SAFETY DATA SHEET according to Regulation 1907/2006
Product name:

Cure It Resin

Creation date: 19.6.2019 · Revision: 2.12.2019 · Version: 1

1. Identification of the substance/mixture and of the company/undertaking


chemius.net/vN79c

1.1. Product identifier

Product name

Cure It Resin

1.2. Relevant identified uses of the substance or mixture and uses advised against

Relevant identified uses

Resin for roofing. Contact the manufacturer for any other applications.

Uses advised against

No information.

1.3. Details of the supplier of the safety data sheet

Supplier

G&B Northwest Ltd
Address: Giants Hall Farm, WN6 8RY Wigan, United Kingdom
Phone: +44 (0)1942 518150
E-mail: technical@cureit.uk.com

1.4. Emergency telephone number

Emergency

+44 (0) 3301 222666

Supplier

+44 (0)1942 518150 Mon-Friday 8.30am – 4.30pm

2. Hazards identification

2.1 Classification of the substance or mixture

Classification according to Regulation (EC) No 1272/2008 (CLP)

Flam. Liq. 3; H226  Flammable liquid and vapour.
Skin Irrit. 2; H315  Causes skin irritation.
Eye Irrit. 2; H319  Causes serious eye irritation.
STOT SE 3; H335  May cause respiratory irritation.
Repr. 2; H361d  Suspected of damaging the unborn child.
STOT RE 1; H372  Causes damage to organs through prolonged or repeated inhalation
Aquatic Chronic 3; H412  Harmful to aquatic life with long lasting effects.

2.2 Label elements

2.2.1. Labelling according to Regulation (EC) No 1272/2008 [CLP]

Signal word: Danger

H226  Flammable liquid and vapour.
H315  Causes skin irritation.
H319  Causes serious eye irritation.
H335  May cause respiratory irritation.
H361d  Suspected of damaging the unborn child.
H372  Causes damage to organs through prolonged or repeated inhalation
H412  Harmful to aquatic life with long lasting effects.
EUH208  Contains phthalic anhydride. May produce an allergic reaction.
P210  Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P243  Take action to prevent static discharges.
P260  Do not breathe vapours.
P273  Avoid release to the environment.
P280  Wear protective gloves/protective clothing/eye protection/face protection.
P302 + P352  IF ON SKIN: Wash with plenty of soap and water.
P304 + P340  IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P305 + P351 + P338  IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P403 + P233  Store in a well-ventilated place. Keep container tightly closed.

2.2.2. Contains:

styrene (CAS: 100-42-5, EC: 202-851-5, Index: 601-026-00-0)

2.2.3. Special provisions

Special hazards are not known or expected.

2.3. Other hazards

No information.

3. Composition/information on ingredients

3.1. Substances

For mixtures see 3.2.

3.2. Mixtures

Name CAS
EC
Index
% Classification according to Regulation (EC)
No 1272/2008 (CLP)
Specific Conc. Limits Classification according to directive 67/548/EEC or 99/45/EC REACH Registration No.
styrene 100-42-5
202-851-5
601-026-00-0
cca. 37 Flam. Liq. 3; H226
Asp. Tox. 1; H304
Skin Irrit. 2; H315
Eye Irrit. 2; H319
Acute Tox. 4; H332
STOT SE 3; H335
Repr. 2; H361d
STOT RE 1; H372
Aquatic Chronic 3; H412
Xn; R20-48/20-65
Xi; R36/37/38
R10
01-2119457861-32
silicon dioxide, amorphous 7631-86-9
231-545-4
-
> 1 not classified not classified 01-2119379499-16
phthalic anhydride 85-44-9
201-607-5
607-009-00-4
<1 Acute Tox. 4; H302
Skin Irrit. 2; H315
Skin Sens. 1; H317
Eye Dam. 1; H318
Resp. Sens. 1; H334
STOT SE 3; H335
Xn; R22-42/43
Xi; R37/38-41
01-2119457017-41
2,2,4,6,6-pentamethylheptane 13475-82-6
236-757-0
-
cca. 0,3 Flam. Liq. 3; H226
Asp. Tox. 1; H304
Aquatic Chronic 4; H413
EUH066
Xn; R65
R10
01-2119490725-29
Naphtha (petroleum), hydrodesulfurized heavy (benzene < 0.1 % w/w)  [P]   64742-82-1
265-185-4
-
cca. 0,1 Flam. Liq. 3; H226
Asp. Tox. 1; H304
Skin Irrit. 2; H315
STOT SE 3; H336
STOT RE 1; H372
Aquatic Chronic 2; H411
Xn; R65
N; R51/53
R10-66-67
01-2119490979-12

Notes for substances:

P The classification as a carcinogen or mutagen need not apply if it can be shown that the substance contains less than 0,1 % w/w benzene (Einecs No 200-753-7).

When the substance is not classified as a carcinogen at least the precautionary statements (P102-)P260- P262-P301 + P310-P331 shall apply.

This note applies only to certain complex oil-derived substances in Part 3.

4. First aid measures

4.1. Description of first aid measures

General notes

When in doubt or if feeling unwell seek medical assistance. Show the safety data sheet and label to the physician. Do not breathe dust/fume/gas/mist/vapors/spray.
Use personal protective equipment. See section 8 for more information.

Following inhalation

Remove patient to fresh air - move out of dangerous area. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. Obtain professional medical help!

