|
SAFETY DATA SHEET according to Regulation 1907/2006 amended by 2020/878/EU
Product name:
smartMELAMINE
Creation date: 29.7.2016 |
 |
smartMELAMINE
Industrial use
There are no uses advised against.
SuppliersmartMELAMINE d.o.o. |
112
+386 1 8959 360
According to the regulation, the product is not classified as hazardous.
Pictograms not applicable according to Regulation 1272/2008.
-
Persons with a history of skin sensitisation problems or asthma, allergies or chronic or recurrent respiratory disease should not be employed in any process in which this product is used.
No information.
Polymer based on melamine resin.
For mixtures see 3.2.
| Name | CAS EC Index |
% | Classification according to Regulation (EC) No 1272/2008 (CLP) |
Specific Conc. Limits | Classification according to directive 67/548/EEC or 99/45/EC | REACH Registration No. |
|---|---|---|---|---|---|---|
| Melamine-formaldehyde resin | 9003-08-1 - - |
>99,99 | not classified | not classified | - | |
| formaldehyde [B, D] | 50-00-0 200-001-8 605-001-00-5 |
<0,01 | Acute Tox. 3; H301 Acute Tox. 3; H311 Skin Corr. 1B; H314 Skin Sens. 1; H317 Acute Tox. 3; H331 Muta. 2; H341 Carc. 1B; H350 |
Skin Corr. 1B; H314: C ≥ 25 % Skin Irrit. 2; H315: 5 % ≤ C < 25 % Skin Sens. 1; H317: C ≥ 0,2 % Eye Irrit. 2; H319: 5 % ≤ C < 25 % STOT SE 3; H335: C ≥ 5 % |
T; R23/24/25 C; R34 Carc. Cat. 2; R45 Muta. Cat. 3; R68 Xi; R43 |
- |
| B | Some substances (acids, bases, etc.) are placed on the market in aqueous solutions at various concentrations and, therefore, these solutions require different classification and labelling since the hazards vary at different concentrations. In Part 3 entries with Note B have a general designation of the following type: "nitric acid … %". In this case the supplier must state the percentage concentration of the solution on the label. Unless otherwise stated, it is assumed that the percentage concentration is calculated on a weight/weight basis. |
|---|---|
| D | Certain substances which are susceptible to spontaneous polymerisation or decomposition are generally placed on the market in a stabilised form. It is in this form that they are listed in Part 3. However, such substances are sometimes placed on the market in a non-stabilised form. In this case, the supplier must state on the label the name of the substance followed by the words "non-stabilised". |
When in doubt or if feeling unwell seek medical assistance.
No special measures required.
No special measures required.
No special measures required.
No special measures required..
No symptoms are expected.
No symptoms are expected.
No symptoms are expected.
No symptoms are expected.
There is no specific antidote.
This material will not burn readily. Carbon dioxide. Dry chemical powder. Water spray. Alcohol resistant foam.
-
In case of a fire toxic gases can be generated; do not inhale gases/smoke.
-
Full protective clothing and self-contained breathing apparatus.
-
Avoid dust formation.
-
-
-
Pick up mechanically and remove it in accordance with regulation. Collect with suitable tools (shovel,...)
-
See also Sections 8 and 13.
Special safety precautions are not necessary; handle according to work instructions.
Avoid formation of dust. Ensure adequate ventilation.
-
Do not breathe dust. Do not eat, drink or smoke while working.
It has unlimited shelf life by normal storage condition.
-
-
Storage class: 13
-
-
-
| Name (CAS) | Limit values | Short-term exposure limit | Remarks | Biological Tolerance Values | ||
|---|---|---|---|---|---|---|
| ml/m3 (ppm) |
mg/m3 |
ml/m3 (ppm) |
mg/m3 |
|||
| Formaldehyde (50-00-0) | 2 | 2,5 | 2 | 2,5 | Carc | |
BS EN 14042:2003 Title Identifier: Workplace atmospheres. Guide for the application and use of procedures for the assessment of exposure to chemical and biological agents. BS EN 482:2021 Workplace exposure. Procedures for the determination of the concentration of chemical agents. Basic performance requirements.
