67/548/EEC or 99/45/EC REACH Registration No.
Melamine-formaldehyde resin 9003-08-1
-
-
>99,99 not classified not classified -
formaldehyde  [B, D]   50-00-0
200-001-8
605-001-00-5
<0,01 Acute Tox. 3; H301
Acute Tox. 3; H311
Skin Corr. 1B; H314
Skin Sens. 1; H317
Acute Tox. 3; H331
Muta. 2; H341
Carc. 1B; H350
T; R23/24/25
C; R34
Carc. Cat. 2; R45
Muta. Cat. 3; R68
Xi; R43
-

Notes for substances:

B Some substances (acids, bases, etc.) are placed on the market in aqueous solutions at various concentrations and, therefore, these solutions require different classification and labelling since the hazards vary at different concentrations.

In Part 3 entries with Note B have a general designation of the following type: "nitric acid … %".

In this case the supplier must state the percentage concentration of the solution on the label. Unless otherwise stated, it is assumed that the percentage concentration is calculated on a weight/weight basis.
D Certain substances which are susceptible to spontaneous polymerisation or decomposition are generally placed on the market in a stabilised form. It is in this form that they are listed in Part 3.

However, such substances are sometimes placed on the market in a non-stabilised form. In this case, the supplier must state on the label the name of the substance followed by the words "non-stabilised".

4. First aid measures

4.1. Description of first aid measures

General notes

When in doubt or if you feel unwell seek medical assistance.

Following inhalation

No special measures required.

Following skin contact

No special measures required.

Following eye contact

No special measures required.

Following ingestion

No special measures required..

4.2. Most important symptoms and effects, both acute and delayed

Inhalation

No symptoms are expected.

Skin contact

No symptoms are expected.

Eye contact

No symptoms are expected.

Ingestion

No symptoms are expected.

4.3. Indication of any immediate medical attention and special treatment needed

There is no specific antidote.

5. Firefighting measures

5.1. Extinguishing media

Suitable extinguishing media

This material will not burn readily. Carbon dioxide. Dry chemical powder. Water spray. Alcohol resistant foam.

Unsuitable extinguishing media

-

5.2. Special hazards arising from the substance or mixture

Hazardous combustion products

In case of a fire toxic gases can be generated; do not inhale gases/smoke.

5.3. Advice for firefighters

Protective actions

-

Special protective equipment for fire-fighters

self-contained breathing apparatus

6. ACCIDENTAL RELEASE MEASURES

6.1. Personal precautions, protective equipment and emergency procedures

6.1.1. For non-emergency personnel

Protective equipment

-

Emergency procedures

Avoid dust formation.

6.1.2. For emergency responders

-

6.2. Environmental precautions

-

6.3. Methods and material for containment and cleaning up

6.3.1. For containment

-

6.3.2. For cleaning up

Pick up mechanically and remove it in accordance with regulation. Collect with suitable tools (shovel,...)

6.3.3. Other information

-

6.4. Reference to other sections

See also sections 8 and 13.

7. Handling and storage

7.1. Precautions for safe handling

7.1.1. Protective measures

Measures to prevent fire

Special safety precautions are not necessary; handle according to work instructions.

Measures to prevent aerosol and dust generation

Avoid formation of dust. Ensure adequate ventilation.

Measures to protect the environment

-

7.1.2. Advice on general occupational hygiene

Do not breathe dust. Do not eat, drink or smoke while working.

7.2. Conditions for safe storage, including any incompatibilities

7.2.1. Technical measures and storage conditions

It has unlimited shelf life by normal storage condition.

7.2.2. Packaging materials

-

7.2.3. Requirements for storage rooms and vessels

-

7.2.4. Storage class

Storage class: 13

7.2.5. Further information on storage conditions

-

7.3. Specific end use(s)

Recommendations

-

Industrial sector specific solutions

-

8. Exposure controls/personal protection

8.1. Control parameters

8.1.1. Occupational Exposure limit values

Name (CAS) Limit values Short-term exposure limit Remarks Biological Tolerance Values
ml/m3
(ppm)
mg/m3
ml/m3
(ppm)
mg/m3
Formaldehyde (50-00-0) 2 2,5 2 2,5

8.1.2. Information on monitoring procedures

BS EN 14042:2003 Title Identifier: Workplace atmospheres. Guide for the application and use of procedures for the assessment of exposure to chemical and biological agents.