Following skin contact

Take off all contaminated clothing. Wash affected skin areas thoroughly with plenty of water and soap. If symptoms develop and persist, seek medical attention.

Following eye contact

Immediately flush eyes with running water, keeping eyelids apart. If irritation persists, seek professional medical attention.

Following ingestion

Do not induce vomiting! Rinse mouth thoroughly with water. Consult a physician. Show the physician the safety data sheet or label. Never give anything by mouth to an unconscious person.

4.2. Most important symptoms and effects, both acute and delayed

Inhalation

Coughing, sneezing, nasal discharge, labored breathing.
Can cause irritation of respiratory system.
Harmful.

Skin contact

Itching, redness, pain.

Eye contact

Redness, tearing, pain.

Ingestion

May cause abdominal discomfort.
May cause nausea/vomiting and diarrhea.
Irritates mucous membranes in the mouth, throat, esophagus and in gastrointestinal area.

4.3. Indication of any immediate medical attention and special treatment needed

-

5. Firefighting measures

5.1. Extinguishing media

Suitable extinguishing media

Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.
Alcohol-resistant foam.
Fire extinguishing powder.
Carbon dioxide (CO2).

Unsuitable extinguishing media

Full water jet.

5.2. Special hazards arising from the substance or mixture

Hazardous combustion products

In case of a fire toxic gases can be generated; do not inhale gases/smoke.
Carbon monoxide (CO).

5.3. Advice for firefighters

Protective actions

In case of fire evacuate the area. In case of fire or heating do not breathe fumes/vapours. No action shall be taken involving any personal risk or without suitable training. Vapours are heavier than air and spread along floor. Vapours may form explosive mixtures with the air. Prolonged heating can cause an explosion. Cool containers at risk with water spray. If possible remove containers from endangered area.

Special protective equipment for firefighters

Firefighters should wear appropriate protective clothing for firefighters (including helmets, protective boots and gloves) (EN 469) and self-contained breathing apparatus (SCBA) with a full face-piece (EN 137).

Additional information

Contaminated firefighting water and fire residues must be disposed of in accordance with the local regulations.

6. ACCIDENTAL RELEASE MEASURES

6.1. Personal precautions, protective equipment and emergency procedures

6.1.1. For non-emergency personnel

Protective equipment

Use personal protective equipment (Section 8).

Emergency procedures

Ensure adequate ventilation. Keep away from sources of ignition and/or heat; No smoking! Take precautionary measures against static discharges. Evacuate the danger zone. No action shall be taken involving any personal risk or without suitable training. Prevent access to unprotected personnel. Do not breathe vapour or mist. Avoid contact with skin, eyes and clothing. In the event of fire and/or explosion do not breathe fumes.

6.1.2. For emergency responders

Use personal protective equipment.

6.2. Environmental precautions

Do not allow product to reach water/drains/sewage systems or permeable soil. If accidental large entry into water or ground occurs, inform responsible authorities.

6.3. Methods and material for containment and cleaning up

6.3.1. For containment

Stem the spill if this does not pose risks.

6.3.2. For cleaning up

Prevent release into the sewer, water, basements or confined areas. Absorb product (with inert material), collect it in special container and dispose it to a licensed hazardous-waste disposal contractor. Make sure the leakage site is well aired. Use spark-proof tools. Dispose in accordance with applicable regulations (see Section 13).

6.3.3. Other information

See Section 12: ECOLOGICAL INFORMATION.

6.4. Reference to other sections

See also Sections 8 and 13.

7. Handling and storage

7.1. Precautions for safe handling

7.1.1. Protective measures

Measures to prevent fire

Ensure adequate ventilation. Take precautionary measures against static discharges. Ensure proper grounding of the equipment. Keep away from sources of ignition - no smoking. Use spark-proof tools. Vapours are heavier than air and spread along the floor. They form explosive mixtures with air. In order to avoid the risk of fires and explosions, never use compressed air when handling. Empty containers may contain flammable or explosive vapours.

Measures to prevent aerosol and dust generation

Use general or local exhaust ventilation to prevent inhaling vapours and aerosols.

Measures to protect the environment

Do not discharge into drains, surface water and soil. After use immediately close container tightly.

7.1.2. Advice on general occupational hygiene

Use good personal hygiene practices – wash hands at breaks and when done working with material. Do not eat, drink or smoke while working. Do not breathe vapours/mist. Avoid contact with skin, eyes and clothes. Remove contaminated clothes and wash them before reuse. Wear suitable protective equipment; see Section 8. In case of insufficient ventilation, wear suitable respiratory protection equipment. Avoid exposure - obtain special instructions before using. Refer to instructions on label and regulations for safety and health at work. Regular cleaning of equipment, work area and clothing is recommended.

7.2. Conditions for safe storage, including any incompatibilities

7.2.1. Technical measures and storage conditions

Store in accordance with local regulations. Keep in a cool, dry and well ventilated place. Store below 30°C. Keep away from heat and sources of ignition. Keep away from food, drink and animal feeding stuffs. Keep away from strong oxidising agents. Keep away from peroxides. Keep away from reducing agents.

7.2.2. Packaging materials

Metallic GRP containers.

7.2.3. Requirements for storage rooms and vessels

Close opened containers after use. Put the containers upright to prevent from leaking. Do not store in unlabelled containers. The empty containers contain the residues of the preparation and therefore can also pose a risk.