| Name | Type | Exposure route | Exposure frequency | Value | Remark |
|---|---|---|---|---|---|
| formaldehyde (50-00-0) | Worker | inhalation | long term (systemic effects) | 9 mg/m3 | |
| formaldehyde (50-00-0) | Worker | inhalation | long term (local effects) | 0,5 mg/m3 | |
| formaldehyde (50-00-0) | Worker | inhalation | short term (local effects) | 1 mg/m3 | |
| formaldehyde (50-00-0) | Worker | dermal | long term (local effects) | 0,037 mg/cm2 | |
| formaldehyde (50-00-0) | Worker | dermal | long term (systemic effects) | 240 mg/kg bw/day | |
| formaldehyde (50-00-0) | Consumer | oral | long term (systemic effects) | 4,1 mg/kg bw/day | |
| formaldehyde (50-00-0) | Consumer | dermal | long term (systemic effects) | 102 mg/kg bw/day | |
| formaldehyde (50-00-0) | Consumer | dermal | long term (local effects) | 0,012 mg/cm2 | |
| formaldehyde (50-00-0) | Consumer | inhalation | long term (systemic effects) | 3,2 mg/m3 | |
| formaldehyde (50-00-0) | Consumer | inhalation | long term (local effects) | 0,1 mg/m3 |
| Name | Exposure route | Value | Remark |
|---|---|---|---|
| formaldehyde (50-00-0) | fresh water | 0,47 mg/L | |
| formaldehyde (50-00-0) | marine water | 0,47 mg/L | |
| formaldehyde (50-00-0) | water, intermittent release | 4,7 mg/L | |
| formaldehyde (50-00-0) | water treatment plant | 0,19 mg/L | |
| formaldehyde (50-00-0) | fresh water sediment | 2,44 mg/kg | |
| formaldehyde (50-00-0) | marine water sediment | 2,44 mg/kg | |
| formaldehyde (50-00-0) | soil | 0,21 mg/kg |
Prevent dusting. Do not eat, drink or smoke while working.
If there is a risk of eye contact use safety glasses.
Choose protective gloves in accordance with workplace specifics. Observe the manufacturer's instructions regarding the use, storage, maintenance and replacement of gloves. In case of damage or at the first signs of wear and tear, change the gloves immediately.
Working clothes and shoes.
Not needed under normal use and adequate ventilation.
-
-
| - | Physical state: | solid |
|---|---|---|
| - | Colour: | according to specification |
| - | Odour: | no odour |
| - | pH | Not applicable |
|---|---|---|
| - | Melting point/freezing point | not relevant |
| - | Initial boiling point/boiling range | Not relevant |
| - | Flash point | Not relevant |
| - | Evaporation rate | Not relevant |
| - | Flammability (solid, gas) | Not relevant |
| - | Explosion limits (vol%) | Not relevant |
| - | Vapour pressure | Not relevant |
| - | Vapour density | Not relevant |
| - | Density | Density: 10 – 50 kg/m3 |
| - | Solubility | Water: Insoluble |
| - | Partition coefficient | No information. |
| - | Auto-ignition temperature | Not relevant |
| - | Decomposition temperature | > 350 °C |
| - | Viscosity | Dynamic: not applicable |
| - | Explosive properties | Product is not explosive. Product is not self igniting. |
| - | Oxidising properties | Not oxidising. |
| - | Particle characteristics | No information. |
| - | Solid contents | 100 % |
|---|---|---|
| - | Remarks: |
No dangerous reaction known under conditions of normal use.
Stable at normal contidions.
There are no known hazardous reactions.
-
Strong oxidising agents. Strong acids.
Under normal use conditions no hazardous decomposition products are expected. Hazardous decomposition products could be formed by thermal decomposition.
| Additional information: The product is not classified for acute toxicity. |
| Additional information: The product is not classified as irritating to skin and eyes. |
No information.
| Additional information: The product is not classified as sensitising. The possibility of extremely sensitive persons developing allergic reactions can not be excluded. |
| Name | Type | Species | Time | Result | Method | Remark |
|---|---|---|---|---|---|---|
| For product | Based to our knowledge and experience there are no adverse health effects expected if handled as recommended. |
| Name | Exposure route | Type | Species | Time | Value | Result | Method | Remark |
|---|---|---|---|---|---|---|---|---|
| For product | Based to our knowledge and experience there are no adverse health effects expected if handled as recommended. |
No information.
The product is not classified as carcinogenic, mutagenic or toxic for reproduction.
No information.
| Name | Exposure route | Type | Species | Time | Organ | Value | Result | Method | Remark |
|---|---|---|---|---|---|---|---|---|---|
| For product | - | - | Based to our knowledge and experience there are no adverse health effects expected if handled as recommended. |
No information.
No information.
No information.
No information.
No information.
No information.
No information.
Not easily biodegradable.
No information.
No information.