8.1.3. DNEL/DMEL values

For components

Name Type Exposure route exp. frequency Value Remark
formaldehyde (50-00-0) Worker inhalation long term (systemic effects) 9 mg/m³
formaldehyde (50-00-0) Worker inhalation long term (local effects) 0,5 mg/m³
formaldehyde (50-00-0) Worker inhalation short term (local effects) 1 mg/m³
formaldehyde (50-00-0) Worker dermal long term (local effects) 0,037 mg/cm2
formaldehyde (50-00-0) Worker dermal long term (systemic effects) 240 mg/kg bw/day
formaldehyde (50-00-0) Consumer oral long term (systemic effects) 4,1 mg/kg bw/day
formaldehyde (50-00-0) Consumer dermal long term (systemic effects) 102 mg/kg bw/day
formaldehyde (50-00-0) Consumer dermal long term (local effects) 0,012 mg/cm2
formaldehyde (50-00-0) Consumer inhalation long term (systemic effects) 3,2 mg/m³
formaldehyde (50-00-0) Consumer inhalation long term (local effects) 0,1 mg/m³

8.1.4. PNEC values

For components

Name Exposure route Value Remark
formaldehyde (50-00-0) fresh water 0,47 mg/L
formaldehyde (50-00-0) marine water 0,47 mg/L
formaldehyde (50-00-0) water, intermittent release 4,7 mg/L
formaldehyde (50-00-0) water treatment plant 0,19 mg/L
formaldehyde (50-00-0) fresh water sediment 2,44 mg/kg
formaldehyde (50-00-0) marine water sediment 2,44 mg/kg
formaldehyde (50-00-0) soil 0,21 mg/kg

8.2. Exposure controls

8.2.1. Appropriate engineering control

Substance/mixture related measures to prevent exposure during identified uses

Prevent dusting. Do not eat, drink or smoke while working.

8.2.2. Personal protective equipment

Eye and face protection

If there is a risk of eye contact use safety glasses.

Hand protection

Choose protective gloves in accordance with workplace specifics.

Skin protection

Working clothes and shoes.

Respiratory protection

Not needed under normal use and adequate ventilation.

Thermal hazards

-

8.2.3. Environmental exposure controls

-

9. PHYSICAL AND CHEMICAL PROPERTIES

9.1. Information on basic physical and chemical properties

- Physical state: solid
- Colour: according to specification
- Odour: No odour

Important health, safety and environmental information

- pH Not applicable
- Melting point/Freezing point not relevant
- Initial boiling point/boiling range Not relevant
- Flash point Not relevant
- Evaporation rate Not relevant
- Flammability (solid, gas) Not relevant
- Explosion limits (vol%) Not relevant
- Vapour pressure Not relevant
- Vapour density Not relevant
- Density Density:
10 – 50 kg/m3
- Solubility Water:
Insoluble
- Partition coefficient No information.
- Auto-ignition temperature Not relevant
- Decomposition temperature > 350 °C
- Viscosity dynamic:
not applicable
- Explosive properties Product is not explosive. Product is not self igniting.
- Oxidising properties Not oxidising.

9.2. Other information

- Solid contents 100 %
- Remarks:

10. STABILITY AND REACTIVITY

10.1. Reactivity

No dangerous reaction known under conditions of normal use.

10.2. Chemical stability

Stable at normal contidions.

10.3. Possibility of hazardous reactions

There are no known hazardous reactions.

10.4. Conditions to avoid

-

10.5. Incompatible materials

Strong oxidizing agents. Strong acids.