7.2.4. Storage class

-

7.2.5. Further information on storage conditions

-

7.3. Specific end use(s)

Recommendations

Roofing resin.

Industrial sector specific solutions

-

8. Exposure controls/personal protection

8.1. Control parameters

8.1.1. Occupational exposure limit values

Name (CAS) Limit values Short-term exposure limit Remarks Biological Tolerance Values
ml/m3
(ppm)
mg/m3
ml/m3
(ppm)
mg/m3
Styrene (100-42-5) 100 430 250 1080
Phthalic anhydride (85-44-9) 4 12 Sen
styrene (100-42-5) 50 215 100 425 India; source: Ministry of Labour and Employment

8.1.2. Information on monitoring procedures

BS EN 14042:2003 Workplace atmospheres. Guide for the application and use of procedures for the assessment of exposure to chemical and biological agents. BS EN 482:2012+A1:2015 Workplace exposure. General requirements for the performance of procedures for the measurement of chemical agents. BS EN 689:2018 Workplace exposure. Measurement of exposure by inhalation to chemical agents. Strategy for testing compliance with occupational exposure limit values.

8.1.3. DNEL/DMEL values

For components

Name Type Exposure route Exposure frequency Value Remark
styrene (100-42-5) Worker inhalation long term (systemic effects) 85 mg/m3
styrene (100-42-5) Worker inhalation short term (systemic effects) 289 mg/m3
styrene (100-42-5) Worker inhalation short term (local effects) 306 mg/m3
styrene (100-42-5) Worker dermal long term (systemic effects) 406 mg/kg bw/day
styrene (100-42-5) Consumer inhalation long term (systemic effects) 10,2 mg/m³
styrene (100-42-5) Consumer inhalation short term (systemic effects) 174,25 mg/m³
styrene (100-42-5) Consumer inhalation long term (local effects) 182,75 mg/m³
styrene (100-42-5) Consumer dermal long term (systemic effects) 343 mg/kg bw/day
styrene (100-42-5) Consumer oral long term (systemic effects) 2,1 mg/kg bw/day

8.1.4. PNEC values

For components

Name Exposure route Value Remark
styrene (100-42-5) fresh water 0,028 mg/L
styrene (100-42-5) water, intermittent release 0,04 mg/L fresh water
styrene (100-42-5) marine water 0,014 mg/L
styrene (100-42-5) water treatment plant 5 mg/L
styrene (100-42-5) fresh water sediment 0,614 mg/kg dry weight
styrene (100-42-5) marine water sediment 0,307 mg/kg dry weight
styrene (100-42-5) soil 0,2 mg/kg dry weight

8.2. Exposure controls

8.2.1. Appropriate engineering control

Substance/mixture related measures to prevent exposure during identified uses

Handle in accordance with good industrial hygiene and safety practice. Use good personal hygiene practices – wash hands at breaks and when done working with material. Do not breathe vapours/aerosols. Do not eat, drink or smoke while working. Avoid contact with skin, eyes and clothes. Appropriate technical measures to reduce exposure of workers must be chosen depending on the specific use of the product and the resulting risk of exposure at the workplace.

Organisational measures to prevent exposure

Remove all contaminated clothes immediately and wash them before reuse.

Technical measures to prevent exposure

Provide good ventilation and local exhaust in areas with increased concentration. Keep away from food, drink and animal feeding stuffs.

8.2.2. Personal protective equipment

Eye and face protection

Safety glasses with side protection (EN 166).

Hand protection

Protective gloves (EN 374). The penetration time is determined by the protective glove manufacturer and must be observed. Observe the manufacturer's instructions regarding the use, storage, maintenance and replacement of gloves. In case of damage or at the first signs of wear and tear, change the gloves immediately. The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer.

Appropriate materials

Material Thickness Penetration Time Remark
Neoprene
Nitrile
Viton (fluorinated rubber)
PVA

Skin protection

Protective antistatic clothing EN 1149 (1:2006, 2:1998 and 3:2004, 5:2008), protective antistatic shoes (EN 20345:2012). Wear fire/flame resistant/retardant clothing. EN ISO 11612:2015 - Protective clothing – Clothing to protect against heat and flame. Standard EN ISO 14116 - Limited flame spread materials

Respiratory protection

In case of insufficient ventilation wear suitable respiratory protection. Protective masks (EN 136) or half masks (EN 140) with filter A (EN 14387). In case of dust formation wear appropriate protective mask - mask with particle filter. Wear suitable protective breathing mask (EN 136) with filter A2-P2 (EN 14387).

Thermal hazards

-

8.2.3. Environmental exposure controls

Technical measures to prevent exposure

Do not allow product to reach drains, sewage systems or ground water.

9. PHYSICAL AND CHEMICAL PROPERTIES

9.1. Information on basic physical and chemical properties

- Physical state: liquid
- Colour: green, blue, according to specification
- Odour: styren like

Important health, safety and environmental information

- pH No information.
- Melting point/freezing point No information.
- Initial boiling point/boiling range No information.
- Flash point 31 °C
- Evaporation rate No information.
- Flammability (solid, gas) No information.
- Explosion limits (vol%) 0,9 – 6,8 vol %
- Vapour pressure 6 hPa at 20 °C
- Vapour density 3,6
- Density Density:
1,11 – 1,15 g/cm3 at 20 °C
- Solubility Water:
Insoluble
- Partition coefficient No information.
- Auto-ignition temperature 490 °C
- Decomposition temperature No information.
- Viscosity kinematic:
209 – 245 mm2/s at 25 °C
Dynamic:
230 – 270 mPas at 25 °C
- Explosive properties No information.
- Oxidising properties No information.