No bioaccumulation expected.
No information.
No information.
No information.
Absorption to soil is not expected.
The components in this formulation do not meet the criteria for classification as PBT or vPvB.
No information.
Product is not classified as dangerous for environment.
Waste should be handled in accordance with local or national regulations Reuse or recycle, if possible.
Emptied container is suitable for recycling.
-
-
-
Not applicable.
ADR, RID, IMDG, ADN, IATA: Not dangerous according to transport regulations.
Not applicable.
Not applicable.
NO.
Not applicable.
Not applicable.
- Regulation (EC) No 1907/2006 concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH)(including last amendment Commission Regulation (EU) 2020/878)
- Regulation (EC) No 1272/2008 on classification, labelling and packaging of substances and mixtures
Not applicable.
The user can obtain addition information on exposure scenarios for preparation components from the supplier of the product.
Revised sections: 8, 16
ATE - Acute Toxicity Estimate
ADR - Agreement concerning the International Carriage of Dangerous Goods by Road
ADN - European Agreement concerning the International Carriage of Dangerous Goods by Inland Waterways
CEN - European Committee for Standardisation
C&L - Classification and Labelling
CLP - Classification Labelling Packaging Regulation; Regulation (EC) No 1272/2008
CAS# - Chemical Abstracts Service number
CMR - Carcinogen, Mutagen, or Reproductive Toxicant
CSA - Chemical Safety Assessment
CSR - Chemical Safety Report
DMEL - Derived Minimal Effect Level
DNEL - Derived No Effect Level
DPD - Dangerous Preparations Directive 1999/45/EC
DSD - Dangerous Substances Directive 67/548/EEC
DU - Downstream User
EC - European Community
ECHA - European Chemicals Agency
EC-Number - EINECS and ELINCS Number (see also EINECS and ELINCS)
EEA - European Economic Area (EU + Iceland, Liechtenstein and Norway)
EEC - European Economic Community
EINECS - European Inventory of Existing Commercial Substances
ELINCS - European List of notified Chemical Substances
EN - European Standard
EQS - Environmental Quality Standard
EU - European Union
Euphrac - European Phrase Catalogue
EWC - European Waste Catalogue (replaced by LoW – see below)
GES - Generic Exposure Scenario
GHS - Globally Harmonized System
IATA - International Air Transport Association
ICAO-TI - Technical Instructions for the Safe Transport of Dangerous Goods by Air
IMDG - International Maritime Dangerous Goods
IMSBC - International Maritime Solid Bulk Cargoes
IT - Information Technology
IUCLID - International Uniform Chemical Information Database
IUPAC - International Union for Pure Applied Chemistry
JRC - Joint Research Centre
Kow - octanol-water partition coefficient
LC50 - Lethal Concentration to 50 % of a test population
LD50 - Lethal Dose to 50% of a test population (Median Lethal Dose)
LE - Legal Entity
LoW - List of Wastes (see http://ec.europa.eu/environment/waste/framework/list.htm)
LR - Lead Registrant
M/I - Manufacturer / Importer
MS - Member States
MSDS - Material Safety Data Sheet
OC - Operational Conditions
OECD - Organization for Economic Co-operation and Development
OEL - Occupational Exposure Limit
OJ - Official Journal
OR - Only Representative
OSHA - European Agency for Safety and Health at work
PBT - Persistent, Bioaccumulative and Toxic substance
PEC - Predicted Effect Concentration
PNEC(s) - Predicted No Effect Concentration(s)
PPE - Personal Protection Equipment
(Q)SAR - Qualitative Structure Activity Relationship
REACH - Registration, Evaluation, Authorisation and Restriction of Chemicals
Regulation (EC) No 1907/2006
RID - Regulations concerning the International Carriage of Dangerous Goods by Rail
RIP - REACH Implementation Project
RMM - Risk Management Measure
SCBA - Self-Contained Breathing Apparatus
SDS - Safety data sheet
SIEF - Substance Information Exchange Forum
SME - Small and Medium sized Enterprises
STOT - Specific Target Organ Toxicity
(STOT) RE - Repeated Exposure
(STOT) SE - Single Exposure
SVHC - Substances of Very High Concern
UN - United Nations
vPvB - Very Persistent and Very Bioaccumulative
-
H301 Toxic if swallowed.
H311 Toxic in contact with skin.
H314 Causes severe skin burns and eye damage.
H317 May cause an allergic skin reaction.
H331 Toxic if inhaled.
H341 Suspected of causing genetic defects .
H350 May cause cancer .