10.6. Hazardous decomposition products

Under normal use conditions no hazardous decomposition products are expected. Hazardous decomposition products could be formed by thermal decomposition.

11. Toxicological information

11.1. Information on toxicological effects

11.1.1. Acute toxicity

Additional information

Not classified for acute toxicity.

11.1.2. Skin corrosion/irritation, serious eye damage/irritation

Additional information

The product is not classified as irritating to skin and eyes.

11.1.3. Respiratory or skin sensitisation

Additional information

Not classified as sensitizing. We can't exclude reactions by extremely sensitive persons.

11.1.4. Carcinogenicity, Mutagenicity, Reproductive toxicity

Carcinogenicity

- For product
Exposure route Type Species Time Value result Method Remark
Based to our knowledge and experience there are no adverse health effects expected if handled as recommended.
(Germ cell) mutagenicity

- For product
Type Species Time result Method Remark
Based to our knowledge and experience there are no adverse health effects expected if handled as recommended.
Reproductive toxicity

No information.

Summary of evaluation of the CMR properties

The product is not classified as carcinogenic, mutagenic or toxic for reproduction.

11.1.5. STOT - single and repeated exposure

For product
Exposure route Type Species Time organ Value result Method Exposure Remark
- - Based to our knowledge and experience there are no adverse health effects expected if handled as recommended. Repeated exposure

11.1.6. Aspiration hazard

No information.

12. Ecological information

12.1. Toxicity

12.1.1. Acute (short-term) toxicity

No information.

12.1.2. Chronic (long-term) toxicity

No information.

12.2. Persistence and degradability

12.2.1. Abiotic degradation, physical- and photo-chemical elimination

No information.

12.2.2. Biodegradation

No information.

Additional information

Not easily biodegradable.

12.3. Bioaccumulative potential

12.3.1. Partition coefficient

No information.

12.3.2. Bioconcentration factor (BCF)

No information.

Additional information

No bioaccumulation expected.

12.4. Mobility in soil

12.4.1. Known or predicted distribution to environmental compartments

No information.

12.4.2. Surface tension

No information.

12.4.3. Adsorption/Desorption

No information.

Additional information

Absorption to soil is not expected.

12.5. Results of PBT and vPvB assessment

The components in this formulation do not meet the criteria for classification as PBT or vPvB.

12.6. Other adverse effects

No information.

12.7. Additional information

For product

Product is not classified as dangerous for environment.

13. Disposal considerations

13.1. Waste treatment methods

13.1.1. Product / Packaging disposal

Waste chemical

Waste should be handled in accordance with local or national regulations Reuse or recycle, if possible.

Packaging

Emptied container is suitable for recycling.

13.1.2. Waste treatment-relevant information

-

13.1.3. Sewage disposal-relevant information

-

13.1.4. Other disposal recommendations

-

14. Transport information

14.1. UN number

not applicable

14.2. UN proper shipping name

ADR, RID, IMDG, ADN, IATA: Not dangerous according to transport regulations.

14.3. Transport hazard class(es)

not applicable

14.4. Packing group

not applicable

14.5. Environmental hazards

NO

14.6. Special precautions for user

not applicable

14.7. Transport in bulk according to Annex II of Marpol and the IBC Code

not applicable

15. Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture

- Regulation (EC) No 1907/2006 concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH)(including last amendment Commission Regulation (EU) 2015/830)

- Regulation (EC) No 1272/2008 on classification, labelling and packaging of substances and mixtures

15.1.1. Information according 2004/42/EC about limitation of emissions of volatile organic compounds (VOC-guideline)

not applicable

15.2. Chemical Safety Assessment

The user can obtain addition information on exposure scenarios for preparation components from the supplier of the product.