9.2. Other information

- Remarks: Soluble in most organic solvents. Solubility in other solvents: Medium Phthalates.

10. STABILITY AND REACTIVITY

10.1. Reactivity

Product may ignite and burn at temperatures exceeding the flash point.

10.2. Chemical stability

Product is stable under normal conditions of use, recommended handling and storage conditions.

10.3. Possibility of hazardous reactions

Vapours and air can form flammable or explosive mixtures. The risk of polymerization.

10.4. Conditions to avoid

Protect from heat, direct sunlight, open fire, sparks. Exposure to light. Take precautionary measures against static discharges.

10.5. Incompatible materials

Strong oxidising agents.
Peroxide. Reducing agents.

10.6. Hazardous decomposition products

Under normal use conditions no hazardous decomposition products are expected. In case of fire/explosion vapours/gases that pose a health hazard are released. Carbon dioxide; Carbon monoxide.

11. Toxicological information

11.1. Information on toxicological effects

(a) Acute toxicity

NameExposure routeTypeSpeciesTimeValueMethodRemark
styrene (100-42-5)oralLD50rat 5000 mg/kg
styrene (100-42-5)dermalLD50rat24 h> 2000 mg/kg bwOECD 402
styrene (100-42-5)inhalationLC50rat4 h 11,8 mg/l
silicon dioxide, amorphous (7631-86-9)oralLD50rat> 5000 mg/kg bwOECD 401
silicon dioxide, amorphous (7631-86-9)dermalLD50rabbit> 5000 mg/kg
silicon dioxide, amorphous (7631-86-9)inhalationLC50rat4 h> 0,14 mg/lOECD 403
phthalic anhydride (85-44-9)oralLD50rat 1530 mg/kg bw
phthalic anhydride (85-44-9)dermalLD50rabbit> 3160 mg/kg bw
phthalic anhydride (85-44-9)inhalationLC50rat4 h> 2,14 mg/l
2,2,4,6,6-pentamethylheptane (13475-82-6)oralLD50rat> 5000 mg/kg bwOECD 401
2,2,4,6,6-pentamethylheptane (13475-82-6)dermalLD50rabbit≥ 3160 mg/kg bw
2,2,4,6,6-pentamethylheptane (13475-82-6)inhalationLC50rat4 h> 4,95 mg/lEquivalent to OECD 403

(b) Skin corrosion/irritation

NameSpeciesTimeResultMethodRemark
styrene (100-42-5)rabbitIrritating.
silicon dioxide, amorphous (7631-86-9)rabbitNon-irritant.OECD 404
phthalic anhydride (85-44-9)rabbitIrritating.OECD 404
2,2,4,6,6-pentamethylheptane (13475-82-6)rabbitNon-irritant.Equivalent to OECD 404
Additional information: Causes skin irritation.

(c) Serious eye damage/irritation

NameSpeciesTimeResultMethodRemark
styrene (100-42-5)rabbitIrritating.
silicon dioxide, amorphous (7631-86-9)rabbitNo irritant effect.OECD 405
phthalic anhydride (85-44-9)rabbitIrritating to eyes.Draize test
2,2,4,6,6-pentamethylheptane (13475-82-6)rabbitNo irritant effect.OECD 405
Additional information: Causes serious eye irritation.

(d) Respiratory or skin sensitisation

NameExposure routeSpeciesTimeResultMethodRemark
styrene (100-42-5)dermalNon sensitising.
styrene (100-42-5)inhalationNon sensitising.
silicon dioxide, amorphous (7631-86-9)-Non sensitising.
phthalic anhydride (85-44-9)dermalguinea pigSensitizing.OECD 406
phthalic anhydride (85-44-9)inhalationguinea pigSensitizing.
2,2,4,6,6-pentamethylheptane (13475-82-6)dermalguinea pigNegative.OECD 406
Additional information: The product is not classified as sensitising. It contains at least one ingredient that can cause sensitisation. Can cause allergic reaction.

(e) (Germ cell) mutagenicity

NameTypeSpeciesTimeResultMethodRemark
styrene (100-42-5)in-vitro mutagenicitySalmonella typhimuriumEquivocalOECD 471
styrene (100-42-5)in-vitro mutagenicityCell: Mammalian-AnimalEquivocalOECD 476
styrene (100-42-5)in-vitro mutagenicitymammalian cytogenetic testPositive.OECD 473, 479Chromosome aberration assay
styrene (100-42-5)in-vivo mutagenicitymouseNegative.OECD 474, 486
silicon dioxide, amorphous (7631-86-9)BacteriaNegative.OECD 471 (Bacterial Reverse Mutation Test)Ames test
silicon dioxide, amorphous (7631-86-9)in-vitro mutagenicityCell: Mammalian-AnimalNegative.OECD 476
silicon dioxide, amorphous (7631-86-9)in-vitro mutagenicityNegative.OECD 473Chromosome aberration assay
silicon dioxide, amorphous (7631-86-9)in-vivo mutagenicityratNegative.
phthalic anhydride (85-44-9)in-vitro mutagenicityCell: Mammalian-AnimalNegative.OECD 476
phthalic anhydride (85-44-9)in-vitro mutagenicitySalmonella typhimuriumNegative.OECD 471
phthalic anhydride (85-44-9)in-vitro mutagenicitymammalian cytogenetic testEquivocalOECD 473Chromosome aberration assay
2,2,4,6,6-pentamethylheptane (13475-82-6)in-vitro mutagenicityS. typhimurium, other: S. typhimurium TA1535, TA1537, TA98, TA100 and TA1538Negative.Equivalent to OECD 471
2,2,4,6,6-pentamethylheptane (13475-82-6)in-vitro mutagenicityMammalian cells - hamsterNegative.Equivalent to OECD 476
2,2,4,6,6-pentamethylheptane (13475-82-6)in-vitro mutagenicityNegative.Equivalent to OECD 473Chromosome aberration assay
2,2,4,6,6-pentamethylheptane (13475-82-6)in-vivo mutagenicitymouseNegative.Equivalent to OECD 474

(f) Carcinogenicity

NameExposure routeTypeSpeciesTimeValueResultMethodRemark
styrene (100-42-5)inhalation (vapours)NOAELrat≥ 4,34 mg/lnegativeOECD 453
styrene (100-42-5)inhalation (vapours)NOAECmouse (male) 0,09 mg/lOECD 453
styrene (100-42-5)inhalation (vapours)LOAECmouse (male/female)0,09 – 0,18 mg/lPositiveOECD 453
styrene (100-42-5)oralNOAELrat≥ 2000 mg/kg bw/day
styrene (100-42-5)oralLOAELmouse 150 mg/kg bw/dayPositive
silicon dioxide, amorphous (7631-86-9)oralNOAELrat1800 – 32000 mg/kg bw/dayNo effectOECD 453
phthalic anhydride (85-44-9)oralNOAELrat105 weeks 1000 mg/kg bw/daynegative
phthalic anhydride (85-44-9)oralNOAELmouse (male)72 weeks 3570 mg/kg bw/daynegative
phthalic anhydride (85-44-9)oralNOAELmouse (female)72 weeks 1785 mg/kg bw/daynegative

(g) Reproductive toxicity

NameReproductive toxicity typeTypeSpeciesTimeValueResultMethodRemark
styrene (100-42-5)Maternal toxicity + developmental toxicityNOAEC/LOAECrat50 days1,08 – 2,15 mg/LPositive.Inhalation
styrene (100-42-5)Maternal toxicityLOAECrat 1,28 mg/LPositive.OECD 4146-15 days; inhalation
styrene (100-42-5)Developmental toxicityNOAECrat≥ 2,56 mg/LNegative.OECD 4146-15 days; inhalation
styrene (100-42-5)Maternal toxicity + developmental toxicityNOAECrabbit 2,56 mg/LNegative.OECD6-18 days; inhalation
styrene (100-42-5)Effects on fertilityNOAEL/LOAELrat60 days100 – 200 mg/kg bw/dayPositive.Inhalation
styrene (100-42-5)Effects on fertilityNOAEL/LOAELrat60 days200 – 400 mg/kg bw/dayPositive.OECD 422oral
styrene (100-42-5)Reproductive toxicityNOAEC (P/F1)rat 0 mg/Ltwo-generation study; OECD 416Inhalation
styrene (100-42-5)Reproductive toxicityLOAEC (P, F1)rat 2,13 mg/Ltwo-generation study; OECD 416Inhalation
styrene (100-42-5)Reproductive toxicityNOAEC (F2)rat 0,21 mg/Ltwo-generation study; OECD 416Inhalation
styrene (100-42-5)Reproductive toxicityLOAEC (F2)rat70 days 0,64 mg/Ltwo-generation study; OECD 416Inhalation
silicon dioxide, amorphous (7631-86-9)Effects on fertilityNOAELrat 497 mg/kg bw/dayNegative.OECD 415oral
silicon dioxide, amorphous (7631-86-9)Maternal toxicityNOAELrat 1350 mg/kg bw/dayOECD 414oral
phthalic anhydride (85-44-9)Reproductive toxicityNOAELmouse (male)72 weeks 3570 mg/kg bw/dayNegative.oral
phthalic anhydride (85-44-9)Reproductive toxicityNOAELmouse (female)72 weeks 1785 mg/kg bw/dayNegative.oral
phthalic anhydride (85-44-9)Reproductive toxicityNOAELrat (female)105 weeks 1000 mg/kg bw/dayoral
phthalic anhydride (85-44-9)Maternal toxicityNOAELrat 1000 mg/kg bw/dayoral
phthalic anhydride (85-44-9)TeratogenicityNOAELrat 1700 mg/kg bw/dayoral
2,2,4,6,6-pentamethylheptane (13475-82-6)oralNOAELrat≥ 1000 mg/kg bw/dayNegative.Equivalent to OECD 422P/F1
2,2,4,6,6-pentamethylheptane (13475-82-6)Developmental toxicityNOAELrat (female)15 days≥ 5220 mg/m³Negative.Equivalent to OECD 414

Summary of evaluation of the CMR properties

Suspected of damaging the unborn child.