16. Other information

Indication of changes

-

Abbreviations and acronyms

ATE - Acute Toxicity Estimate
ADR - European Agreement concerning the International Carriage of Dangerous Goods by Road
ADN - European Agreement concerning the International Carriage of Dangerous Goods by Inland Waterways
CEN - European Committee for Standardisation
C&L - Classification and Labelling
CLP - Classification Labelling Packaging Regulation; Regulation (EC) No 1272/2008
CAS# - Chemical Abstracts Service number
CMR - Carcinogen, Mutagen, or Reproductive Toxicant
CSA - Chemical Safety Assessment
CSR - Chemical Safety Report
DMEL - Derived Minimal Effect Level
DNEL - Derived No Effect Level
DPD - Dangerous Preparations Directive 1999/45/EC
DSD - Dangerous Substances Directive 67/548/EEC
DU - Downstream User
EC - European Community
ECHA - European Chemicals Agency
EC-Number - EINECS and ELINCS Number (see also EINECS and ELINCS)
EEA - European Economic Area (EU + Iceland, Liechtenstein and Norway)
EEC - European Economic Community
EINECS - European Inventory of Existing Commercial Substances
ELINCS - European List of notified Chemical Substances
EN - European Standard
EQS - Environmental Quality Standard
EU - European Union
Euphrac - European Phrase Catalogue
EWC - European Waste Catalogue (replaced by LoW – see below)
GES - Generic Exposure Scenario
GHS - Globally Harmonized System
IATA - International Air Transport Association
ICAO-TI - Technical Instructions for the Safe Transport of Dangerous Goods by Air
IMDG - International Maritime Dangerous Goods
IMSBC - International Maritime Solid Bulk Cargoes
IT - Information Technology
IUCLID - International Uniform Chemical Information Database
IUPAC - International Union for Pure Applied Chemistry
JRC - Joint Research Centre
Kow - octanol-water partition coefficient
LC50 - Lethal Concentration to 50 % of a test population
LD50 - Lethal Dose to 50% of a test population (Median Lethal Dose)
LE - Legal Entity
LoW - List of Wastes (see http://ec.europa.eu/environment/waste/framework/list.htm)
LR - Lead Registrant
M/I - Manufacturer / Importer
MS - Member States
MSDS - Material Safety Data Sheet
OC - Operational Conditions
OECD - Organization for Economic Co-operation and Development
OEL - Occupational Exposure Limit
OJ - Official Journal
OR - Only Representative
OSHA - European Agency for Safety and Health at work
PBT - Persistent, Bioaccumulative and Toxic substance
PEC - Predicted Effect Concentration
PNEC(s) - Predicted No Effect Concentration(s)
PPE - Personal Protection Equipment
(Q)SAR - Qualitative Structure Activity Relationship
REACH - Registration, Evaluation, Authorisation and Restriction of Chemicals Regulation (EC) No 1907/2006
RID - Regulations concerning the International Carriage of Dangerous Goods by Rail
RIP - REACH Implementation Project
RMM - Risk Management Measure
SCBA - Self-Contained Breathing Apparatus
SDS - Safety data sheet
SIEF - Substance Information Exchange Forum
SME - Small and Medium sized Enterprises
STOT - Specific Target Organ Toxicity
(STOT) RE - Repeated Exposure
(STOT) SE - Single Exposure
SVHC - Substances of Very High Concern
UN - United Nations
vPvB - Very Persistent and Very Bioaccumulative

Key literature references and sources for data

-

List of relevant H phrases

H301  Toxic if swallowed.
H311  Toxic in contact with skin.
H314  Causes severe skin burns and eye damage.
H317  May cause an allergic skin reaction.
H331  Toxic if inhaled.
H341  Suspected of causing genetic defects .
H350  May cause cancer .

The information of this SDS is based on the present state of our knowledge and meets the requirements of EU and national laws. The user’s working conditions however, are beyond our knowledge and control. The product is not to be used for purposes other than those specified under section 1 without a written permission. It remains the responsibility of the user to ensure that the necessary steps are taken to meet the laws and regulations. Handling of the product may only be done by people above 18 years of age, who are satisfactorily informed of how to do the work, the hazardous properties and necessary safety precautions. The information given in this SDS is to describe the product only in terms of health and safety requirements and should not, therefore, be construed as guaranteeing specific properties.