(h) STOT-single exposure

NameExposure routeTypeSpeciesTimeOrganValueResultMethodRemark
phthalic anhydride (85-44-9)inhalation-May cause respiratory irritation.
Additional information: May cause respiratory irritation.

(i) STOT-repeated exposure

NameExposure routeTypeSpeciesTimeOrganValueResultMethodRemark
styrene (100-42-5)inhalation-rat (male)28 daysCentral nervous system, hearing organs 3,47 mg/LCauses damage to organs through prolonged or repeated exposure.
styrene (100-42-5)inhalationNOAEC28 days 2,13 mg/Lototoxicity
styrene (100-42-5)inhalationNOAECmouse28 days 0,181 mg/LOECD 412
styrene (100-42-5)inhalationNOAECrat28 days 0,688 mg/LOECD 412
styrene (100-42-5)inhalationNOAECrat90 daysnose 0,85 mg/L
styrene (100-42-5)inhalationNOAECrat90 daysoverall 2,13 mg/L
styrene (100-42-5)oralNOAELrat 1000 mg/kg bw/day
styrene (100-42-5)oralLOAELrat 2000 mg/kg bw/day
styrene (100-42-5)oralNOAELmouse 150 mg/kg bw/day
styrene (100-42-5)oralLOAELmouse 300 mg/kg bw/day
styrene (100-42-5)inhalationLOAECrat 0,21 mg/LOECD 453
silicon dioxide, amorphous (7631-86-9)oralNOELrat90 days4000 – 4500 mg/kg/dayOECD 408
silicon dioxide, amorphous (7631-86-9)inhalationNOECrat90 days 1,3 mg/m3OECD 413
silicon dioxide, amorphous (7631-86-9)dermalNOAELrabbit≥ 1000 mg/kg bw/day
phthalic anhydride (85-44-9)oralNOAELrat7 weeks 1250 mg/kg bw/day
phthalic anhydride (85-44-9)oralLOAELrat7 weeks 2500 mg/kg bw/day
phthalic anhydride (85-44-9)oralNOAELrat105 weeks 500 mg/kg bw/day
phthalic anhydride (85-44-9)oralLOAELmouse (male/female)72 weeks1717 – 2340 mg/kg bw/day
2,2,4,6,6-pentamethylheptane (13475-82-6)inhalationNOAECmouse17 days≥ 400 ppmEquivalent to OECD 412
2,2,4,6,6-pentamethylheptane (13475-82-6)oralNOAELrat13 weeks≥ 1000 mg/kgEquivalent to OECD 408
2,2,4,6,6-pentamethylheptane (13475-82-6)inhalationNOAELrat13 weeks≥ 1,16 mg/m3OECD 413
2,2,4,6,6-pentamethylheptane (13475-82-6)inhalationNOAECrat105 weeks≥ 400 ppm
2,2,4,6,6-pentamethylheptane (13475-82-6)inhalationNOAECrat105 weeks 25 ppmEquivalent to OECD 453
Additional information: Causes damage to organs through prolonged or repeated exposure.

(j) Aspiration hazard

Additional information: Aspiration hazard: Not classified.

12. Ecological information

12.1. Toxicity

12.1.1. Acute (short-term) toxicity

For components
Substance (CAS Nr.) Type Value Exposure time Species Organism Method Remark
styrene (100-42-5) LC50 4,9 mg/L 72 h algae Pseudokirchneriella subcapitata EPA OTS 797.1050
EC50 4,7 mg/L 48 h crustacea Daphnia magna OECD 202
NOEC 1,9 mg/L 48 h crustacea Daphnia magna OECD 202
EC50 500 mg/L 30 min activated sludge OECD 209
LC50 4,02 mg/L 96 h fish Pimephales promelas OECD 203
silicon dioxide, amorphous (7631-86-9) EL50 ≥ 1000 mg/L 24 h crustacea Daphnia magna OECD 202
LC50 > 10000 mg/L 96 h fish Danio rerio OECD 203
phthalic anhydride (85-44-9) EC50 68 mg/L 72 h algae Pseudokirchneriella subcapitata OECD 201
NOEC 32 mg/L 72 h algae Pseudokirchneriella subcapitata OECD 201
EC50 71 mg/L 48 h crustacea Daphnia magna OECD 202
LC50 > 99 mg/L 96 h fish Oryzias latipes OECD 203
EC50 > 1000 mg/L 3 h microorganisms Activated sludge ISO 8192
EC50 13 mg/L 16 h microorganisms Pseudomonas putida ISO 10712
EC50 731 mg/L Plants Lactuca sativa
2,2,4,6,6-pentamethylheptane (13475-82-6) EC50 > 22,5 mg/L 72 h algae Desmodesmus subspicatus OECD 201
EC50 > 1,3 mg/L 48 h crustacea Daphnia magna ASTM E729-88
LC50 > 2,8 mg/L 96 h fish Danio rerio OECD 203

12.1.2. Chronic (long-term) toxicity

For components
Substance (CAS Nr.) Type Value Exposure time Species Organism Method Remark
styrene (100-42-5) NOEC 1,01 mg/l 21 days crustacea Daphnia magna OECD 211
LOEC 2,06 mg/l 21 days crustacea Daphnia magna
EC50 1,88 mg/l 21 days crustacea Daphnia magna OECD 203
LC50 120 mg/kg soil dw 14 days earthworms Eisenia fetida OECD 207
LOEC 65 mg/kg soil dw earthworms Eisenia fetida OECD 207 burrowing time and mean percent weight change
LOEC 180 mg/kg soil dw earthworms Eisenia fetida OECD 207 survival
NOEC 34 mg/kg soil dw earthworms Eisenia fetida OECD 207 mean percent weight change
phthalic anhydride (85-44-9) NOEC 16 mg/l 21 days crustacea Daphnia magna OECD 211
EC50 42 mg/l 21 days crustacea Daphnia magna OECD 211
LC50 560 mg/l 7 days fish Danio rerio OECD 210
LOEC 32 mg/l 60 days fish
NOEC 10 mg/l 60 days fish OECD 210
2,2,4,6,6-pentamethylheptane (13475-82-6) NOEC 0,013 mg/l 21 days crustacea Daphnia magna OECD 211
NOELR 0,267 mg/l 28 days fish Oncorhynchus mykiss QSAR

12.2. Persistence and degradability

12.2.1. Abiotic degradation, physical- and photo-chemical elimination

No information.

12.2.2. Biodegradation

For components
Substance (CAS Nr.) Type Rate Time Evaluation Method Remark
styrene (100-42-5) biodegradability 87 % 20 days readily biodegradable OECD 301 D
phthalic anhydride (85-44-9) biodegradability 68 % 10 days readily biodegradable OECD 301 D
phthalic anhydride (85-44-9) biodegradability 74 % 30 days readily biodegradable OECD 301 D
2,2,4,6,6-pentamethylheptane (13475-82-6) biodegradability 14 31 days Not inherently degradable EPA OTS 796.3100

12.3. Bioaccumulative potential

12.3.1. Partition coefficient

For components
Substance (CAS Nr.) Media Value Temperature pH Concentration Method
styrene (100-42-5) Octanol-water (log Pow) 3
phthalic anhydride (85-44-9) Octanol-water (log Pow) 1,6

12.3.2. Bioconcentration factor (BCF)

For components
Substance (CAS Nr.) species Organism Value Duration Evaluation Method Remark
styrene (100-42-5) BCF 74 Calculated value

12.4. Mobility in soil

12.4.1. Known or predicted distribution to environmental compartments

No information.

12.4.2. Surface tension

No information.

12.4.3. Adsorption/Desorption

For components
Substance (CAS Nr.) Type Criterion Value Evaluation Method Remark
styrene (100-42-5) Soil 352 Koc
styrene (100-42-5) Soil log KOC 2,55
phthalic anhydride (85-44-9) Soil 31 Koc

12.5. Results of PBT and vPvB assessment

No evaluation.

12.6. Other adverse effects

No specific effects or critical hazards known.

12.7. Additional information

For product

Harmful to aquatic life with long lasting effects.
Do not allow to reach ground water, water courses or sewage system.

For components

Substance: styrene

This substance is not considered to be persistent, bioaccumulative and toxic (PBT). This substance is not considered to be very persistent and very bioaccumulative (vPvB).

Substance: silicon dioxide, amorphous

This substance is not considered to be persistent, bioaccumulative and toxic (PBT). This substance is not considered to be very persistent and very bioaccumulative (vPvB).

Substance: phthalic anhydride

This substance is not considered to be persistent, bioaccumulative and toxic (PBT). This substance is not considered to be very persistent and very bioaccumulative (vPvB).

Substance: 2,2,4,6,6-pentamethylheptane

This substance is not considered to be persistent, bioaccumulative and toxic (PBT). This substance is not considered to be very persistent and very bioaccumulative (vPvB).

13. Disposal considerations

13.1. Waste treatment methods

13.1.1. Product / Packaging disposal

Waste chemical

Dispose of in accordance with applicable waste disposal regulation. Disposal must be made according to official regulations: deliver it to authorised collector/remover/transformer of hazardous waste. Do not allow product to reach drains/sewage systems.

Packaging

Dispose of in accordance with applicable waste disposal regulation. Uncleaned containers are classified as hazardous waste - they should be handled in the same manner as the contents. Deliver completely emptied containers to approved waste disposal authorities. Empty containers represent a fire hazard as they may contain flammable product residues and vapour. Uncleaned containers should not be perforated, cut or welded.

13.1.2. Waste treatment-relevant information

-

13.1.3. Sewage disposal-relevant information

-

13.1.4. Other disposal recommendations

-

14. Transport information

14.1. UN number

UN 1866

14.2. UN proper shipping name

RESIN SOLUTION

14.3. Transport hazard class(es)

3

14.4. Packing group

III

14.5. Environmental hazards

NO.

14.6. Special precautions for user

Limited quantities

5 L

Tunnel restriction code

(D/E)

IMDG flashpoint

31 °C, c.c.

IMDG EmS

F-E, S-E

14.7. Transport in bulk according to Annex II of Marpol and the IBC Code

Goods may not be carried in bulk in bulk containers, containers or vehicles.


15. Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture

- Regulation (EC) No 1907/2006 concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH)(including last amendment Commission Regulation (EU) 2015/830)

- Regulation (EC) No 1272/2008 on classification, labelling and packaging of substances and mixtures

15.1.1. Information according 2004/42/EC about limitation of emissions of volatile organic compounds (VOC-guideline)

Not applicable.

15.1.2. Special instructions

Observe the regulations on employment and protection against dangerous substances for young people, pregnant women and nursing mothers.

15.2. Chemical Safety Assessment

No Chemical Safety Assessment has been carried out for this substance/mixture by the supplier.

16. Other information

Indication of changes

-

Abbreviations and acronyms

ATE - Acute Toxicity Estimate
ADR - European Agreement concerning the International Carriage of Dangerous Goods by Road
ADN - European Agreement concerning the International Carriage of Dangerous Goods by Inland Waterways
CEN - European Committee for Standardisation
C&L - Classification and Labelling
CLP - Classification Labelling Packaging Regulation; Regulation (EC) No 1272/2008
CAS# - Chemical Abstracts Service number
CMR - Carcinogen, Mutagen, or Reproductive Toxicant
CSA - Chemical Safety Assessment
CSR - Chemical Safety Report
DMEL - Derived Minimal Effect Level
DNEL - Derived No Effect Level
DPD - Dangerous Preparations Directive 1999/45/EC
DSD - Dangerous Substances Directive 67/548/EEC
DU - Downstream User
EC - European Community
ECHA - European Chemicals Agency
EC-Number - EINECS and ELINCS Number (see also EINECS and ELINCS)
EEA - European Economic Area (EU + Iceland, Liechtenstein and Norway)
EEC - European Economic Community
EINECS - European Inventory of Existing Commercial Substances
ELINCS - European List of notified Chemical Substances
EN - European Standard
EQS - Environmental Quality Standard
EU - European Union
Euphrac - European Phrase Catalogue
EWC - European Waste Catalogue (replaced by LoW – see below)
GES - Generic Exposure Scenario
GHS - Globally Harmonized System
IATA - International Air Transport Association
ICAO-TI - Technical Instructions for the Safe Transport of Dangerous Goods by Air
IMDG - International Maritime Dangerous Goods
IMSBC - International Maritime Solid Bulk Cargoes
IT - Information Technology
IUCLID - International Uniform Chemical Information Database
IUPAC - International Union for Pure Applied Chemistry
JRC - Joint Research Centre
Kow - octanol-water partition coefficient
LC50 - Lethal Concentration to 50 % of a test population
LD50 - Lethal Dose to 50% of a test population (Median Lethal Dose)
LE - Legal Entity
LoW - List of Wastes (see http://ec.europa.eu/environment/waste/framework/list.htm)
LR - Lead Registrant
M/I - Manufacturer / Importer
MS - Member States
MSDS - Material Safety Data Sheet
OC - Operational Conditions
OECD - Organization for Economic Co-operation and Development
OEL - Occupational Exposure Limit
OJ - Official Journal
OR - Only Representative
OSHA - European Agency for Safety and Health at work
PBT - Persistent, Bioaccumulative and Toxic substance
PEC - Predicted Effect Concentration
PNEC(s) - Predicted No Effect Concentration(s)
PPE - Personal Protection Equipment
(Q)SAR - Qualitative Structure Activity Relationship
REACH - Registration, Evaluation, Authorisation and Restriction of Chemicals Regulation (EC) No 1907/2006
RID - Regulations concerning the International Carriage of Dangerous Goods by Rail
RIP - REACH Implementation Project
RMM - Risk Management Measure
SCBA - Self-Contained Breathing Apparatus
SDS - Safety data sheet
SIEF - Substance Information Exchange Forum
SME - Small and Medium sized Enterprises
STOT - Specific Target Organ Toxicity
(STOT) RE - Repeated Exposure
(STOT) SE - Single Exposure
SVHC - Substances of Very High Concern
UN - United Nations
vPvB - Very Persistent and Very Bioaccumulative

Key literature references and sources for data

-

List of relevant H phrases

H226  Flammable liquid and vapour.
H302  Harmful if swallowed.
H304  May be fatal if swallowed and enters airways.
H315  Causes skin irritation.
H317  May cause an allergic skin reaction.
H318  Causes serious eye damage.
H319  Causes serious eye irritation.
H332  Harmful if inhaled.
H334  May cause allergy or asthma symptoms or breathing difficulties if inhaled.
H335  May cause respiratory irritation.
H336  May cause drowsiness or dizziness.
H361d  Suspected of damaging the unborn child.
H372  Causes damage to organs through prolonged or repeated exposure .
H411  Toxic to aquatic life with long lasting effects.
H412  Harmful to aquatic life with long lasting effects.
H413  May cause long lasting harmful effects to aquatic life.
EUH066  Repeated exposure may cause skin dryness or cracking.

  • Provided correct labelling of the product
  • Compliance with the local legislation
  • Provided correct classification of the product
  • Provided adequate transport data

© BENS Consulting | www.bens-consulting.com

The information of this SDS is based on the present state of our knowledge and meets the requirements of EU and national laws. The user’s working conditions however, are beyond our knowledge and control. The product is not to be used for purposes other than those specified under Section 1 without a written permission. It remains the responsibility of the user to ensure that the necessary steps are taken to meet the laws and regulations. Handling of the product may only be done by people above 18 years of age, who are satisfactorily informed of how to do the work, the hazardous properties and necessary safety precautions. The information given in this SDS is to describe the product only in terms of health and safety requirements and should not, therefore, be construed as guaranteeing specific properties.